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Carbon – Molybdenum – Titanium

Refractory metal systems: phase diagrams, crystallographic and thermodyamic data
  • Materials Science International Team, MSIT ®
  • Ales Kroupa
  • Andy Watson
Part of the Landolt-Börnstein - Group IV Physical Chemistry book series (volume 11E2)

Abstract

This document is part of Volume 11 ‘Ternary Alloy Systems: Phase Diagrams, Crystallographic and Thermodynamic Data’, Subvolume E ‘Refractory Metal Systems’, of Landolt-Börnstein - Group IV ‘Physical Chemistry’.

It contains crystallographic and thermodynamic data about the ternary alloy system:C-Mo-Ti

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Introduction

Keywords

refractory metal system crystallographic data lattice parameter Pearson symbol space group thermodynamic data binary systems solid phases invariant equilibria isothermal section temperature-composition section material properties applications 

References

  1. [1936Mol]
    Molkov, L.P., Vikker, I.V., “Mutual Solubility of the Refractory Metals Carbides” (in Russian), Vestn. Metalloprom., 16(6), 75–2 (1936) (Crys. Structure, Experimental, Phase Relations, 0)Google Scholar
  2. [1943Kie]
    Kieffer, R., Hotop, W., “E. Properties of the Sintered Hard Metals” (in German), in “Pulvermetallurgie und Sinterwerkstoffe”, Springer, Berlin, Heidelberg, 293–2 (1943) (Experimental, Kinetics, Phys. Properties, Thermodyn., 28)Google Scholar
  3. [1956Alb]
    Albeit, H.J., Norton, J.T., “Isothermal Sections in the Systems Molybdenum-Tungsten-Carbon and Molybdenum-Titanium-Carbon” (in German), Planseeber. Pulvermetall., 4(1), 2–2 (1956) (Experimental, Phase Diagram, Phase Relations, Crys. Structure, 1)Google Scholar
  4. [1959Bic]
    Bickerdike, R.L., Hughes, G., “An Examination of Part of the Titanium-Carbon System”, J. Less-Common Met., 1, 42–2 (1959) (Phase Diagram, Phase Relations, Experimental, 4)CrossRefGoogle Scholar
  5. [1961Eng]
    English, J.J., “Binary and Ternary Phase Diagrams of Columbium, Molybdenum, Tantalum and Tungsten”, Defense Metals Information Center, Batelle Memorial Institute, Columbus 1, Ohio, 152, 136–2 (1961) (Phase Diagram, Phase Relations, Review, 1)Google Scholar
  6. [1963Ere]
    Eremenko, V.N., Velikanova T.Ya., “The Interaction of Molybdenum with Titanium Carbide”, Powder Metall. Met. Ceram., 2(5), 347–352 (1963), translated from Poroshk. Metall., 5(17), 3–2 (1963) (Experimental, Morphology, Crys. Structure, Phase Relations, Phase Diagram, 4)CrossRefGoogle Scholar
  7. [1965Kie]
    Kieffer, R., Benesovsky, F., “TiC-Mo2C Hard Metals” (in German), in “Hartmetalle”, Springer-Verlag, Vienna, New York, 250–2 (1965) (Experimental, Mechan. Prop., Review 4)Google Scholar
  8. [1965Rud]
    Rudy, E., Windisch, St., Chang, Y.A., Techn. Rep. AFML-TR-65-2, part 1, vol. 2, 164 (1965) as quoted in [Mas2]Google Scholar
  9. [1967Rud]
    Rudy, E., Windisch, St., Stosick, A.J., Hoffman, J.R., “Constitution of Binary Molybdenum-Carbon Alloys”, Trans. A.I.M.E., 239(11), 1247–1267 (1967) as quoted in [1988And].Google Scholar
  10. [1968Zak]
    Zakharov, A.M., Savitskii, E.M., “Investigation of the Equilibrium Diagram of the Mo-Ti-C System in the Molybdenum-Rich Range”, Russ. Metall. (Engl. Transl.), 1, 100–102 (1968), translated from Izv. Akad. Nauk. SSSR, Met., (1), 162–2 (1968) (Experimental, Phase Diagram, Phase Relations, 9)Google Scholar
  11. [1969Zak]
    Zakharov, A.M., Savitskii, E.M., “Interaction of Mo with Group IV metals and C” (in Russian), Izv. Vyss. Uchebn. Zaved., Tsvetn. Metall., 12(6), 96–2 (1969) (Experimental, Phase Diagram, Phase Relations, 9)Google Scholar
  12. [1969Ere]
    Eremenko, V.N., Velikanova, T.Ya., “Phase Equilibria in the Mo-TiC-Ti Region of the Ternary System Mo-Ti-C. Character of Solidification of Alloys and Projection of the Solidus Surface Part I”, Powder Metall. Met. Ceram., 8(11), 931–936 (1969), translated from Poroshk. Metall., 11(83), 82–2 (1969) (Experimental, Phase Relations, Crys. Structure, Phase Diagram, 14)CrossRefGoogle Scholar
  13. [1969Rud]
    Rudy, E., “Part V. Compendium of Phase Diagram Data, Sect.III.E.6 Ti-Mo-C System” in “Ternary Phase Equilibria in Transition Metal-Boron-Carbon-Silicon Systems”, Techn. Rep. AFML-TR-65-2, Contact No. USAF 33(615)-1249 and 33(615)-67-C-1513, Air Force Materials Laboraty, Wright-Patterson Air Force Base, OH, 5, 298–2 (1969) (Crys. Structure, Experimental, Phase Diagram, Phase Relations, 2)Google Scholar
  14. [1970Ere1]
    Eremenko, V.N., “Carbon-Molybdenum-Titanium” (in Russian), in “Diagrammy Sostoyaniya Metallicheskikh System”, Ageev, N.V. (Ed.), VINITI, Moscow, 270–2 (1970) (Experimental, Phase Diagrams, Phase Relations, Review, 4)Google Scholar
  15. [1970Ere2]
    Eremenko, V.N., Velikanova, T.Ya., “Phase Equilibria in the Mo-TiC-Ti Region of the Ternary System Mo-Ti-C. Part II”, Powder Metall. Met. Ceram., 9(9), 744–747 (1970), translated from Poroshk. Metall., 9(93), 57–2 (1969) (Experimental, Phase Relations, Phase Diagram, Crys. Structure, 9)CrossRefGoogle Scholar
  16. [1970Rud]
    Rudy, E., “Part I. The Phase Diagram of the Systems Ti-Nb-C, Ti-Ta-C, and Ti-Mo-C” in “Phase Equilibria Investigations of Binary, Ternary, and Higher Order Systems”, Tech. Rep. AFML-TR-69-117, Contract No. USAF 33(615)-67-C-1513, Air Force Materials Laboratory, Wright-Patterson Air Force Base, OH, 1–132 (1970)Google Scholar
  17. [1970Zak]
    Zakharov, A.M., Novikov, I.I., Parshikov, V.G., “The Mo-Ti-C Ternary System”, Izv. Vyss. Uchebn. Zaved., Tsvetn. Metall., 13(6), 106–112, (1970) (Experimental, Phase Diagrams, Phase Relations, 6)Google Scholar
  18. [1972Sam1]
    Samsonov, G.V., Bogomol, I.V., L`vov, S.N., Lesnaya, M.I., “Electrophysical Properties of Cermets TiC-Nb, TiC-Ta, TiC-Mo and TiC-W Cermets”, Powder Metall. Met. Ceram., 10(11), 824–828 (1972), translated from Poroshk. Metall., 10(118), 62–2 (1972) (Experimental, Thermodyn., Electr. Prop., 12)CrossRefGoogle Scholar
  19. [1972Sam2]
    Samsonov, G.V., Bogomol, I.V., L`vov, S.N., Lesnaya, M.I., “Thermal Conductivity of Cermets Containing Titanium Carbide”, Powder Metall. Met. Ceram., 11(11), 910–912 (1972), translated from Poroshk. Metall., 11(119), 62–2 (1972) (Experimental, Thermodyn., Electr. Prop., 7)CrossRefGoogle Scholar
  20. [1973Gor]
    Gorbacheva, T.B., Krylov, Yu.I., Mikova, N.M., “Investigation of the Process of High-Temperature Interaction of Refractory Metals with Carbides” (in Russian), Nauch. Tr. Vses. Nauch.-Issled. Proekt. Inst. Tugoplavkikh Met. Tverd. Splavov, 14, 233–2 (1973) (Crys. Structure, Experimental, Phase Relations, 9)Google Scholar
  21. [1973Sam]
    Samsonov, G.V., Bogomol, I.V., Okhremchuk, L.N., Podchernyaeva, I.A., Fomenko, V.S., “Thermoemission Properties of Refractory Carbide Alloys”, Inorg. Mater. (Engl. Trans.), 9(6), 951–953 (1973), translated from Izv. Akad. Nauk SSSR, Neorg. Mater., 9(6), 1064–2 (1973) (Experimental, Phys. Prop., 12)Google Scholar
  22. [1974Vel]
    Velikanova, T.Ya., Eremenko, V.N., “Phase Equilibria in the Ternary Systems Formed by Molybdenum and Tungsten with the Groups IV and V Transition Metals and Carbon”, Powder Metall. Met. Ceram., 13(4), 293–297 (1974), translated from Poroshk. Metall., 4(136), 46–2 (1974) (Experimental, Phase Diagram, Phase Relations, Review, 5)CrossRefGoogle Scholar
  23. [1975Sam]
    Samsonov, G.W., Bogomol, I.W., Ochremtschuk, L.N., Podtschernjajewa, I.A., Fomenko, W.S., “Thermionic Emission of Cermets Made of Refractory Carbides” (in German), Rev. Int. Hautes Temp. Refract., 12(3), 251–2 (1975) (Experimental, Phys. Prop., 10)Google Scholar
  24. [1977Rog]
    Rogl, P., Naik, S.K., Rudy, E., “A Constitutional Diagram of the System TiC-HfC-MoC”, Monats. Chem., 108(6), 1325–2 (1997) (Experimental, Phase Relations, Phase Diagram, 13)CrossRefGoogle Scholar
  25. [1977Tre]
    Trefilov, V.I., Barabash, O.M., Borisenko, V.A., Zakharkin, A.S., Krashenko, V.P., Moiseyev, V.F., Pechkovskiy, E.P., “An Investigation of Composition-Long-Term Hardness Diagrams of Molybdenum Alloys with Interstitial Phases”, Russ. Metall. (Engl. Transl.), 6, 110–116 (1977), translated from Izv. Akad. Nauk SSSR, Met., (6), 136–2 (1977) (Experimental, Mechan. Prop., 25)Google Scholar
  26. [1979Shu]
    Shurin, A.K., Dmitrieva, G.P., Panarin, V.E., “Hardness of Quasibinary Eutectic Alloys with Inclusive Phases” (in Russian), Metallofizika, Sborn. Nauch. Rabot Inst. Metallofiz., (76), 81–2 (1979) (Experimental, Mechan. Prop., Review, 6)Google Scholar
  27. [1981Hol]
    Holleck, H., “Ternary Carbide Systems of the Transition Metals of the 4, 5 and 6 Groups” (in German), in “Binäre und Ternäre Carbide und Nitride der Übergangsmetalle und Ihre Phasen-Beziehungen”, Habil. 1980, KFZ Karlsruhe, 134–2 (1981) (Crys. Structure, Phase Diagram, Phase Relations, Review, 102)Google Scholar
  28. [1982Tak]
    Takatsu, S., Ishimatsu, E., “Sintering and Properties of TiC-, TiN-, and TiB2-Alloys with Refractory Metal Binder”, Int. J. Refract. Hard Mater., 1(2), 75–2 (1982) (Experimental, Mechan. Prop., Morphology, 11)Google Scholar
  29. [1984Hol]
    Holleck, H., “Ternary Carbide Systems of the Transition Metals of the 4, 5, 6 Groups” (in German), in “Binaere und Terneare Carbid- und Nitridsysteme der Uebergangsmetalle”, Petzow, G. (Ed.), Gebrueder Borntraeger, Berlin, Stuttgart, 6, 114–2 (1984) (Crys. Structure, Phase Diagram, Phase Relations, Review, 106)Google Scholar
  30. [1985Ere]
    Eremenko, V.N., Velikanova, T.Ya., Artyukh, L.V., “Phase Diagram of the Mo-Ti-C System” (in Russian), in “Troynie Sistemy Molibdena s Uglerodom i Perehodn. Metall. IV Gruppi”, Naukova Dumka, Kiev, 85–2 (1985) (Crystal Structure, Experimental, Morphology, Phase Diagram, Phase Relations, Review, 206)Google Scholar
  31. [1988And]
    Andersson, J.-O., “Thermodynamic Properties of Mo-C”, Calphad, 12(1), 1–8, (1988) (Phase Diagram, Phase Relations, Thermodyn., Assessment, Theory, 29)CrossRefGoogle Scholar
  32. [1988Bog]
    Bogomolov, A.M., Dzodziev, G.T., Kalkov, A.A., Pak, Yu.A., Shuvaev, A.P., Gotlik, V.A., “Crystal Structure of (Ti,Mo)C Phase”, Powder Metall. Met. Ceram., 27(3), 231–234 (1988), translated from Poroshk. Metall., 3(303), 61–2 (1988) (Crys. Structure, Experimental, 12)Google Scholar
  33. [1988Vel1]
    Velikanova, T.Ya., Eremenko, V.N., “Relationships Governing Phase Equilibria in Refractory Carbide-Bearing Systems of Transition Metals”, Powder Metall. Met. Ceram., 27(2), 145–149 (1988), translated from Poroshk. Metall., 2(302), 63–2 (1988) (Review, Theory, Thermodyn., Electronic Structure, Phase Diagram, Phase Relations, 21)CrossRefzbMATHGoogle Scholar
  34. [1988Vel2]
    Velikanova, T.Ya., Kublii, V.Z., Khaenko, B.V., “Solid State Transformations and Phase Equilibria in the Molybdenum-Carbon System”, Powder Metall. Met. Ceram., 27(11), 891–896 (1988), translated from Poroshk. Metall., 11(311), 61–2 (1988) (Experimental, Phase Diagram, Phase Relations, Thermodyn., 9)Google Scholar
  35. [1990Vel]
    Velikanova, T.Ya., Danilenko, V.M., Rubashevsky, A.A., “Measurements on Systems Containing Metal Carbides”, Powder Metall. Met. Ceram., 29(3), 219–223 (1990), translated from Poroshk. Metall., 3(327), 54–2 (1990) (Phase Diagram, Phase Relations, Theory, Thermodyn., 9)CrossRefGoogle Scholar
  36. [1994Lev]
    Levashov, E.A., Shtanskii, D.V., Vyushkov, B.V., Shtanskaya, E.V., “Formation of the Structure of Titanium-Carbide-Based Alloys in the TiC(α)-Mo-Ni and TiC(α)-Mo Systems during Self-Propagating High-Temperature Compacting”, Phys. Met. Metallogr. (Engl. Transl.), 78(4), 454–2 (1994) (Crys. Structure, Experimental, 8)Google Scholar
  37. [1994McH]
    McHale, A.E., “XI. Carbon Plus Two Metals” in “Phase Equilibria Diagrams, Phase Diagrams for Ceramists”, McHale, A.E. (Ed.), Ceramic Div., Natl. Inst. Stand. Technol., Gaithersburg, Maryland, 10, 320–2 (1994) (Phase Diagram, Phase Relations, Review, 3)Google Scholar
  38. [1996Shi]
    Shim, J., Oh, C.-S., Lee, D., “A Thermodynamic Evaluation of the Ti-Mo-C System”, Metall. Trans. B, 27B, 955–2 (1996) (Calculation, Phase Relations, Phase Diagram, Thermodyn., 29)Google Scholar
  39. [1997Ath]
    Athanasiou, N.S., “Structural Instability and Superconductivity of the Defect Cubic Structure δ-MoC1–x”, Modern Physics Letters B, 11(21–22), 939–2 (1997) (Crys. Structure, Experimental, Phase Relations, Superconduct., 16)CrossRefADSGoogle Scholar
  40. [1997Rya]
    Ryan, N.E., Soffa, W.A., Crawford, R.C., “Orientation and Habit Plane Relationships for Carbide and Nitride Precipitates in Mo”, Mater. Charact., 39(2–5), 65–2 (1997) (Experimental, Morphology, Thermodyn., 5)CrossRefGoogle Scholar
  41. [1999Ban]
    Bandyopadhyay, D., Haldar, B., Sharma, R.C., Chakraborti, N., “The Ti-Mo-C (Titanium-Molybdenum-Carbon) System”, J. Phase Equilib., 20(3), 332–2 (1999) (Phase Relations, Phase Diagram, Review, 9)CrossRefGoogle Scholar
  42. [1999Chu]
    Chung, H-J., Shim, J-H., Lee, D.N., “Thermodynamic Evaluation and Calculation of Phase Equilibria of the Ti-Mo-C-N Quaternary System”, J. Alloys Compd., 282, 142–2 (1999) (Calculation, Phase Relations, Thermodyn., 29)CrossRefGoogle Scholar
  43. [1999Dum]
    Dumitrescu, L.F.S., Hillert, M., Sundman, B., “A Reassessment of Ti-C-N based on a Critical Review of Available Assessments of Ti-N and Ti-C”, Z. Metallkd., 90(7), 534–2 (1999) (Phase Diagram, Phase Relations, Thermodyn., Assessment, 38)Google Scholar
  44. [2002Kou]
    Koutzaki, S.H., Krzanowski, J.E., Nainaparampil, J.J., “Phase Formation and Microstructure in Sputter-Deposited Ti-Mo-C and Ti-W-C Thin Films”, Metall. Mater. Trans. A, 33(6), 1579–2 (2002) (Interface Phenomena, Morphology, Phase Diagram, Phase Relations, 35)CrossRefGoogle Scholar
  45. [2003Che]
    Chen, Z.Q., Li, Y.G., Hu, D., Loretto, M.H., Wu, X., “Role of Alloying Elements in Microstructures of Beta Titanium Alloys with Carbon Additions”, Mater. Sci. Technol., 19, 1391–2 (2003) (Crys. Structure, Experimental, Morphology, Phase Relations, 11)CrossRefGoogle Scholar
  46. [2003Fri]
    Frisk, K., “A Revised Thermodynamic Description of the Ti-C System”, Calphad, 27(4), 367–2 (2003) (Phase Diagram, Phase Relations, Thermodyn., Assessment, Theory, 22)CrossRefGoogle Scholar
  47. [2003Hir]
    Hiraoka, Y., “Strengths and Ductility of Mo-TiC Alloys after Secondary Recrystallization”, Int. J. Refract. Met. Hard Mater., 21(5–6), 265–2 (2003) (Experimental, Kinetics, Mechan. Prop., Morphology, 13)CrossRefGoogle Scholar
  48. [2005Kit]
    Kitsunai, Y., Kurishita, H., Kuwabara, T., Narui, M., Hasegawa, M., Takida, T., Takebe, K., “Radiation Embrittlement Behavior of Fine-grained Molybdenum Alloy with 0.2 mass% TiC Addition”, J. Nucl. Mater., 346(2–3), 233–2 (2005) (Experimental, Mechan. Prop., Morphology, 34)CrossRefADSGoogle Scholar
  49. [2006Ino]
    Inoue, T., Hiraoka, Y., Nagae, M., Takada, J., “Effects of Ti Addition on Carbon Diffusion in Molybdenum”, J. Alloys Compd., 414(1–2), 82–2 (2006) (Experimental, Morphology, Transport Phenomena, 11)CrossRefGoogle Scholar
  50. [2007Kim]
    Kim, T., Kang, S., “On the Quantitative Analysis of Secondary Carbide and Carbon in (Ti1–xMox)C Solid Solutions via XRD Measurements”, Int. J. Refract. Met., in press (available on-line 2007)Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Materials Science International Team, MSIT ®
    • 1
  • Ales Kroupa
  • Andy Watson
  1. 1.Materials Science International Services GmbHStuttgartGermany

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