Abstract
Various applications of carbon nanotubes require their chemical modification inorder to tune/control their physicochemical properties. One way for achieving thiscontrol is by carrying out doping processes through which atoms and moleculesinteract (covalently or noncovalently) with the nanotube surfaces. The aim of thischapter is to emphasize the importance of different types of doping in carbonnanotubes (single-, double- and multiwall). There are three main categories ofdoping: exohedral, endohedral and inplane doping. We will review the most efficientways to dope carbon nanotubes and discuss the effects on the electronic, vibrational,chemical, magnetic and mechanical properties. In addition, we will discuss thedifferent ways of characterizing these doped nanotubes using spectroscopictechniques, such as resonant Raman, X-ray photoelectron, electron energy lossspectroscopy and others. It will be demonstrated that doped carbon nanotubes couldbe used in the fabrication of nanodevices (e.g., sensors, protein immobilizers,field emission sources, efficient composite fillers, etc.). We will also presentresults related to the importance of inplane-doped nanotubes for attachingvarious metal clusters and polymers covalently using wet chemical routes.
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References
M. S. Dresselhaus, G. Dresselhaus, P. C. Eklund: Science of Fullerenes and Carbon Nanotubes (Academic Press, New York 1996)
J. Sloan, M. Terrones, S. Nufer, S. Friedrichs, S. R. Bailey, H. G. Woo, M. Ruhle, J. L. Hutchison, M. L. H. Green: Metastable one-dimensional {AgCl1-xIx} solid-solution wurzite ``tunnel'' crystals formed within single-walled carbon nanotubes, J. Am. Chem. Soc. 124, 2116 (2002)
A. M. Rao, P. C. Eklund, S. Bandow, A. Thess, R. E. Smalley: Evidence for charge transfer in doped carbon nanotube bundles from {Raman} scattering, Nature 388, 257 (1997)
R. S. Lee, H. J. Kim, J. E. Fischer, A. Thess, R. E. Smalley: Conductivity enhancement in single-walled carbon nanotube bundles doped with {K} and {Br}, Nature 388, 255 (1997)
M. S. Dresselhaus, G. Dresselhaus: Intercalationındex{intercalation} compounds of graphite, Adv. Phys. 30, 139 (1981)
S. Kazaoui, N. Minami, R. Jacquemin, H. Kataura, Y. Achiba: Amphoteric doping of single-wall carbon-nanotube thin films as probed by optical absorption spectroscopy, Phys. Rev. B 60, 13339 (1999)
M. R. Pederson, J. Q. Broughton: Nanocapillarity in fullerene tubules, Phys. Rev. Lett. 69, 2689 (1992)
P. M. Ajayan, T. W. Ebbesen, T. Ichihashi, S. Iijima, K. Tanigaki, H. Hiura: Opening carbon nanotubes with oxygen and implications for filling, Nature 362, 522 (1993)
M. Monthioux: Filling single-wall carbon nanotubes, Carbon 40, 1809 (2002)
D. Tasis, N. Tagmatarchis, A. Bianco, M. Prato: Chemistry of carbon nanotubes, Chem. Rev. 106, 1105 (2006)
Z. Y. Wang, Z. B. Zhao, J. S. Qiu: Development of filling carbon nanotubes, Prog. Chem. 18, 563 (2006)
M. Terrones, N. Grobert, W. K. Hsu, Y. Q. Zhu, W. B. Hu, H. Terrones, J. P. Hare, H. W. Kroto, D. R. M. Walton: Advances in the creation of filled nanotubes and novel nanowires, Mater. Res. Soc. Bull. 24, 43 (1999)
S. Iijima, T. Ichihashi: Single-shell carbon nanotubes of 1 nm diameter, Nature 363, 603 (1993)
D. S. Bethune, C. H. Kiang, M. S. D. Vries, G. Gorman, R. Savoy, J. Vazquez, R. Beyers: Cobalt-catalyzed growth of carbon nanotubes with single-atomic-layerwalls, Nature 363, 605 (1993)
B. W. Smith, M. Monthioux, D. E. Luzzi: Encapsulated {C60} in carbon nanotubes, Nature 296, 323 (1998)
J. Sloan, J. Hammer, M. Z. Sibley, M. L. H. Green: The opening and filling of single walled carbon nanotubes ({SWTs}), Chem. Commun. 3, 347 (1998)
C. H. Kiang, J. S. Choi, T. T. Tran, A. D. Bacher: Molecular nanowires of 1 nm diameter from capillary filling of single-walled carbon nanotubes, J. Phys. Chem. B 103, 7449 (1999)
P. Corio, A. P. Santos, M. L. A. Temperini, V. W. Brar, M. A. Pimenta, M. S. Dresselhaus: Chem. Phys. Lett. 383, 475 (2004)
A. Govindaraj, B. C. Satishkumar, M. Nath, C. N. R. Rao: Metal nanowires and intercalated metal layers in single-walled carbon nanotube bundles, Chem. Mater. 12, 205 (2000)
J. Sloan, D. M. Wright, H. G. Woo, S. R. Bailey, G. Brown, A. P. E. York, K. S. Coleman, J. L. Hutchison, M. L. H. Green: Capillarity and silver nanowire formation observed in single walled carbon nanotubes, Chem. Commun. 700, 699 (1999)
R. R. Meyer, J. Sloan, R. E. Dunin-Borkowski, A. Kirkland, M. C. Novotny, S. R. Bailey, J. L. Hutchison, M. L. H. Green: Discrete atom imaging of one-dimensional crystals formed within single-walled carbon nanotubes, Science 289, 1324 (2000)
D. E. Luzzi, B. W. Smith: Carbon cage structures in single wall carbon nanotubes: a new class of materials, Carbon 38, 1751 (2000)
E. Hernández, V. Meunier, B. W. Smith, R. Rurali, H. Terrones, Buongiorno, N. Nardelli, M. Terrones, D. E. Luzzi, J. C. Charlier: Fullerene coalescence in nanopeapods: A path to novel tubular carbon, Nano Lett. 3, 1037 (2003)
K. Hirahara, K. Suenaga, S. Bandow, H. Kato, T. Okazaki, H. Shinohara, S. Iijima: One-dimensional metallofulerene crystal generated inside single-walled carbon nanotubes, Phys. Rev. Lett. 85, 5384 (2000)
A. Khlobystov, D. A. Britz, A. Ardavan, G. A. D. Briggs: Observation of ordered phases of fullerenes in carbon nanotubes, Phys. Rev. Lett. 92, 245507 (2004)
D. Ugarte, T. Stockli, J. M. Bonard, A. Chatelain, W. A. D. Heer: Filling carbon nanotubes, Appl. Phys. A 67, 101 (1998)
A. Kolesnikov, J. M. Zanotti, C. K. Loong, P. Thiyagarajan, A. P. Moravsky, R. O. Loutfy, C. J. Burnham: Anomalously soft dynamics of water in a nanotube: A revelation of nanoscale confinement, Phys. Rev. Lett. 93, 035503 (2004)
L. J. Li, A. N. Khlobystov, J. G. Wiltshire, G. A. Briggs, R. J. Nicholas: Diameter-selective encapsulation of metallocenes in single-walled carbon nanotubes, Nature Mater. 4, 481 (2005)
H. Kataura, Y. Maniwa, T. Kodama, K. Kikuchi, K. Hirahara, S. Iijima, S. Suzuki, W. Krätschmer, Y. Achiba: Fullerene-peapods: Synthesis, structure, and {Raman} spectroscopy, in H. Kuzmany, J. Fink, M. Mehring, S. Roth (Eds.): Electronic Properties of Molecular Nanostructures, AIP Proc. 591 (2001) p. 251
C. E. Lowell: Solid solution of boron in graphite, J. Am. Ceram. Soc. 50, 142 (1966)
C. T. Hach, L. E. Jones, C. Crossland, P. A. Thrower: An investigation of vapor deposited boron rich carbon – a novel graphite-like material – part {I}: the structure of {BCx (C6B)} thin films, Carbon 37, 221 (1999)
A. Oya, R. Yamashita, S. Otani: Catalytic graphitization of carbons by borons, Fuel 58, 495 (1979)
M. Endo, T. Hayashi, S. H. Hong, T. Enoki, M. S. Dresselhaus: Scanning tunneling microscope study of boron-doped highly oriented pyrolytic graphite, J. Appl. Phys. 90, 5670 (2001)
M. Endo, C. Kim, T. Karaki, Y. Nishimura, M. J. Matthews, S. D. M. Brown, M. S. Dresselhaus: Anode performance of a {Li} ion battery based on graphitized and {B}-doped milled mesophase pitch-based carbon fibers, Carbon 37, 561 (1999)
A. Marchand, J. V. Zanchetta: Proprietes electroniques d'un carbone dope a l'azote, Carbon 3, 483 (1966)
K. Takeya, K. Yazawa: Unusual galvanomagnetic properties of pyrolytic graphite, J. Phys. Soc. Jpn. 19, 138 (1964)
K. T. K. Yazawa, N. Okuyama, H. Akutsu: Evidence for existence of extremely light carriers in pyrolytic carbons, Phys. Rev. Lett. 15, 111 (1965)
T. Belz, A. Baue, J. Find, M. Günter, D. Herein, H. Möckel, N. Pfänder, H. Sauer, G. Schulz, J. Schütze, O. Timpe, U. Wild, R. Schlögi: Structural and chemical characterization of {N}-doped nanocarbons, Carbon 36, 731 (1998)
E. Hernández, C. Goze, P. Bernier, A. Rubio: Elastic properties of {C} and {B}x{C}y{N}z composite nanotubes, Phys. Rev. Lett. 80, 4502 (1999)
E. Hernández, C. Goze, P. Bernier, A. Rubio: Elastic properties of single-wall nanotubes, Appl. Phys. A. Mater 68, 287 (1999)
R. P. Gao, Z. L. Wang, Z. G. Bai, W. A. de Heer, L. M. Dai, M. Gao: Nanomechanics of individual carbon nanotubes from pyrolytically grown arrays, Phys. Rev. Lett. 85, 622 (2000)
R. J. Baierle, S. B. Fagan, R. Mota, A. J. R. da Silva, A. Fazzio: Electronic and structural properties of silicon-doped carbon nanotubes, Phys. Rev. 64, 085413 (2001)
E. Cruz-Silva, D. Cullen, L. Gu, J. M. Romo-Herrera, E. {Muñoz}-Sandoval, F. L\'opez-Ur\'ias, D. J. Smith, H. Terrones, M. Terrones: Hetero-doped nanotubes: Theory, synthesis and characterization of phosphorous-nitrogen doped multiwalled carbon nanotubes submitted
S. B. Fagan, R. Mota, R. J. Baierle, A. J. R. da Silva, A. Fazzio: Ab initio study of an organic molecule interacting with a silicon-doped carbon nanotube, Diam. Relat. Mater. 12, 861 (2003)
O. Stephan, P. M. Ajayan, C. Colliex, P. Redlich, J. M. Lambert, P. Bernier, P. Lefin: Doping graphitic and carbon nanotube structures with boron and nitrogen, Science 266, 1683 (1994)
P. Redlich, L. Loeffler, P. M. Ajayan, J. Bill, F. Aldinger, M. Ruhle: {B}-{C}-{N} nanotubes and boron doping of carbon nanotubes, Chem. Phys. Lett. 260, 465 (1996)
M. Terrones, W. K. Hsu, S. Ramos, R. Castillo, H. Terrones: The role of boron nitride in graphite plasma arcs, Full. Sci. Tech. 6, 787 (1998)
W. K. Hsu, M. Terrones: unpublished results
M. Glerup, J. Steinmetz, D. Samaille, O. Stephan, S. Enouz, A. Loiseau, S. Roth, P. Bernier: Synthesis of {N}-doped {SWNT} using the arc-discharge procedure, Chem. Phys. Lett. 387, 193 (2004)
Y. Zhang, H. Gu, K. Suenaga, S. Iijima: Heterogeneous growth of {B}–{C}–{N} nanotubes by laser ablation, Chem. Phys. Lett. 279, 264 (1997)
P. Gai, O. Stephan, K. McGuire, A. M. Rao, M. S. Dresselhaus, G. Dresselhaus, C. Colliex: Structural systematics in boron-doped single wall carbon nanotubes, J. Mater. Chem. 14, 669 (2004)
M. Terrones, N. Grobert, J. Olivares, J. P. Zhang, H. Terrones, K. Kordatos, W. K. Hsu, J. P. Hare, P. D. Townsend, K. Prassides, A. K. Cheetham, H. W. Kroto, D. R. M. Walton: Controlled production of aligned-nanotube bundles, Nature 388, 52 (1997)
M. Terrones, P. Redlich, N. Grobert, S. Trasobares, W. K. Hsu, H. Terrones, Y. Q. Zhu, J. P. Hare, C. L. Reeves, A. K. Cheetham, M. Ruhle, H. W. Kroto, D. R. M. Walton: Carbon nitride nanocomposites: Formation of aligned {C}x{N}y nanofibers, Adv. Mater. 11, 655 (1999)
R. Sen, B. C. Satishkumar, S. Govindaraj, K. R. Harikumar, M. K. Renganathan, C. N. R. Rao: Nitrogen-containing carbon nanotubes, J. Mater. Chem. 7, 2335 (1997)
G. Keskar, R. Rao, J. Luo, J. Hudson, A. M. Rao: Growth, nitrogen doping and characterization of isolated single-wall carbon nanotubes using liquid precursors, Chem. Phys. Lett. 412, 269 (2005)
F. Villalpando-Paez, A. Zamudio, A. L. Elias, H. Son, E. B. Barros, S. Chou, Y. A. Kim, H. Muramatsu, T. Hayashi, J. Kong, H. Terrones, G. Dresselhaus, M. Endo, M. Terrones, M. S. Dresselhaus: Synthesis and characterization of long strands of nitrogen-doped single-walled carbon nanotubes, Chem. Phys. Lett. 424, 345 (2006)
D. Golberg, Y. Bando, L. Bourgeois, K. Kurashima, T. Sato: Large-scale synthesis and {HRTEM} analysis of single-walled {B}- and {N}-doped carbon nanotube bundles, Carbon 38, 2017 (2000)
E. Borowiak-Palen, T. Pichler, G. G. Fuentes, A. Graff, R. J. Kalenczuk, M. Knupfer, J. Fink: Efficient production of {B}-substituted single-wall carbon nanotubes, Chem. Phys. Lett. 378, 516 (2003)
M. Endo, H. Muramatsu, T. Hayashi, Y. A. Kim, G. V. Lier, J. C. Charlier, H. Terrones, M. Terrones, M. S. Dresselhaus: Atomic nanotube welders: Boron interstitials triggering connections in double-walled carbon nanotubes, Nano Lett. 5, 1099 (2005)
E. G. Wang, Z. G. Guo, J. Ma, M. M. Zhou, Y. K. Pu, S. Liu, G. Y. Zhang, D. Y. Zhong: Optical emission spectroscopy study of the influence of nitrogen on carbon nanotube growth, Carbon 41, 1827 (2003)
K. Teo, M. Chhowalla, G. A. J. Amaratunga, W. I. Milne, D. G. Hasko, G. Pirio, P. Legagneux, F. Wyczisk, D. Pribat: Uniform patterned growth of carbon nanotubes without surface carbon, Appl. Phys. Lett. 79, 1534 (2001)
K. Teo, D. B. Hash, R. G. Lacerda, N. L. Rupesinghe, M. S. Bell, S. H. Dalal, D. Bose, T. R. Govindan, B. A. Cruden, M. Chhowalla, G. A. J. Amaratunga, J. M. Meyyappan, W. I. Milne: The significance of plasma heating in carbon nanotube and nanofiber growth, Nano Lett. 4, 921 (2004)
J. Yu, X. D. Bai, J. Ahn, S. F. Yoon, E. G. Wang: Highly oriented rich boron {B}–{C}–{N} nanotubes by bias-assisted hot filament chemical vapor deposition, Chem. Phys. Lett. 323, 529 (2000)
A. Jorio, M. A. Pimenta, A. G. {Souza Filho}, R. Saito, M. S. Dresselhaus, G. Dresselhaus: {Characterizing} carbon nanotube samples with resonance {Raman} scattering, New J. Phys. 5, 137 (2003)
K. Koziol, M. S. Shaffer, A. H. Windle: Three-dimensional internal order in multiwalled carbon nanotubes grown by chemical vapor deposition, Adv. Mater. 17, 760 (2005)
C. Ducati, K. Koziol, S. Friedrichs, T. J. V. Yates, M. S. Shaffer, P. A. Midgkey, A. H. Windle: Crystallographic order in multi-walled carbon nanotubes synthesized in the presence of nitrogen, Small 2, 774 (2006)
P. Kohler-Redlich, M. Terrones: Detection of {B} using {EELS} within {B}-doped carbon nanotubes, Unpublished results
X. Blase, J.-C. Charlier, A. D. Vita, R. Car, P. Redlich, Ph, M. Terrones, W. K. Hsu, H. Terrones, D. L. Carroll, P. M. Ajayan: Boron-mediated growth of long helicity-selected carbon nanotubes, Phys. Rev. Lett. 83, 5078, (1999)
W. Hsu, S. Firth, P. Redlich, M. Terrones, H. Terrones, Y. Q, Zhu, N. Grobert, A. Schilder, R. J. H. Clark, H. W. Kroto, D. R. M. Walton: Boron doping effects in carbon nanotubes, J. Mater. Chem. 10, 1425 (2000)
E. Hernández, P. Ordejόn, I. Boustani, A. Rubio, J. A. Alonso: Tight binding molecular dynamics stuides of boron assisted nanotube growth, J. Chem. Phys. 113, 3814 (2000)
M. Terrones, N. Grobert, H. Terrones: Synthetic routes to nanoscale {B}x{C}y{N}z architectures, Carbon 40, 1665 (2002)
K. McGuire, N. Gothard, P. Gai, M. Dresselhaus, G. Sumanasekera, A. Rao: Synthesis and {Raman} characterization of boron-doped single-walled carbon nanotubes, Carbon 43, 219 (2005)
M. Terrones, W. K. Hsu, A. Schilder, H. Terrones, N. Grobert, J. P. Hare, Y. Q. Zhu, M. Schwoerer, K. Prassides, H. W. Kroto, D. R. M. Walton: Novel nanotubes and encapsulated nanowires, Appl. Phys. A-Mater. 66, 307 (1998)
D. Carroll, P. Redlich, X. Blase, J. C. Charlier, S. Curran, P. M. Ajayan, S. Roth, M. Ruhle: Effects of nanodomain formation on the electronic structure of doped carbon nanotubes, Phys. Rev. Lett. 81, 2332 (1998)
R. Czerw, M. Terrones, J. C. Charlier, X. Blase, B. Foley, R. Kamalakaran, N. Grobert, H. Terrones, D. Tekleab, P. M. Ajayan, W. Blau, M. Ruhle, D. L. Carroll: {Identification} of electron donor states in {N}-doped carbon nanotubes, Nano Lett. 1, 457 (2001)
K. Liu, P. Avouris, R. Martel, W. K. Hsu: Electrical transport in doped multiwalled carbon nanotubes, Phys. Rev. B 63, 161404 (2001)
D. Golberg, P. S. Dorozhkin, Y. Bando, Z. C. Dong, C. C. Tang, Y. Uemura, N. Grobert, M. Reyes-Reyes, H. Terrones, M. Terrones: {Structure}, transport and field-emission properties of compound nanotubes: {CN}_x vs. {BNC}_x (x < 0.1), Appl. Phys. A-Mater. 76, 499 (2003)
S. Latil, S. Roche, D. Mayou, J.-C. Charlier: Mesoscopic transport in chemically doped carbon nanotubes, Phys. Rev. Lett. 92, 256805 (2004)
W. K. Hsu, S. Y. Chu, E. Munoz-Picone, J. L. Boldu, S. Firth, P. Franchi, B. P. Roberts, A. Schilder, H. Terrones, N. Grobert, Y. Q. Zhu, M. Terrones, M. E. McHenry, H. W. Kroto, D. R. M. Walton: Metallic behaviour of boron-containing carbon nanotubes, Chem. Phys. Lett. 323, 572 (2000)
Y. M. Choi, D. S. Lee, R. Czerw, P. W. Chiu, N. Grobert, M. Terrones, M. Reyes-Reyes, H. Terrones, J. C. Charlier, P. M. Ajayan, S. Roth, D. L. Carroll, Y. W. Park: Nonlinear behavior in the thermopower of doped carbon nanotubes due to strong, localized states, Nano Lett. 3, 839 (2003)
L. Grigorian, G. U. Sumanasekera, A. L. Loper, S. Fang, J. L. Allen, P. C. Eklund: Transport properties of alkali-metal-doped single-wall carbon nanotubes, Phys. Rev. B 58, 4195 (1998)
K. Bradley, S. Jhi, P. G. Collins, J. Hone, M. L. Cohen, S. G. Louie, A. Zettl: Is the intrinsic thermoelectric power of carbon nanotubes positive?, Phys. Rev. Lett. 85, 4361 (2000)
S. Bandow, A. M. Rao, G. U. Sumanasekera, P. C. Eklund, F. Kokai, K. Takahashi, S. Iijima: {Evidence} for anomalously small charge transfer in doped single-wall carbon nanohorn aggregates with {Li}, {K} and {Br}, Appl. Phys. A-Mater. 71, 561 (2000)
M. S. Dresselhaus, P. C. Eklund: Phonons in carbon nanotubes, Adv. Phys. 40, 705 (2000)
M. S. Dresselhaus, G. Dresselhaus, A. Jorio, A. G. {Souza Filho}, R. Saito: Raman spectroscopy on isolated single wall carbon nanotubes, Carbon 40, 2043 (2002)
A. Kukovecz, T. Pichler, R. Pfeiffer, H. Kuzmany: {Diameter} selective charge transfer in p- and n-doped single wall carbon nanotubes synthesized by the {HiPCO} method, Chem. Commun. 5, 1730 (2002)
A. Jorio, R. Saito, J. H. Hafner, C. M. Lieber, M. Hunter, T. McClure, G. Dresselhaus, M. S. Dresselhaus: {Structural} (n, m) determination of isolated single-wall carbon nanotubes by resonant {Raman} scattering, Phys. Rev. Lett. 86, 1118 (2001)
A. G. {Souza Filho}, A. Jorio, G. G. Samsonidze, G. Dresselhaus, R. Saito, M. S. Dresselhaus: Raman spectroscopy for probing chemically/physically induced phenomena in carbon nanotubes, Nanotechnol. 14, 1130 (2003)
Y. A. Kim, M. Kojima, H. Muramatsu, S. Umemoto, T. Watanabe, K. Yoshida, K. Sato, T. Ikeda, T. Hayashi, M. Endo, M. Terrones, M. S. Dresselhaus: In situ {Raman} study on single- and double-walled carbon nanotubes as a function of lithium insertion, Small 2, 667–676 (2006)
B. Akdim, X. Duan, D. A. Shiffler, R. Pachter: Theoretical study of the effects of alkali-metal atoms adsorption on {Raman} spectra of single-wall carbon nanotubes, Phys. Rev. B 72, 121402 (2005)
H. Kuzmany, A. Kukovecz, F. Simon, M. Holzweber, C. Kramberger, T. Pichler: Functionalization of carbon nanotubes, Synth. Met. 141, 113 (2004)
S. B. Fagan, A. G. {Souza Filho}, J. {Mendes Filho}, P. Corio, M. S. Dresselhaus: {Electronic} properties of {Ag}- and {CrO}3-filled single-wall carbon nanotubes, Chem. Phys. Lett. 456, 54 (2005)
P. Corio, A. P. Santos, M. L. A. Temperini, V. W. Brar, M. A. Pimenta, M. S. Dresselhaus: Characterization of single wall carbon nanotubes filled with silver and with chromium compounds, Chem. Phys. Lett. 383, 475 (2004)
G. Chen, C. A. Furtado, U. J. Kim, P. C. Eklund: Alkali-metal-doping dynamics and anomalous lattice contraction of individual debundled carbon nanotubes, Phys. Rev. B 72, 155406 (2005)
G. Chen, C. A. Furtado, S. Bandow, S. Iijima, P. C. Eklund: {Anomalous} contraction of the {C}–{C} bond length in semiconducting carbon nanotubes observed during {Cs} doping, Phys. Rev. B 71, 045408 (2005)
L. Terrazos, R. B. Capaz: unpublished results
T. Pichler, A. Kukovecz, H. Kuzmany, H. Kataura: Charge transfer in doped single wall carbon nanotubes, Synth. Met. 135-136, 717 (2003)
S. Guerini, A. G. {Souza Filho}, J. M. Filho, O. L. Alves, S. B. Fagan: {Electronic} properties of {FeCl}3-adsorbed single-wall carbon nanotubes, Phys. Rev. B 72, 233401 (2005)
A. Rakitin, C. Papadopoulos, J. M. Xu: Carbon nanotube self-doping: Calculation of the hole carrier concentration, Phys. Rev. B 67, 033411 (2003)
A. G. {Souza Filho}, M. Endo, H. Muramatsu, T. Hayashi, Y. A. Kim, E. B. Barros, N. Akuzawa, G. G. Samsonidze, R. Saito, M. S. Dresselhaus: {Resonance} {Raman} scattering studies in {Br}-2-adsorbed double-wall carbon nanotubes, Phys. Rev. B 73, 235413 (2006)
T. C. Chieu, M. S. Dresselhaus, M. Endo: Raman studies of benzene-derived graphite fibers, Phys. Rev. B 26, 5867 (1982)
M. Endo, Y. A. Kim, T. Hayashi, H. Muramatsu, M. Terrones, R. Saito, F. Villalpando-Paez, S. G. Chou, M. S. Dresselhaus: Nanotube coalescence-inducing mode: A novel vibrational mode in carbon systems, Small 2, 1031 (2006)
C. Fantini, E. Cruz, A. Jorio, M. Terrones, H. Terrones, G. V. Lier, J. C. Charlier, M. S. Dresselhaus, R. Saito, Y. A. Kim, T. Hayashi, H. Muramatsu, M. Endo, M. A. Pimenta: Resonance {Raman} study of linear carbon chains formed by the heat treatment of double-wall carbon nanotubes, Phys. Rev. B 73, 193408 (2006)
V. Georgakilas, D. Voulgaris, E. Vazquez, M. Prato, D. M. Guldi, A. Kukovecz, H. Kuzmany: Purification of {HiPCO} carbon nanotubes via organic functionalization, J. Am. Chem. Soc. 124, 14318 (2002)
M. Zheng, A. Jagota, E. D. Semke, B. A. Diner, R. S. Mclean, S. R. Lustig, R. Richardson, N. G. Tassi: {DNA}-assisted dispersion and separation of carbon nanotubes, Nature Mater. 2, 338 (2003)
M. Zheng, A. Jagota., M. S. Strano, A. P. Santos, P. Barone, S. G. Chou, B. A. Diner, M. S. Dresselhaus, R. S. Mclean, G. B. Onoa, G. G. Samsonidze, E. D. Semke, M. Ursey, D. J. Walls: {Structure}-based carbon nanotube sorting by sequence-dependent {DNA} assembly, Science 302, 1545 (2003)
D. A. Heller, E. S. Jeng, T. K. Yeung, B. M. Martinez, A. E. Moll, J. B. Gastala, M. S. Strano: {Optical} detection of {DNA} conformational polymorphism on single-walled carbon nanotubes, Science 311, 508 (2006)
J.-C. Charlier, M. Terrones, M. Baxendale, V. Meunier, T. Zacharia, N. L. Rupesinghe, W. K. Hsu, N. Grobert, H. Terrones, G. A. J. Amaratunga: {Enhanced} electron field emission in {B}-doped carbon nanotubes, Nano Lett. 2, 1191 (2002)
M. Doytcheva, M. Kaiser, M. Reyes-Reyes, M. Terrones, N. de Jonge: Electron emission from individual nitrogen-doped multi-walled carbon nanotubes, Chem. Phys. Lett. 396, 126 (2004)
M. Endo, Y. A. Kim, T. Hayashi, K. Nishimura, T. Matusita, K. Miyashita, M. S. Dresselhaus: {Vapor}-grown carbon fibers ({VGCFs}) – {Basic} properties and their battery applications, Carbon 39, 1287 (2001)
D. Y. Zhang, G. Y. Zhang, S. Liu, E. G. Wang, Q. Wang, H. Li, X. J. Huang: Lithium storage in polymerized carbon nitride nanobells, Appl. Phys. Lett. 79, 3500 (2001)
J. Kong, N. R. Franklin, C. W. Zhou, M. G. Chapline, S. Peng, K. J. Cho, H. J. Dai: Nanotube molecular wires as chemical sensors, Science 287, 622–625 (2000)
S. S. Wong, E. Joselevich, A. T. Woolley, C. L. Cheung, C. M. Lieber: Covalently functionalized nanotubes as nanometre-sized probes in chemistry and biology, Nature 394, 52–55 (1998)
P. Collins, K. Bradley, M. Ishigami, A. Zettl: Extreme oxygen sensitivity of electronic properties of carbon nanotubes, Science 287, 1801–1804 (2000)
F. Villalpando-Páez, A. H. Romero, E. Munoz-Sandoval, L. M. Martinez, H. Terrones, M. Terrones: {Fabrication} of vapor and gas sensors using films of aligned {CN}x nanotubes, Chem. Phys. Lett. 386, 137 (2004)
P. Calvert: Nanotube composites – a recipe for strength, Nature 399, 210 (1999)
A. Eitan, L. S. Schadler, J. Hansen, P. M. Ajayan, R. W. Siegel, M. Terrones, N. Grobert, M. Reyes-Reyes, M. Mayne, H. Terrones: Processing and thermal characterization of nitrogen doped {MWNT}/epoxy composites, in Proc. Tenth US–Japan Conf. Compos. Mater. (2002) pp. 634–640
B. Fragneaud, K. Masenelli-Varlot, A. González-Montiel, M. Terrones, J. Y. Cavaillé: {Efficient} coating of {N}-doped carbon nanotubes with polystayrene using atomic transfer radical polymerization, Chem. Phys. Lett. 419, 567 (2005)
M. Dehonor, K. Masenelli-Varlot, A. González-Montiel, C. Gauthier, J. Y. Cavaillé, H. Terrones, M. Terrones: Nanotube brushes: Polystyrene grafted covalently on {CN\rm x} nanotubes by nitroxide-mediated radical polymerization, Chem. Commun. 42, 5349 (2005)
B. Fragneaud, K. Masenelli-Varlot, A. {Gonz\'alez}-Montiel, M. Terrones, \mbox{J.-Y.} Cavaill\'e: Electrical behavior of polymer grafted nanotubes/polymer nanocomposites using {N}-doped carbon nanotubes, Chem. Phys. Lett. 444, 1 (2007)
D. M. Guldi, M. Marcaccio, D. Paolucci, F. Paolucci, M. Tagmatarchis, D. Tasis, E. Vasquez, M. Prato: Angew. Chem. Int. Ed. 42, 4206 (2003)
K. Jiang, L. S. Schadler, R. W. Siegel, X. J. Zhang, H. F. Zhang, M. Terrones: Protein immobilization on carbon nanotubes via a two-step process of diimide-activated amidation, J. Mater. Chem. 14, 37 (2004)
K. Jiang, A. Eitan, L. S. Schadler, P. M. Ajayan, R. W. Siegel, N. Grobert, M. Mayne, M. Reyes-Reyes, H. Terrones, M. Terrones: Selective attachment of gold nanoparticies to nitrogen-doped carbon nanotubes, Nano Lett. 3, 275 (2003)
A. Zamudio, A. L. ElÃas, J. A. RodrÃguez-Manzo, F. LÏŒpez-UrÃas, G. RodrÃguez-Gattorno, F. Lupo, M. Rühle, D. J. Smith, H. Terrones, D. DÃaz, M. Terrones: Efficient anchoring of silver nanoparticles on {N}-doped carbon nanotubes, Small 2, 346 (2005)
X. Leprό, Y. {Vega-Cant\'u}, F. J. Rodr\'iguez-Mac\'ias, Y. Bando, D. Golberg, M. Terrones: Production and characterization of co-axial nanotube junctions and networks of {CNx/CNT}, Nano Letters 7, 2220 (2007)
J. L. Carrero-Sánchez, A. L. ElÃas, R. Mancilla, G. ArellÃn, H. Terrones, J. P. Laclette, M. Terrones: Biocompatibility and toxicological studies of carbon nanotubes doped with nitrogen, Nano Lett. 6, 1609 (2006)
D. B. Warheit, B. R. Laurence, K. L. Reed, D. H. Roach, G. A. M. Reynolds, T. R. Webb: Comparative pulmonary toxicity assessment of single-wall carbon nanotubes in rats, Toxicol. Sci. 77, 117 (2004)
A. L. Elias, J. Carrero-Sánchez, H. Terrones, M. Endo, J. Laclette, M. Terrones: Comparative viability studies of pure carbon and nitrogen-doped multi walled carbon nanotube with amoeba cells: From amoebicidal to biocompatible structures, Small 3, 1723 (2007)
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Terrones, M., Filho, A.G.S., Rao, A.M. (2007). Doped Carbon Nanotubes: Synthesis, Characterization and Applications. In: Jorio, A., Dresselhaus, G., Dresselhaus, M.S. (eds) Carbon Nanotubes. Topics in Applied Physics, vol 111. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-72865-8_17
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