Abstract
MTBE and other fuel oxygenates threaten the water sources for drinking water production. Due to their persistence in the environment, these substances pass through the subsoil unchanged and thus are not reliably retained by riverbank filtration. Conventional drinking water treatment technology—i.e., aeration and adsorption on activated carbon—are not able to remove them in a feasible manner. New adsorption materials show better performance but high costs and low availability prevent their use in drinking water production. Chemical oxidation by advanced oxidation technology (i.e., ozone/H2O2 or UV-induced advanced oxidation processes) is most likely able to eliminate MTBE and other ethers, however, only with high expenses. Nanofiltration might be an option since the retention by nanofiltration membranes is quite high. However, for the production of drinking water, the resulting water has to be further conditioned in order to meet drinking water standards. In this book chapter the treatment technologies currently available for water treatment are illuminated in detail on their potential for removing MTBE and other fuel oxygenates from water.
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References
McKinnon RJ, Dyksen JE (1984) J Am Water Works Assoc 76:42
Chang DPY, Last JA (1998) J Environ Eng 124:910
Juhler RK, Felding G (2000) Water Air Soil Pollut 149:145
Ayotte JD, Argue DM, McGarry FJ (2005) Environ Sci Technol 39:9
Brown JS, Bay SM, Greenstein DJ, Ray WR (2001) Mar Pollut Bull 42:957
Dale MS, Koch B, Losee RF, Crofts EW, Davis MK (2000) J Am Water Works Assoc 92:42
Klinger J, Stieler C, Sacher F, Brauch H-J (2002) J Environ Monit 4:276
Lethbridge G (2000) Petrol Rev 54:50
Schmidt TC, Haderlein SB (2000) Does the use of MTBE pose environmental prob-lems in Switzerland? Report for the Swiss Agency for Environment, Forests and Landscape AG 02–05
Schmidt TC, Morgenroth E, Schirmer M, Effenberger M, Haderlein SB (2001) Use and occurrence of fuel oxygenates in Europe. In: Diaz AF, Drogos DL (eds) Oxy-genates in Gasoline—Environmental Aspects. Am Chem Soc, Washington, DC, p 58
Sinclair M, Lightbody P (2001) Health Stream Australia 23:1
Nishigaki M, Komatsu M, Kankam-Yeboah K Kim M (2003) First European Conference on MTBE. Dresden, Germany
Simazaki D, Asami M Nishimura T, Kunikane S, Aizawa T, Magara Y (2006) Water Sci Technol Water Supply 6:47
Tufenkji N, Ryan JN, Elimelech M (2002) Environ Sci Technol 36:423A
Kühn W, Müller UJ (2000) J Am Water Works Assoc 92:60
Achten C, Kolb A, Püttmann W (2002) Environ Sci Technol 36:3662
Schmidt CK (2006) Database on the behaviour of organic trace compounds during riverbank filtration. Exportorientierte F&E auf dem Gebiet der Wasserver- und -entsorgung. Technologiezentrum Wasser, Karlsruhe, Germany
Mitani MM, Keller AA, Bunton CA, Rinker RG, Sandall OC (2002) J Hazard Mater B89:197
Cater SR, Dussert BW, Megonnel N (2000) Pollut Eng 32:36
Effenberger M, Löbel E, Noack T, Schirmer M (2001) Altlasten Spektrum 4:177
Fiorenza S, Suarez MP, Rifai HS (2002) J Environ Eng 128:773
Kane SR, Beller HR, Legler TC, Happel AM (2002) Soil Sediment Contam 11:448
Bradley PM, Landmeyer JE, Chapelle FH (2001) Environ Sci Technol 35:658
Klinger J, Sacher F, Brauch H-J (2002) Wasser Abwasser gwf 143:166
Baus C, Hung H-W, Sacher F, Fleig M, Brauch H-J (2005) Acta Hydrochim Hydrobiol 33:118
Schmidt TC, Schirmer M, WeiE H, Haderlein SB (2004) J Contam Hydrol 70:173
Sutherland J, Adams C, Kekobad J (2004) Water Res 38:193
Stocking AJ, Rodriguez R, Flores AE, Creek D, Davidson J, Kavanaugh MC (2000) Treatment technologies for removal of methyl tertiary butyl ether (MTBE) from drinking water: air stripping, advanced oxidation processes, granular activated car-bon, synthetic resin sorbents. Report #NWRI-99-08. The California MTBE Research Partnership, Fountain Valley, California
Safarzadeh-Amiri A (2001) Water Res 35:3706
Karpel del Leitner N, Papailhou A-L, Croue J-P, Peyrot J, Dore M (1994) Ozone Sci Eng 16:41
Liang S, Palencia LS, Yates RS, Davis MK, Bruno J-M, Wolfe RL (1999) J Am Water Works Assoc 91:104
Sahle-Demessie E, Richardson T, Almquist CB, Pillai UR (2002) J Environ Eng 128:782
Wagler JL, Malley JP Jr (1994) J New Engl Water Works Assoc 108:236
Wilhelm MJ, ASCE AM, Adams VD, Curtis JG, Middlebrooks EJ, ASCE M (2002) J Environ Eng 128:813
Ramakrishnan B, Sorial GA, Speth TF, Clark P, Zaffiro A, Patterson C et al. (2004) J Air Waste Manage Assoc 54:529
Keller AA, Sandall OC, Rinker RG, Mitani MM, Bierwagen BG, Snodgrass MJ (2000) Ground Water Monit Remed 20:114
Sutherland J, Adams C, Kekobad J (2005) J Environ Eng 131:623
Reetz B, Hofmeister CR (2001) Upflow 27:10
Mackay D, Shiu WY, Ma KC (1992) Monoaromatic hydrocarbons, chlorobenzenes and PCB’s. In: Illustrated Handbook of Physical-Chemical Properties and Environ-mental Fate for Organic Chemicals. Lewis, Chelsea, MI, USA
Mackay D, Shiu WY, Ma KC (1993) Volatile organic chemicals. In: Illustrated Hand-book of Physical-Chemical Properties and Environmental Fate for Organic Chemicals. Lewis, Chelsea, MI, USA
USEPA (1998) Oxygenates in water: critical information and research needs. Report #EPA/600/R-98/048
Squillace PJ, Pankow JF, Kortes NE, Zogorski JS (1998) Environmental behavior and fate of methyl tert-butyl ether (MTBE) Report. US Department of the Interior – US Geological Survey – National Water Quality Assessment Program (NAWQA), USA
Howard PH, Sage GW, Jarvis WF, Gray DA (1991) Handbook of environmental fate and exposure data for organic chemicals, 2nd edn. Lewis, Chelsea, MI
Robbins GA, Wang S, Stuart JD (1993) Anal Chem 65:3113
Baehr AL, Stackelberg PE, Baker RJ (1999) Water Resour Res 35:127
Bierwagen BG, Keller AA (2001) Environ Toxicol Chem 20:1625
Davis SW, Powers SE (2000) J Environ Eng 126:354
Crittenden J (1986) J WPCF 58:312
Crittenden JC, Berrigan JK, Hand DW, Lykins B (1987) J Environ Eng 113:24
Marcus P (2005) PhD Thesis, TU Dresden, Germany
Yu L, Adams C, Ludlow D (2005) J Environ Eng 131:983
Hung H-W, Lin T-F, Baus C, Sacher F, Brauch H-J (2005) Environ Technol 26:1371
Suffet IHM, Shih TC et al (2000) Sorption for removing methyl tertiary butyl ether (MTBE) from drinking water. Report. University of California Toxic Substances Re-search & Teaching Program (UC TSR&TP)
Knappe DRU, Rossner Campos AA (2005) Water Sci Technol Water Supply 5:83
Shih TC, Wangpaichitr M, Suffet IHM (2003) Water Res 37:375
Bi E, Haderlein SB, Schmidt TC (2005) Water Res 39:4164
Anderson MA (2000) Environ Sci Technol 34:725
Shih TC, Wangpaichitr M, Suffet IHM (2005) J Environ Eng 131:450
Lin SH, Wang CS, Chang CH (2005) Ind Eng Chem Res 41:4116
Kolb A, Püttmann W (2005) Environ Pollut 140:294
Baus C, Sacher F, Brauch H-J (2003) First European Conference on MTBE, Dresden, Germany
Baus C, Sacher F, Brauch H-J (2005) Ozone Sci Eng 27:27
Lin T-F, Liu C-L, Yang F-C, Hung H-W (2003) Water Res 37:21
Staehelin J, Hoigné J (1982) Environ Sci Technol 16:676
Safarzadeh-Amiri A (2006) Ozone Sci Eng 24:55
Acero JL, Haderlein SB, Schmidt TC, Suter MJ-F, von Gunten U (2001) Environ Sci Technol 35:4252
Mofidi AA, Min JH, Palencia LS, Coffey BM, Liang S, Green JF (2002) Task 2.1: Advanced oxidation processes and UV photolysis for treatment of drinking water. Report. California Energy Commission Sacramento, California, USA
Liang S, Yates RS, Davis DV, Pastor SJ, Palencia LS, Bruno J-M (2001) J Am Water Works Assoc 93:110
Dionysiou DD, Weavers L, Choi W (2004) AEESP-ACS Symposium (Division of En-vironmental Chemistry) 228th ACS National Meeting, Philadelphia, USA
Baus C, Sona M, Brauch H-J (2006) 4th International Conference on Oxidation Tech-nologies for Water and Wastewater Treatment, Goslar, Germany
Kerfoot WB (2002) Soil Sediment Contam 11:449
Kerfoot WB, LeCheminant P (2002) Soil Sediment Contam 11:944
Buxton G, Greenstock C, Helman W, Ross A (1988) J Phys Chem Ref Data 17:513
Eibenberger J (1980) PhD Thesis, Vienna University, Austria
O’Shea KE, Kim DK, Cooper WJ, Wu T, Mezyk SP (2002) Radiat Phys Chem 65:343
Chang PBL, Yuoung TM (2000) Water Res 34:2233
Mezyk SP, Cooper WJ, Bartels DM, O’Shea KE, Wu T (2001) J Phys Chem 105:3521
Onstein P, Stefan M, Bolton JR (1999) J Adv Oxidat Technol 5:231
Hardison DR, Cooper WJ, Stephen PM, Bartels DM (2002) Radiat Phys Chem 65:309
Hoigne J, Bader H (1983) Water Res 17:173
Gordon S, Schmidt KH, Hart EI (1977) J Phys Chem 81:104
Burbano A, Dionysiou DD, Suidan MT, Richardson T (2005) Water Res 39:107
Adams GE, Boag JW, Currant J, Michael BD (1965) Trans Faraday Soc 61:1417
Willson RL, Greenstock CL, Adams GE, Wagemann R, Dorfman LM (1971) Int J Ra-diat Phys Chem 3:211
Fischer MM, Hamill WH (1973) J Phys Chem 77:717
Baxendale JH, Khan AA (1969) Int J Radiat Phys Chem 1:11
Getoff N, Schwoerer F, Markovic VM, Sehested K, Nielsen SO (1971) J Phys Chem 75:749
Krakjic I (1967) Kinetics of OH radical reactions in radiolysis, photolysis, and the Fenton system. In: Johnson GRA, Scholes G (eds) The chemistry of ionization and excitation. Taylor and Francis Ltd, London, p 303
Xu X-R, Li H-B, Gu J-D (2006) Chemosphere 63:254
Zang Y, Farnood R (2005) Chem Eng Sci 60:1641
Salari D, Daneshvar N, Aghazadeh F, Khataee AR (2005) J Hazard Mater 125:205
Klauson D, Preis S, Portjanskaja E, Kachina A, Kallas J (2004) Environ Technol 26:653
Zang Y, Farnood R (2006) Top Catal 37:91
Zhou H, Smith DW (2001) Can J Civ Eng 28(1):49
Trueb E, Hoigne J, Masschelein W (2006) 8th Ozone World Congress, Zurich, Switzerland
Speth TF, Swanson G (2002) Demonstration of the HiPOx advanced oxidation tech-nology for the treatment of MTBE-contaminated groundwater. Report #EPA/600/R- 02/094. National Risk Management Research Laboratory US EPA, Cincinnati, Ohio
Whisman CB, Herlihy P (2004) Soil Sediment Contam 13:208
Gurol MD, Garoma T, Lorraine G (2005) 2nd IUVA World Conference. Whistler, Canada
Garoma T, Gurol MD (2006) J Environ Eng 132:1404
Graham JL, Striebich R, Patterson CL, Radha Krishnan E (2004) Chemosphere 54:1011
Garoma T, Gurol MD (2004) Environ Sci Technol 38:5246
Cater SR, Stefan MI, Bolton JR, Safarzadeh-Amiri A (2000) Environ Sci Technol 34:659
Stefan MI, Mack J, Bolton JR (2000) Environ Sci Technol 34:650
Leong LYC, Drago JA, Dial CE, Sun PT, Pierce D (2000) Water Quality Technology Conference. Salt Lake City, Utah, USA
Hung CH (2006) Water Sci Technol Water Supply 6:77
Burbano A, Dionysiou DD, Richardson TL, Suidan MT (2002) J Environ Eng 128:799
Andreozzi R, Caprio V, Insola A, Marotta R (1999) Catal Today 53:51
Kang J-W, Hung H-M, Lin A, Hoffmann MR (1999) Environ Sci Technol 33:3199
Kim DK, O’Shea KE, Cooper WJ (2002) J Environ Eng 128:806
Lifka J, Ondruschka B (2002) Chem Eng Technol 74:291
Kang J-W, Hoffmann MR (1998) Environ Sci Technol 32:3194
Hsieh L-L, Lin Y-L, Wu C-H (2004) Water Res 38:3627
Cooper WJ, Nickelsen MG, Mezyk SP, Leslie G, Tornatore PM, Hardison W (2002) Radiat Phys Chem 65:451
Huang K-C, Couttenye RA (2002) Soil Sediment Contam 11:447
Kelley KL, Marley MC, Sperry KL (2002) AEHS Contam Soil Sediment & Water p 36
Damm JH, Hardacre C, Kalin RM, Walsh KP (2002) Water Res 36:3638
Lien H-L, Zhang W (2002) J Environ Eng 128:791
Kasprzyk-Hordern B, Andrzejewski P, Nawrocki J (2005) Ozone Sci Eng 27:301
von Gunten U, Hoigne J (1994) Environ Sci Technol 28:1234
von Gunten U, Driedger A, Gallard H, Salhi E (2001) Water Res 35:2095
Hoigne J (1994) Water Sci Technol Water Supply 12:187
Hoigne J (1998) Chemistry of aqueous ozone and transformation of pollutants by ozonation and advanced oxidation processes. In: Hrubec J (ed) The Handbook of Environmental Chemistry, vol 5. part C. Quality and Treatment of Drinking Water II. Springer, Berlin Heidelberg New York
Sacher F, Schmidt W, Böhme U, Brauch H-J (1997) gwf Wasser Abwasser 138:199
European Union (1998) Council Directive 98/83/EC
Bolton JR, Bircher KG, Tumas W, Tolman CA (2001) Pure Appl Chem 76:627
Naraghi K, Lenz M, Wong W, Yulinski W (2003) AWWA Conference on Membrane Technology, Atlanta, Georgia
Lipp P (2006) Was können Membranverfahren leisten? In: Organische Spurenstoffe in der Wasserversorgung. Schriftenreihe des Technologiezentrum Wasser Bd30, Karlsruhe, p 139
Keller AA, Bierwagen BG (2001) Environ Sci Technol 35:1875
Urkiaga A, Bolano N, De Las Fuente L (2002) Desalination 149:55
Vane LM, Alvarez FR, Mullins B (2001) Environ Sci Technol 35:391
Gullick RW, LeChevallier MW (2000) J Am Water Works Assoc 92:100
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Baus, C., Brauch, HJ. (2007). Removal of MTBE and Other Fuel Oxygenates During Drinking Water Treatment. In: Barceló, D. (eds) Fuel Oxygenates. The Handbook of Environmental Chemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-72641-8_12
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DOI: https://doi.org/10.1007/978-3-540-72641-8_12
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