The Dirac equation is a fundamental wave equation that satisfies the requirements of the special theory of relativity. Shortly after the appearance of the ► Schrodinger equation, several physicists attempted to extend it to the relativistic domain. The result — known as the Klein-Gordon-equation ► relativistic quantum mechanics — was however unable to describe ► electrons correctly. Paul A.M. Dirac realized that the formal structure of the Schrodinger equation, the form Hψ = i ℏ∂ψ/∂t, had to be retained also in a relativistic theory, implying that the ► Hamilton operator must be of the first order in the space derivatives. By “playing around with mathematics” he derived in late 1927 a wave equation which was linear in both space and time derivatives. For a free electron he wrote it as (W/c + α,i.p,/i. + βm 0 c)ψ = 0, where the quantities α and β were 4×4 matrices. In later literature the matrices were often designated γμ(μ = 1, 2, 3,4).
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Primary Literature
P. A. M. Dirac: The Quantum Theory of the Electron. Proceedings of the Royal Society of London A 117, 610–624; A 118, 351–361 (1928)
P. A. M. Dirac: The Principles of Quantum Mechanics (Clarendon, Oxford 1930)
Secondary Literature
H. Kragh: Dirac. A Scientific Biography (Cambridge University Press, Cambridge 1990)
J. Mehra, H. Rechenberg: The Historical Development of Quantum Theory. (Springer, New York 2000, Vol. 6, Part 1)
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Kragh, H. (2009). Dirac Equation. In: Greenberger, D., Hentschel, K., Weinert, F. (eds) Compendium of Quantum Physics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-70626-7_54
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