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Chirped molecular vibration after impulsive Raman excitation in a stilbene derivative molecule in solution

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Ultrafast Phenomena XV

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 88))

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Abstract

The vibrational dynamics in 4-methoxy-4′-nitrostilbene in a condensed phase was studied by femtosecond pump-probe spectroscopy and quantum-chemical calculation. Transient changes in absorbance due to bleaching exhibit oscillations reflecting chirped molecular vibrational on the potential surface.

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Author information

Authors and Affiliations

  1. Department of Physics, Faculty of Science, University of Tokyo, Hongo 7-3-1, Bunkyoku, Tokyo, 113-0033, Japan

    T. Kobayashi

  2. Department of Applied Physics and Chemistry and Institute for Laser Science, University of Electro-Communications, 1-5-1 Chofugaoka, Chofu, Tokyo, 182-8585, Japan

    T. Kobayashi & I. Iwakura

  3. Institute of Laser Engineering, Osaka University, 2-6 Yamada-oka, Suita, Osaka, 565-0971, Japan

    T. Kobayashi

  4. Department of Electrophysics, National Chiao Tung University, Hsinchu, 300, Taiwan

    T. Kobayashi & A. Yabushita

  5. Laboratory for Optics and Biosciences Ecole polytechnique, 91128, Palaiseau Cedex, France

    A. Colonna

  6. Department of Physics, Faculty of Science, Science University of Tokyo, Shinjuku Ku, 1-3 Kagurazaka, Tokyo, 162-8601, Japan

    E. Tokunaga

Authors
  1. T. Kobayashi
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  2. A. Colonna
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  3. A. Yabushita
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  4. I. Iwakura
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  5. E. Tokunaga
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Editor information

Editors and Affiliations

  1. Steacie Institute for Molecular Sciences, National Research Council Canada, 100 Sussex Drive, Rm 2063, Ottawa, ON, K1A 0R6, Canada

    Paul Corkum

  2. Department of Chemistry & Biochemistry 215 UCB, University of Colorado, Boulder, Boulder, CO, 80309-0215, USA

    David M. Jonas

  3. Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6, Canada

    R. J. Dwayne. Miller

  4. School of Electrical & Computer Engineering, Purdue University, 1285 Elec. Eng. Bldg., West Lafayette, IN, 47907-1285, USA

    Andrew M. Weiner

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© 2007 Springer-Verlag Berlin Heidelberg

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Kobayashi, T., Colonna, A., Yabushita, A., Iwakura, I., Tokunaga, E. (2007). Chirped molecular vibration after impulsive Raman excitation in a stilbene derivative molecule in solution. In: Corkum, P., Jonas, D.M., Miller, R.J.D., Weiner, A.M. (eds) Ultrafast Phenomena XV. Springer Series in Chemical Physics, vol 88. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-68781-8_90

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