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Ultrafast Chelation Dynamics of Model Photoswitches: Cyclopentadienyl Manganese and Arene Chromium Tricarbonyl Derivatives with Pendant Sulfides

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Ultrafast Phenomena XV

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 88))

Abstract

The chelation dynamics of [Mn{η5-C5H4C(O)R}(CO)3] and [Cr{η6-C6H5C(O)R}(CO)3] (R=CH2(SCH3), CH(SCH3)2, C(SCH3)3) in solution were investigated on the picosecond timescale by UV-pump IR-probe transient absorption spectroscopy. Tailoring the side chain structure and solvent environment influences the reaction rates and chelation pathways.

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References

  1. (a) To, T. T.; Burkey T. J.; Heilweil E. J. “Time-Resolved Infrared Absorption Study of Cyclopentadienyl Manganese Tricarbonyl Derivatives: Chelation with Pendant Sulfides in Acetonitrile,” J. Phys. Chem. A 2006, in press. (b) Yeston J. S.; To T. T.; Burkey T. J.; Heilweil E. J. J. Phys. Chem. B 2004, 108, 4582. (c) Jiao, T.; Pang, Z.; Burkey, T. J.; Johnston, R. F.; Heimer, T. A.; Kleiman, V. D.; Heilweil, E. J. J. Am. Chem. Soc. 1999, 121, 4618.

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Author information

Authors and Affiliations

  1. Optical Technology Division, National Institute of Standards and Technology, Gaithersburg, Maryland, 20899-8443

    Tung T. To & Edwin J. Heilweil

  2. Department of Chemistry, University of Memphis, Campus Box 526060, Memphis, Tennessee, 38152-6060

    Charles B. Duke III & Theodore J. Burkey

Authors
  1. Tung T. To
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  2. Charles B. Duke III
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  3. Theodore J. Burkey
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  4. Edwin J. Heilweil
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Editor information

Editors and Affiliations

  1. Steacie Institute for Molecular Sciences, National Research Council Canada, 100 Sussex Drive, Rm 2063, Ottawa, ON, K1A 0R6, Canada

    Paul Corkum

  2. Department of Chemistry & Biochemistry 215 UCB, University of Colorado, Boulder, Boulder, CO, 80309-0215, USA

    David M. Jonas

  3. Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6, Canada

    R. J. Dwayne. Miller

  4. School of Electrical & Computer Engineering, Purdue University, 1285 Elec. Eng. Bldg., West Lafayette, IN, 47907-1285, USA

    Andrew M. Weiner

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© 2007 Springer-Verlag Berlin Heidelberg

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To, T.T., Duke, C.B., Burkey, T.J., Heilweil, E.J. (2007). Ultrafast Chelation Dynamics of Model Photoswitches: Cyclopentadienyl Manganese and Arene Chromium Tricarbonyl Derivatives with Pendant Sulfides. In: Corkum, P., Jonas, D.M., Miller, R.J.D., Weiner, A.M. (eds) Ultrafast Phenomena XV. Springer Series in Chemical Physics, vol 88. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-68781-8_84

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