Abstract
Most chemical reactions and all biological processes take place in solution. The solvent influences the energetics of chemical reactivity because the reactants, transition state, and products may be stabilized differently by the solvent, and it creates fluctuating external forces for the dynamics.
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Dobryakov, A.L., Ernsting, N.P., Gawelda, W., Bressler, C., Chergui, M. (2007). Observing molecular structure changes and dynamics in polar solution. In: Kühn, O., Wöste, L. (eds) Analysis and Control of Ultrafast Photoinduced Reactions. Chemical Physics, vol 87. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-68038-3_8
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DOI: https://doi.org/10.1007/978-3-540-68038-3_8
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