Abstract
Mössbauer investigations about iron atom redistribution in oxide films of zirconium alloys subjected to corrosion at 500°C in pure oxygen and water pair have been analysed. The alloys were also subjected to autoclave conditions at a pressure of 10.0 MPa and autoclave conditions at 350°C and at a pressure of 16.8 MPa, using distilled water and water with additives of lithium and fluorine. It is shown that, depending on the corrosion environment, various compounds of iron, such as α-Fe2O3, Fe3O4, and FeO, as solid solutions of iron in ZrO2 are formed in oxide films.
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Filippov, V.P., Petrov, V.I., Shikanova, Y.A. (2006). Mossbauer investigations of corrosion environment influence on Fe valence states in oxide films of zirconium alloys. In: Lippens, PE., Jumas, JC., Génin, JM.R. (eds) ICAME 2005. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-49853-7_7
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DOI: https://doi.org/10.1007/978-3-540-49853-7_7
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