Synthesis, Properties and Application of Conducting PPY Nanoparticles

Li, Xingui; Huang, Meirong; Xie, Yunbin

doi:10.1007/978-3-540-49661-8_22

Synthesis, Properties and Application of Conducting PPY Nanoparticles

Xingui Li⁴,
Meirong Huang⁴ &
Yunbin Xie⁴

Chapter

1594 Accesses
2 Citations

Abstract

The successful fabrication, various structure, unique properties, and wide application potential of novel conducting polypyrrole (PPY) nanoparticles and nanocomposites with an intrinsically electrical conductivity have been systematically reviewed. Wholly new pyrrole (PY) copolymer nanoparticles were synthesized by a chemical oxidative precipitation polymerization from 20 mol% PY and 80 mol% 4-sulfonic diphenylamine (SD) in HCl aqueous solution without any external stabilizer. Their structure and morphology were characterized by laser particle-size analyzer and transmission electron microscopy. Unique effects of polymerization temperature on the polymerization yield, particle size, and bulk electrical conductivity were systematically studied. The number-average diameter of the particles in water depends on the polymerization temperature from 0 to 25°C, reaching a minimum of 78 nm with an extremely low polydispersity index of 1.033 by laser particle-size analyzer. Dry particles exhibit much smaller size of around 10 nm based on a high-resolution transmission electron microscopy observation. The PY/SD (20/80) copolymer has a gradually increased conductivity from 1 × 10⁻⁴ to 5 × 10⁻³ S/cm with lowering polymerization temperature from 25 °C to 0°C. The relatively low purity, poor self-stability, and high cost of the nanoscale PPYs with intrinsic electroconductivity could be overcome by effortlessly incorporating a certain amount of SD comonomer as internal emulsifier during PY polymerization in emulsifier-free HCl aqueous solution.

This is a preview of subscription content, log in via an institution.

Chapter: USD 29.95; Price excludes VAT (USA)

eBook: USD 169.00; Price excludes VAT (USA)

Hardcover Book: USD 219.99; Price excludes VAT (USA)

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

References

Benabderrahmane, S., S. Bousalem, C. Mangeney, A. Azioune, M. J. Vaulay, M. M. Chehimi. Polymer 46: 1339 (2005).
Article CAS Google Scholar
Bhat, N.V., Y. B. Shaikh. J. Appl. Polym. Sci. 53: 187 (1994).
Article CAS Google Scholar
Pomposo, J.A., J. Rodriguez, H. Grande. Synth. Met. 104: 107 (1999).
Article CAS Google Scholar
Jager, E.W.H., E. Smela, O. Inganas. Science 290: 1540 (2000).
Article CAS PubMed Google Scholar
Susumu, K., T. Masahide. J. Electrochem. Soc. 149: A988 (2002).
Article Google Scholar
Lee, J.Y., D. Y. Kim, C. Y. Kim. Synth. Met. 74: 103 (1995).
Article CAS Google Scholar
Kiskan, B., A. Akar, N. Kizilcan, B. Ustamehmetoglu. J. Appl. Polym. Sci. 96: 1830 (2005).
Article CAS Google Scholar
Jang, J., J. H. Oh, G. D. Stucky. Angew. Chem. Int. Ed. 41: 4016 (2002).
Article CAS Google Scholar
Shi, G.X., R. Rouabhia, Z. X. Wang, L. H. Dao, Z. Zhang. Biomaterials 25: 2477 (2004).
Article CAS PubMed Google Scholar
Hong, S.H., B. H. Kim, J. Joo, J. W. Kim, H. J. Choi. Curr. Appl. Phys. 1: 447 (2001).
Article Google Scholar
He, Y.H., J. Y. Yuan, G. Q. Shi. J. Mater. Chem. 15: 859 (2005).
Article CAS Google Scholar
Wan, M.X., K. Huang, L. J. Zhang, Z. M. Zhang, Z. X. Wei, Y. S. Yang. Int. J. Nonlinear Sci. Numerical Simul. 3: 465 (2002).
CAS Google Scholar
Bocharova, V., A. Kiriy, H. Vinzelberg, I. Mönch, M. Stamm. Angew. Chem. Int. Ed. 44: 6391 (2005).
Article CAS Google Scholar
Jérôme, C. R. Jérôme. Angew. Chem. Int. Ed. 37: 2488 (1998).
Article Google Scholar
Zhong, W.B., S. M. Liu, X. H. Chen, Y. X. Wang, W. T. Yang. Macromolecules 39: 3224 (2006).
Article CAS Google Scholar
Johnson, B.J.S., J. H. Wolf, A. S. Zalusky, M. A. Hillmyer. Chem. Mater. 16: 2909 (2004).
Article CAS Google Scholar
Ikegame, M., K. Tajima, T. Aida. Angew. Chem. Int. Ed. 42: 2154 (2003).
Article CAS Google Scholar
Maeda, Y., F. Chiba, K. Iida, K. Totani, K. Ogino, T. Ishibashi, H. S. Nalwa, T. Watanabe. Electrochemistry 72: 430 (2004).
CAS Google Scholar
Cheng, D.N., H.B. Xia, H. S. O. Chan. Langmuir 20: 9909 (2004).
Article CAS PubMed Google Scholar
Yang, X.M., Y. Lu. Polymer 46: 5324 (2005).
Article CAS Google Scholar
Yang, X.M., T. Y. Dai, Y. Lu. Polymer 47: 441 (2006).
Article CAS Google Scholar
Xu, X.J., L. M. Gan, K. S. Siow, M. K. Wong. J. Appl. Polym. Sci. 91: 1360 (2004).
Article CAS Google Scholar
Jang, J., J. H. Oh. Adv. Funct. Mater. 15: 494 (2005).
Article CAS Google Scholar
Wang, H.X., T. Lin, A. Kaynak. Synth. Met. 151: 136 (2005).
Article CAS Google Scholar
Liu, Y., Y. Chu, L. K. Yang. Mater. Chem. Phys. 98: 304 (2006).
Article CAS Google Scholar
Men’shikova, A.Y., B. M. Shabsel’s, T. G. Evseeva. Russian J. Appl. Chem. 76: 822 (2003).
Article CAS Google Scholar
Chen, P.L., P. Gao, M. H. Liu. Polymer 47: 7446 (2006).
Article CAS Google Scholar
Yang, Y., M. Suzuki, H. Shirai, K. Hanabusa. Polym. Prepri. Japan 54(1) 1020 (2005).
Google Scholar
Wang, S.T., Y. H. Qin, S. Y. Zhai, L. H. Zhou, H. D. Xu, J. H. Li. Chem. J. Chinese Universities 25: 841 (2004).
Google Scholar
Khor, E., J. L. H. Whey. Carbohydrate Polym. 26: 183 (1995).
Article CAS Google Scholar
Wang, Z.X., C. Roberge, Y. Wan, L. H. Dao, R. Guidoin, Z. Zhang. J. Biomed. Mater. Res. 66A: 738 (2003).
Article CAS Google Scholar
Shi, G.X., M. Rouabhia, Z. X. Wang, L. H. Dao, Z. Zhang. Biomaterials 25: 2477 (2004).
Article CAS PubMed Google Scholar
Jiang, X., Y. Marois, A. Traoré, D. Tessier, L. H. Dao, R. Guidoin, Z. Zhang. Tissue Eng. 8: 635 (2002).
Article CAS PubMed Google Scholar
Almira, R., S. Wolfgang, R. Arunas. Colloids Surf. B. Biointerfaces 48: 159 (2006).
Article Google Scholar
Tarcha, P.J., L. Salvati, R. W. Johnson. Surf. Sci. Spectra 8: 312 (2001a).
Article CAS Google Scholar
Tarcha, P.J., L. Salvati, R. W. Johnson. Surf. Sci. Spectra 8: 323 (2001a).
Article CAS Google Scholar
Jang, J., Y. Nam, H. Yoon. Adv. Mater. 17: 1382 (2005).
Article CAS Google Scholar
Sonmez, H.B., G. Sonmez, B. F. Senkal, A. S. Sarac, N. Bicak. Synth. Met. 135–136: 807 (2003).
Article Google Scholar
Deng, J.G., Y. X. Peng, C. L. He, X. P. Long, P. Li, A. S. C. Chan. Polym. Int. 52: 1182 (2003).
Article CAS Google Scholar
Gangopadhyay, R., A. De. Eur. Polym. J. 35: 1985 (1999).
Article CAS Google Scholar
Mallouki, M., F. Tran-Van, C. Sarrazin, P. Simon, A. De, C. Chevrot, J. F. Fauvarque. 207th Meeting of the Electrochemical Society — Meeting Abstracts, 1677 (2005).
Google Scholar
Ham, H.T., Y. S. Choi, N. Jeong, I. J. Chung. Fluid Phase Equilibria 234: 6308 (2005).
Google Scholar
Liu, Y.C., C. E. Tsai, W. H. Chiu. 207th Meeting of the Electrochemical Society-Meeting Abstracts 1673 (2005).
Google Scholar
Liu, Y.C., H. T. Lee, Polymer 46: 10,727 (2005).
Article Google Scholar
Lee, E.S., J. H. Park, G. G. Wallace, H. B. You. Polym. Int. 53: 400 (2004).
Article CAS Google Scholar
Wang, E.B., Y. Lan, Y. H. Song, Y. L. Song, Z. H. Kang, L. Xu, Z. Li. Polymer 47: 1480 (2006).
Article Google Scholar
Weidlich, C., K.-M. Mangold, K. Juttner. Electrochim. Acta 47: 741 (2001).
Article CAS Google Scholar
Dall’Acqua, L., C. Tonin, A. Varesano, M. Canetti, W. Porzio, M. Catellani. Synth. Met. 156: 379 (2006).
Article Google Scholar
Pang, Y., N. Chen, L. Hong. Materials Research Society Symposium-Proceedings 635: C691 (2001).
Google Scholar
Li, X.G., R. F. Chen, M. R. Huang, M. F. Zhu, Q. Chen. J. Polym. Sci. Part A. Polym. Chem. 42: 2073 (2004a).
Article CAS Google Scholar
Li, X.G., M. R. Huang, M. F. Zhu. Polymer 45: 385 (2004b).
Article CAS Google Scholar
Kim, J.H., M. Chainey, M. S. El-Aasser, J. W. Vanderhoff. J. Polym. Sci. Part A: Polym. Chem. 30: 171 (1992).
Article CAS Google Scholar
Sunkara, H.B., J. M. Jethmalani, W. T. Ford. J. Polym. Sci. Part A: Polym. Chem. 32: 1431 (1994).
Article CAS Google Scholar
Li, X.G., Q. F. Lü, M. R. Huang. Chem. Eur. J. 12: 1349 (2006).
Article CAS Google Scholar
Kassim, A., Z. B. Basar, H. N. M. E. Mhamud. Proc. Indian Acad. Sci. (Chem Sci) 114(2) 155 (2002).
Article CAS Google Scholar
Li, X.G., H. J. Zhou, M. R. Huang, M. F. Zhu, Y. M. Chen. J. Polym. Sci. Part A: Polym. Chem. 42: 3380 (2004c).
Article CAS Google Scholar
Li, X.G., F. Wei, M.R. Huang, Y.B. Xie. J. Phys. Chem. B111: 5829 (2007).
Google Scholar

Download references

Author information

Authors and Affiliations

Key Laboratory of Advanced Civil Engineering Materials, College of Materials Science and Engineering, Tongji University, Shanghai, 200092, China
Xingui Li, Meirong Huang & Yunbin Xie

Authors

Xingui Li
View author publications
You can also search for this author in PubMed Google Scholar
Meirong Huang
View author publications
You can also search for this author in PubMed Google Scholar
Yunbin Xie
View author publications
You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xingui Li .

Editor information

Editors and Affiliations

Department of Chemical and Materials Engineering, College of Engineering, University of Cincinnati, Cincinnati, OH, 45221, USA
Donglu Shi
The Institute for Advanced Materials and Nano Biomedicine, Tongji University, Shanghai, 200092, China
Donglu Shi
Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai, 200240, China
Donglu Shi

Rights and permissions

Reprints and permissions

Copyright information

About this chapter

Cite this chapter

Li, X., Huang, M., Xie, Y. (2009). Synthesis, Properties and Application of Conducting PPY Nanoparticles. In: Shi, D. (eds) NanoScience in Biomedicine. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-49661-8_22

Download citation

DOI: https://doi.org/10.1007/978-3-540-49661-8_22
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-49660-1
Online ISBN: 978-3-540-49661-8
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)

Publish with us

Policies and ethics