This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Chapter 4-Reactions of nucleophiles and electrophiles with complexes
S.G. Davies, M.L.H Green, D.M. Mingos-Nucleophilic Addition to Organo-Transition Metal Cations Containing Unsaturated Hydrocarbon Ligands, Tetrahedron 34, 20, 1978.
D. Astruc, P. Michaud, A.M. Madonik, J.-Y. Saillard, R. Hoffmann-The Regiospecific Reaction of Nucleophiles with [FeII(ν5-cyclohexadienyl) (ν6-benzene)]+: a Frontier Orbital Controlled Route to [Fe0(ν4-cyclohexadiene) (ν6-benzene)], Nouv. J. Chim. 9, 41, 1985.
E.O. Fischer-On the Way to Metal Carbene and Carbyne Complexes, Adv. Organomet. Chem. 1, 14, 1976.
a) C.P. Casey, W.M. Miles-The Preparation of Methoxyalkyliron Complexes: Precursors of Secondary Carbeneiron Complexes, J. Organomet. Chem. 254, 333, 1983; see also ref. 20.11; b) B. Crociani, P. Uguagliati, U. Belluco-Steric Role of Aromatic Ring Ortho-Substituents in the Mechanism of Carbene Formation from Palladium(II) Arylisocyanide Complexes and Anilines, J. Organomet. Chem. 117, 189, 1976.
M.F. Semmelhack-Arene-Metal Complexes in Organic Synthesis, Annals New York Acad. Sci., 36, 1977; B.M. Trost Ed.-Comprehensive Organic Chemistry, Pergamon Press, 1991, Vol. 4, 517; J. Organomet. Chem. Library 1, 361, 1976.
M.F. Semmelhack et al.-Addition of Carbon Nucleophiles to Arene-Chromium Complexes, Tetrahedron 37, 3957, 1981; M.F. Semmelhack, A. Yamashita-J. Am. Chem. Soc. 102, 5926, 1980; G. Jaouen, A. Meyer, G. Simonneaux-J. Chem. Soc., Chem. Commun., 813, 1975.
H. Des Abbayes, M.-A. Boudeville-Alkylation of Arylacetic Ester by Phase-Transfer Catalysis and Sodium Hydride: Activation and Stereochemical Effects of the Cr(CO)3 Group, J. Org. Chem. 42, 4104, 1977.
A. Solladié-Cavallo, G. Soladié, E. Tsamo-Chiral Arene-Tricarbonyl-Chromium Complexes: Resolution of Aldehydes, J. Org. Chem. 44, 4189, 1979; M.C. Sénéchal-Tocquer, D. Sénéchal, J.-Y. Le Bihan, D. Gentric, B. Caro-Bull. Soc. Chim. Fr. 129, 121, 1992.
E.P. Kündig et al.-Thermodynamic Control of Regioselectivity in the Addition of Carbanions to Arene-Tricarbonyl-Chromium Complexes, J. Am. Chem. Soc. 111, 1804, 1989.
D. Astruc-Organo-Iron Complexes of Aromatic Compounds. Application in Organic Synthesis, Tetrahedron Report No 157, Tetrahedron 39, 4027, 1983.
A. Alexakis, F. Rose-Münch, E. Rose et al.-Resolution and Asymmetric Synthesis of Ortho-Substituted Benzaldehyde-Tricarbonyl-Chromium Complexes, J. Am. Chem. Soc. 114, 8288, 1992.
a) A.F. Cunningham Jr-Mechanism of Mercuration of Ferrocene: General Treatment of Electrophilic Substitution of Ferrocene Derivatives, Organometallics 16, 1114, 1997; b) J. Weber et al.-Density Functional Study of Protonated, Acetylated, and Mercurated Derivatives of Ferrocene: Mechanism of the Electrophilic Substitution Reaction, Organometallics 17, 4983, 1998.
Rights and permissions
Copyright information
© 2007 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
(2007). Reactions of Nucleophiles and Electrophiles with Complexes. In: Organometallic Chemistry and Catalysis. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-46129-6_6
Download citation
DOI: https://doi.org/10.1007/978-3-540-46129-6_6
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-46128-9
Online ISBN: 978-3-540-46129-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)