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Distinction between electrostatic and specific adsorption of anions on (hydr)oxide/electrolyte interfaces by application of a radiotracer technique

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Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 125))

Abstract

On the basis of the comparative radiotracer study of the adsorption of sulfate and pertechnetate ions on γ-Al2O3, it is shown that the application of the radiotracer technique allows us to distinguish specific and nonspecific adsorption without the knowledge and the use of quantitative data as to the extent of the adsorption or the surface area of the adsorbent. It is demonstrated that the study of the adsorption of the TcO4 - ion offers a tool for the investigation of electrostatic effects at the Al2O3/electrolyte interface.

Acknowledgement Financial support from the Hungarian Scientific Research Fund and the Ministry of Environmental Protection is acknowledged (OTKA grant T 031703).

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Correspondence to G. Horányi .

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Miklós Zrínyi Zoltán D. Hórvölgyi

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© 2004 Springer-Verlag

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Horányi, G., Joó, P. (2004). Distinction between electrostatic and specific adsorption of anions on (hydr)oxide/electrolyte interfaces by application of a radiotracer technique. In: Zrínyi, M., Hórvölgyi, Z. (eds) From Colloids to Nanotechnology. Progress in Colloid and Polymer Science, vol 125. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-45119-8_20

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  • DOI: https://doi.org/10.1007/978-3-540-45119-8_20

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-40658-7

  • Online ISBN: 978-3-540-45119-8

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