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Bifunctional Silicas with Immobilized Lignin

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Nanochemistry, Biotechnology, Nanomaterials, and Their Applications (NANO 2017)

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 214))

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Abstract

Silica/lignin biocomposites were obtained by impregnation of the modified pyrogenic silicas with water solutions of polymer. Modification of silica surface was carried out using liquid-phase and gas-phase treatment with alkoxyorganosilanes and hexamethyldisilazane, respectively. The silicas with methyl, amine, and silicon hydride groups in a mono- or bifunctional (methyl-hydride, methyl-amino, amino-hydride) surface layers were impregnated with kraft lignin and characterized using differential scanning calorimetry (DSC), attenuated total reflectance (ATR), Fourier transform infrared (FT-IR), and UV spectroscopies. The influence of nature and amount of silica surface functional groups on physicochemical properties of immobilized lignin has been studied. The data on the structure of the polymer layer and the nature of silica/lignin interactions are discussed.

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Acknowledgments

The research leading to these results has received funding from the People Programme (Marie Curie Actions) of the European Union’s Seventh Framework Programme FP7/2007-2013 under REA grant agreement no. PIRSES-GA-2013-612484.

Competing Interest

The authors declare that they have no competing interests.

Author information

Authors and Affiliations

  1. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Yulia Bolbukh, Stanislav Sevostianov & Valentin Tertykh

  2. Faculty of Chemistry, Maria Curie-Sklodowska University, Lublin, Poland

    Beata Podkoscielna, Dariusz Sternik & Barbara Gawdzik

  3. Department of Physics, National Technical University of Athens, Athens, Greece

    Panagiotis Klonos & Polycarpos Pissis

Authors
  1. Yulia Bolbukh
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  2. Stanislav Sevostianov
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  3. Beata Podkoscielna
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  4. Dariusz Sternik
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  5. Panagiotis Klonos
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  6. Polycarpos Pissis
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  7. Barbara Gawdzik
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  8. Valentin Tertykh
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Editor information

Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Leonid Yatsenko

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Bolbukh, Y. et al. (2018). Bifunctional Silicas with Immobilized Lignin. In: Fesenko, O., Yatsenko, L. (eds) Nanochemistry, Biotechnology, Nanomaterials, and Their Applications. NANO 2017. Springer Proceedings in Physics, vol 214. Springer, Cham. https://doi.org/10.1007/978-3-319-92567-7_26

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