A Critical Evaluation of Cathode Materials for Lithium-Ion Electric Vehicle Batteries

  • Robert ReinhardtEmail author
  • B. Amante García
  • Lluc Canals Casals
  • S. Gassó Domingo
Conference paper
Part of the Lecture Notes in Management and Industrial Engineering book series (LNMIE)


There has been an intensive research and development focus on lithium-ion batteries, which have revolutionized the electric vehicle market due to the batteries’ high energy and power density, longer lifespan, and increased safety than comparable rechargeable battery technologies. The performance of lithium-ion batteries is achieved by packaging design, electrolyte, and electrodes material’s selection. This study focuses on cathode materials as they currently need to overcome critical challenges. In fact, cathode materials affect energy density, rate capability and working voltage that led to the cathode currently costing twice as much as the anode. For this reason, this study reviews cathode materials for electric vehicle lithium-ion batteries under economic and environmental perspectives to optimize the batteries’ structures and properties. Findings reveal that presently there is no commercially installed battery that can satisfy both, economic and environmental concerns while offering an overall excellent performance.


Electric vehicle Lithium-ion Battery Cathode 



The authors would like to thank the Universitat Politècnica de Catalunya (UPC), the ReViBe project TEC2015-63899-C3-1-R funded by the Spanish government, the Ministerio de Economía y Competitividad y al Fondo Europeo de Desarrollo Regional (FEDER) TEC2015-63899-C3-1-R (MINECO/FEDER) and the scholarship program FI-DGR 2016 by Agència de Gestió de les Ajudes Unisersitàries i d’Investigació (AGAUR).


  1. Aguirre K, Eisenhardt L, Lim C et al (2012) Lifecycle analysis comparison of a battery electric vehicle and a conventional gasoline vehicle Accessed 24 Jan 2016
  2. Amine K, Kanno R, Tzeng Y (2014) Rechargeable lithium batteries and beyond: Progress, challenges, and future directions. MRS Bull 39:395–401. Scholar
  3. Amirault J, Chien J, Garg S et al (2009) The electric vehicle battery landscape : opportunities and challenges. Accessed 12 Feb 2016
  4. Armand M, Tarascon J-M (2008) Building better batteries. Nature 451:652–657. Scholar
  5. Barnett B, Rempel J, Ofer D et al (2010) PHEV battery cost assesment. Accessed 19 Dec 2015
  6. Bonges HA, Lusk AC (2016) Addressing electric vehicle (EV) sales and range anxiety through parking layout, policy and regulation. Transp Res Part A Policy Pract 83:63–73. Scholar
  7. Casals LC, García BA, Aguesse F, Iturrondobeitia A (2015) Second life of electric vehicle batteries: relation between materials degradation and environmental impact. Int J Life Cycle Assess 1–12. Scholar
  8. Cluzel C, Douglas C (2012) Cost and performance of EV batteries: final report for the committee on climate change. Accessed 3 Jan 2016
  9. Deng D (2015) Li-ion batteries: basics, progress, and challenges. Energy Sci Eng 3:385–418. Scholar
  10. Dinger A, Martin R, Mosquet X et al (2010) Batteries for electric cars - challenges, opportunities, and the outlook to 2020. Accessed 27 Jan 2016
  11. Etacheri V, Marom R, Elazari R et al (2011) Challenges in the development of advanced Li-ion batteries: a review. Energy Environ Sci 4:3243–3262. Scholar
  12. Frischknecht R (2011) Life cycle assessment of driving electric cars an scope dependent LCA models. In: 43. Ökobilanz-Diskussionsforum, Zürich: SwitzerlandGoogle Scholar
  13. Gaines L, Cuenca R (2000) Costs of lithium-ion batteries for vehicles. Energy 48:73. Scholar
  14. Gaines L, Nelson P (2009) Lithium Ion batteries: possible materials issues. Argonne National Laboratory, ArgonneGoogle Scholar
  15. Goodenough JB, Park K-SS (2013) The Li-ion rechargeable battery: a perspective. J Am Chem Soc 135:1167–1176. Scholar
  16. Hakimian a., Kamarthi S, Erbis S, et al (2015) Economic analysis of CNT lithium-ion battery manufacturing. Environ Sci Nano 2:463–476. Scholar
  17. Huat SL, Yonghuang Y, Tay AAO (2015) Integration issues of lithium-ion battery into electric vehicles battery pack. J Clean Prod. Scholar
  18. Liu C, Neale ZG, Cao G (2015) Understanding electrochemical potentials of cathode materials in rechargeable batteries. Mater Today 19:109–123. Scholar
  19. Lu L, Han X, Li J et al (2013) A review on the key issues for lithium-ion battery management in electric vehicles. J Power Sources 226:272–288. Scholar
  20. Majeau-Bettez G, Hawkins TR, Stromman AH (2011) Life cycle environmental assessment of lithium-ion and nickel metal hydride batteries for plug-in hybrid and battery electric vehicles. Environ Sci Technol 45:4548–4554. Scholar
  21. Manthiram A (2011) Materials challenges and opportunities of lithium ion batteries. J Phys Chem Lett 2:176–184. Scholar
  22. Navigant Research (2015) Advanced energy storage for automotive applications. Accessed 14 Jan 2016
  23. Nealer R, Reichmuth D, Anair D (2015) Cleaner cars from cradle to grave: how electric cars beat gasoline cars on lifetime global warming emissions. Union of Concerned Scientists, Cambridge (USA)Google Scholar
  24. Nelson PA, Gallagher KG, Bloom I, Dees DW (2011) modeling the performance and cost of lithium-ion batteries for electric-drive vehicles. 1–102.
  25. Nitta N, Wu F, Lee JT, Yushin G (2015) Li-ion battery materials: present and future. Mater Today 18:252–264. Scholar
  26. Notter DA, Gauch M, Widmer R et al (2010) Contribution of Li-ion batteries to the environmental impact of electric vehicles. Environ Sci Technol 44:6550–6556. Scholar
  27. Rempel J, Barnett B, Hyung Y (2013) PHEV battery cost assessment. Accessed 17 Dec 2015
  28. Saevarsdottir G, Tao P, Stefansson H, Harvey W (2015) Potential use of geothermal heat in lithium-ion battery production. World Geothermal Congress 2015. Melbourne, Australia, pp 1–6Google Scholar
  29. Sakti A, Michalek JJ, Fuchs ERH, Whitacre JF (2015) A techno-economic analysis and optimization of Li-ion batteries for light-duty passenger vehicle electrification. J Power Sources 273:966–980. Scholar
  30. Scrosati B, Garche J (2010) Lithium batteries: Status, prospects and future. J Power Sources 195:2419–2430. Scholar
  31. Shen PK, Wang C-Y, Jiang SP et al (2015) Electrochemical energy: advanced materials and technologies. CRC Press, Boca RatonCrossRefGoogle Scholar
  32. Tarascon J-M, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414:359–367. Scholar
  33. Thackeray MM, Wolverton C, Isaacs ED (2012) Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries. Energy Environ Sci 5:7854. Scholar
  34. Whittingham MS (2008) Materials challenges facing electrical energy storage. MRS Bull 33:411–419. Scholar
  35. Whittingham MS (2004) Lithium batteries and cathode materials. Chem Rev 104:4271–4301. Scholar
  36. Xu B, Qian D, Wang Z, Meng YS (2012) Recent progress in cathode materials research for advanced lithium ion batteries. Mater Sci Eng R Reports 73:51–65. Scholar
  37. Xu J, Dou S, Liu H, Dai L (2013) Cathode materials for next generation lithium ion batteries. Nano Energy 2:439–442. Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2019

Authors and Affiliations

  • Robert Reinhardt
    • 1
    Email author
  • B. Amante García
    • 1
  • Lluc Canals Casals
    • 2
  • S. Gassó Domingo
    • 1
  1. 1.Department of Project and Construction EngineeringUniversitat Politècnica de CatalunyaTerrassaSpain
  2. 2.Energy System Analytics Group, Institut de Recerca en Energia de CatalunyaSant Adrià de BesòsSpain

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