Skip to main content

Facile Synthesis and Characterisation of Nanocomposite Doped Chitosan—Polystyrene Polymer Blends

  • Conference paper
  • First Online:
Book cover Advanced Manufacturing and Materials Science

Abstract

This study is an attempt to establish a novel technique for the synthesis of Chitosan (CS)—Polystyrene (PS) blends to achieve specific combination of physical properties. The CS–PS blends were synthesized from homogenous solutions at different ratios of the polymers. An attempt is made to improve their functionality by doping them with mixed metal oxide nanocomposites of ZnO–TiO2 synthesized by an electrochemical thermal technique. The obtained nanocomposite doped polymer blends are appropriately characterized by Fourier Transform Infrared Spectroscopy (FT-IR) to confirm functional groups. It indicates the formation of blends due to intermolecular hydrogen bonding between the 2 components. SEM images substantiate the presence of nanoparticles in the blends. Thermal stability of these polymers is analyzed by Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). X-ray diffraction (XRD) analysis confirms the amorphous nature of the synthesized blends. These studies reveal that the obtained blends could have potential physiochemical applications as adsorbents for dyes in the treatment of effluent water from textile industries.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Pfaendner R (2010) Photo-oxidation of polypropylene/montmorillonite nanocomposites. 1. Influence of nanoclay and compatibilizing agent. Polym Degrad Stab 95:369–373

    Article  CAS  Google Scholar 

  2. Stejskal J, Sapurina I, Trchov´a M, Konyushenko EN (2008) oxidation of aniline: polyaniline granules, nanotubes, and oligoaniline microspheres. Macromolecules 41:3530

    Article  CAS  Google Scholar 

  3. Wei Y (2001) Nonclassical or reactivation chain polymerization: a general scheme of polymerization J Chem Educ 78:551

    Article  CAS  Google Scholar 

  4. Ciric-Marjanovic G, Trchova M, Stejskal J (2008) Theoretical study of the oxidative polymerization of aniline with peroxydisulfate: tetramer formation. Int J Quantum Chem 108:318

    Article  CAS  Google Scholar 

  5. Tzou K, Gregory RV (1992) Kinetic study of the chemical polymerization of aniline in aqueous solutions. Synth Met 47:267

    Article  CAS  Google Scholar 

  6. Wei Y, Sun Y, Tang X (1989) Effects of p-aminodiphenylamine on electrochemical polymerization of aniline. J Phys Chem 93:4878

    Article  CAS  Google Scholar 

  7. Ortiz RP, Facchetti A, Marks TJ (2010) High-k organic, inorganic, and hybrid dielectrics for low-voltage organic field-effect transistors. Chem Rev 110:205

    Article  CAS  Google Scholar 

  8. Chiang CK, Popielarz R (2002) Polymer composites with high dielectric constant. Ferroelectrics 1:275

    Article  Google Scholar 

  9. Cao Y, Smith P, Heeger AJ (1993) Counter-ion induced processibility of conducting polyaniline. Synth Met 55–57:3514–3519

    Article  Google Scholar 

  10. Winie T, Jamal A, Hanif NSM, Shahril NSM (2014) Hexanoyl chitosan-polystyrene blend based composite polymer electrolyte with surface treated TiO2 fillers. Key Eng Mater 594–595:656–660

    Google Scholar 

  11. Yu CL et al (2012) Sci China Chem 55:1802–1810

    Google Scholar 

  12. Sang CK et al (2003) Physical 103:130

    Google Scholar 

  13. Waghmare VG, Kariya KP, Paliwal LJ (2011) J Mater Sci Eng B1:485

    Google Scholar 

  14. Munnawar et al (2017) Synergistic effect of chitosan-zinc oxide hybrid nanoparticles on antibiofouling and water disinfection of mixed matrix polyethersulfone nanocomposite membranes. Carbohydr Polym. http://dx.doi.org/10.1016/j.carbpol.2017.08.036

  15. Dhanavel et al (2014) Photocatalytic activity of Chitosan/ZnO nanocomposites for degrading methylene blue. Int J chemtech 1880–1882

    Google Scholar 

  16. Hanif NSM, Shahril NSM, Azmar A, Winie T (2015) Studies on the effect of acid treated TiO2 on the electrical and tensile properties of hexanoyl chitosan-polystyrene-LiCF3SO3 composite polymer electrolytes. In: American Institute of Physics Conference Proceedings 1674, 020028-1-020028-7

    Google Scholar 

Download references

Acknowledgements

Authors thank the Principal, St Aloysius College (Autonomous), Mangalore for providing the Laboratory and experimental facilities for the research work carried out.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Naveen Praveen Mascarenhas .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer International Publishing AG, part of Springer Nature

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Mascarenhas, N.P., Goveas, J.J., Gonsalves, R.A., Shetty, T.C.S., Crasta, V. (2018). Facile Synthesis and Characterisation of Nanocomposite Doped Chitosan—Polystyrene Polymer Blends. In: Antony, K., Davim, J. (eds) Advanced Manufacturing and Materials Science. Lecture Notes on Multidisciplinary Industrial Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-76276-0_26

Download citation

Publish with us

Policies and ethics