Abstract
Mg alloys attract more and more attentions for biomedical applications. Mg-Gd alloys were designed as biodegradable implant materials which combine favorable mechanical and corrosion properties. In this work, the microstructure and mechanical properties of binary Mg-2Gd, ternary Mg-2Gd-(Ag, Ca) and quaternary Mg-2Gd-2Ag-0.4Ca alloys were investigated. The alloys were prepared by permanent mould casting. The results show that the additions of Ag and Ca had significant influences on the microstructure and mechanical properties of Mg-2Gd alloy. Ag and Ca additions affect the formation of second phases. A quaternary Mg-Gd-Ag-Ca second phase was found in the quaternary alloy. Both the hardness and tensile yield strength were improved by adding Ag and Ca to 2 wt% Gd-containing alloys due to grain refinement and formation of different intermetallic phases (IMPs). Furthermore, the addition of Ag and Ca can apparently enhance the age hardening of Mg-2Gd alloy.
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References
Staiger MP, Pietak AM, Huadmai J, Dias G (2006) Magnesium and its alloys as orthopedic biomaterials: a review. Biomaterials 27:34-1728
Chen Y, Xu Z, Smith C, Sankar J (2014) Recent advances on the development of magnesium alloys for biodegradable implants. Acta Biomater 10:4561–4573
Li N, Zheng Y (2013) Novel magnesium alloys developed for biomedical application: a review. J Mater Sci Technol 29:489–502
Song GL (2007) Control of biodegradation of biocompatable magnesium alloys. Corros Sci 49:1696–1701
Yang L, Huang Y, Feyerabend F, Willumeit R, Mendis C, Kainer KU, Hort N (2013) Microstructure, mechanical and corrosion properties of Mg–Dy–Gd–Zr alloys for medical applications. Acta Biomater 9:8499–8508
Hou L, Li Z, Pan Y, Du L, Li X, Zheng Y, Li L (2014) In vitro and in vivo studies on biodegradable magnesium alloy. Prog Nat Sci Mater Int 24:466–471
Hänzi AC, Gunde P, Schinhammer M, Uggowitzer PJ (2009) On the biodegradation performance of an Mg–Y–RE alloy with various surface conditions in simulated body fluid. Acta Biomater 5:162–171
Gunde P, Hänzi AC, Sologubenko AS, Uggowitzer PJ (2011) High-strength magnesium alloys for degradable implant applications. Mater Sci Eng A 528:1047–1054
Feyerabend F, Fischer J, Holtz J, Witte F, Willumeit R, Drucker H, Vogt C, Hort N (2010) Evaluation of short-term effects of rare earth and other elements used in magnesium alloys on primary cells and cell lines. Acta Biomater 6:1834–1842
Atrens A, Liu M, Zainal Abidin NI (2011) ‘Corrosion mechanism applicable to biodegradable magnesium implants. Mater Sci Eng B 176:1609–1636
Gu X-N, Zheng Y-F (2010) A review on magnesium alloys as biodegradable materials. Front Mater Sci Chin 4:111–115
Persaud-Sharma D, Mcgoron A (2012) Biodegradable magnesium alloys: a review of material development and applications. J Biomimetics, Biomater Tissue Eng 12:25–39
Tie D, Feyerabend F, Muller WD, Schade R, Liefeith K, Kainer KU, Willumeit R (2013) Antibacterial biodegradable Mg-Ag alloys. Eur Cells Mater 25:284–298
Salahshoor M, Guo Y (2012) Biodegradable orthopedic magnesium-calcium (Mg–Ca) alloys, processing, and corrosion performance. Materials 5:135–155
Nayeb-Hashemi AA, Clark JB (1998) Phase diagrams of binary magnesium alloys. ASM International, Metals Park, Ohio
Hort N, Huang Y, Fechner D, Stoermer M, Blawert C, Witte F, Vogt C, Druecker H, Willumeit R, Kainer KU, Feyerabend F (2010) Magnesium alloys as implant materials—Principles of property design for Mg–RE alloys. Acta Biomater 6:1714–1725
Peng Q, Ma N, Li H (2012) Gadolinium solubility and precipitate identification in Mg–Gd binary alloy. J Rare Earths 30:1064–1068
Chino Y, Kobata M, Iwasaki H, Mabuchi M (2002) Tensile properties from room temperature to 673 K of Mg–0.9 mass%Ca alloy containing lamella Mg2Ca. Mater Trans 43:2643–2646
Acknowledgements
This research was financially supported by the Helmholtz Virtual Institute VH-VI-523 (In vivo studies of biodegradable magnesium based implant materials).
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© 2018 The Minerals, Metals & Materials Society
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Lu, Y., Huang, Y., Feyerabend, F., Willumeit-Römer, R., Kainer, K.U., Hort, N. (2018). Microstructure and Mechanical Properties of Mg-Gd Alloys as Biodegradable Implant Materials. In: & Materials Society, T. (eds) TMS 2018 147th Annual Meeting & Exhibition Supplemental Proceedings. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72526-0_23
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DOI: https://doi.org/10.1007/978-3-319-72526-0_23
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