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Microstructure and Mechanical Properties of Mg-Gd Alloys as Biodegradable Implant Materials

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TMS 2018 147th Annual Meeting & Exhibition Supplemental Proceedings (TMS 2018)

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Abstract

Mg alloys attract more and more attentions for biomedical applications. Mg-Gd alloys were designed as biodegradable implant materials which combine favorable mechanical and corrosion properties. In this work, the microstructure and mechanical properties of binary Mg-2Gd, ternary Mg-2Gd-(Ag, Ca) and quaternary Mg-2Gd-2Ag-0.4Ca alloys were investigated. The alloys were prepared by permanent mould casting. The results show that the additions of Ag and Ca had significant influences on the microstructure and mechanical properties of Mg-2Gd alloy. Ag and Ca additions affect the formation of second phases. A quaternary Mg-Gd-Ag-Ca second phase was found in the quaternary alloy. Both the hardness and tensile yield strength were improved by adding Ag and Ca to 2 wt% Gd-containing alloys due to grain refinement and formation of different intermetallic phases (IMPs). Furthermore, the addition of Ag and Ca can apparently enhance the age hardening of Mg-2Gd alloy.

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References

  1. Staiger MP, Pietak AM, Huadmai J, Dias G (2006) Magnesium and its alloys as orthopedic biomaterials: a review. Biomaterials 27:34-1728

    Article  CAS  Google Scholar 

  2. Chen Y, Xu Z, Smith C, Sankar J (2014) Recent advances on the development of magnesium alloys for biodegradable implants. Acta Biomater 10:4561–4573

    Article  CAS  Google Scholar 

  3. Li N, Zheng Y (2013) Novel magnesium alloys developed for biomedical application: a review. J Mater Sci Technol 29:489–502

    Article  CAS  Google Scholar 

  4. Song GL (2007) Control of biodegradation of biocompatable magnesium alloys. Corros Sci 49:1696–1701

    Article  CAS  Google Scholar 

  5. Yang L, Huang Y, Feyerabend F, Willumeit R, Mendis C, Kainer KU, Hort N (2013) Microstructure, mechanical and corrosion properties of Mg–Dy–Gd–Zr alloys for medical applications. Acta Biomater 9:8499–8508

    Article  CAS  Google Scholar 

  6. Hou L, Li Z, Pan Y, Du L, Li X, Zheng Y, Li L (2014) In vitro and in vivo studies on biodegradable magnesium alloy. Prog Nat Sci Mater Int 24:466–471

    Article  CAS  Google Scholar 

  7. Hänzi AC, Gunde P, Schinhammer M, Uggowitzer PJ (2009) On the biodegradation performance of an Mg–Y–RE alloy with various surface conditions in simulated body fluid. Acta Biomater 5:162–171

    Article  CAS  Google Scholar 

  8. Gunde P, Hänzi AC, Sologubenko AS, Uggowitzer PJ (2011) High-strength magnesium alloys for degradable implant applications. Mater Sci Eng A 528:1047–1054

    Article  CAS  Google Scholar 

  9. Feyerabend F, Fischer J, Holtz J, Witte F, Willumeit R, Drucker H, Vogt C, Hort N (2010) Evaluation of short-term effects of rare earth and other elements used in magnesium alloys on primary cells and cell lines. Acta Biomater 6:1834–1842

    Article  CAS  Google Scholar 

  10. Atrens A, Liu M, Zainal Abidin NI (2011) ‘Corrosion mechanism applicable to biodegradable magnesium implants. Mater Sci Eng B 176:1609–1636

    Article  CAS  Google Scholar 

  11. Gu X-N, Zheng Y-F (2010) A review on magnesium alloys as biodegradable materials. Front Mater Sci Chin 4:111–115

    Article  Google Scholar 

  12. Persaud-Sharma D, Mcgoron A (2012) Biodegradable magnesium alloys: a review of material development and applications. J Biomimetics, Biomater Tissue Eng 12:25–39

    Article  CAS  Google Scholar 

  13. Tie D, Feyerabend F, Muller WD, Schade R, Liefeith K, Kainer KU, Willumeit R (2013) Antibacterial biodegradable Mg-Ag alloys. Eur Cells Mater 25:284–298

    Article  CAS  Google Scholar 

  14. Salahshoor M, Guo Y (2012) Biodegradable orthopedic magnesium-calcium (Mg–Ca) alloys, processing, and corrosion performance. Materials 5:135–155

    Article  CAS  Google Scholar 

  15. Nayeb-Hashemi AA, Clark JB (1998) Phase diagrams of binary magnesium alloys. ASM International, Metals Park, Ohio

    Google Scholar 

  16. Hort N, Huang Y, Fechner D, Stoermer M, Blawert C, Witte F, Vogt C, Druecker H, Willumeit R, Kainer KU, Feyerabend F (2010) Magnesium alloys as implant materials—Principles of property design for Mg–RE alloys. Acta Biomater 6:1714–1725

    Article  CAS  Google Scholar 

  17. Peng Q, Ma N, Li H (2012) Gadolinium solubility and precipitate identification in Mg–Gd binary alloy. J Rare Earths 30:1064–1068

    Article  CAS  Google Scholar 

  18. Chino Y, Kobata M, Iwasaki H, Mabuchi M (2002) Tensile properties from room temperature to 673 K of Mg–0.9 mass%Ca alloy containing lamella Mg2Ca. Mater Trans 43:2643–2646

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This research was financially supported by the Helmholtz Virtual Institute VH-VI-523 (In vivo studies of biodegradable magnesium based implant materials).

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Correspondence to Yiyi Lu .

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Lu, Y., Huang, Y., Feyerabend, F., Willumeit-Römer, R., Kainer, K.U., Hort, N. (2018). Microstructure and Mechanical Properties of Mg-Gd Alloys as Biodegradable Implant Materials. In: & Materials Society, T. (eds) TMS 2018 147th Annual Meeting & Exhibition Supplemental Proceedings. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72526-0_23

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