Abstract
As the absorbing material composed of sole carbon is difficult to meet the comprehensive requirements of microwave applications, preparation of carbonaceous nanocomposite materials becomes an effective method to increase microwave absorption properties. In this study, a novel nanocomposite composed of Co–Ni ferrite and graphene was synthesized via a simple and rapid microwave hydrothermal method in just a few minutes. It was demonstrated that the minimum microwave reflection loss of the composite of 3 mm thickness with a low filling ratio (20 wt%) reached −13.1 dB at 17.2 GHz with an effective absorption bandwidth of 3.1 GHz. The good performance of the composite was believed to be a result of high dielectric loss of graphene associated with a multi-dielectric relaxation process and magnetic loss of the ferrite mainly originated from natural ferromagnetic resonance.
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Wu X, Che Y (1992) Foreign microwave absorbing materials. National University of Defense Technology press
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191
Loh KP, Bao Q, Ang PK, Yang J (2010) The chemistry of graphene. J Mater Chem 20:2277–2289
Ma E, Li J, Zhao N, Liu E, He C, Shi C (2013) Preparation of reduced graphene oxide/Fe3O4 nanocomposite and its microwave electromagnetic properties. Mater Lett 91:209–212
Lv H, Ji G, Li X, Chang X, Wang M, Zhang H, Du Y (2015) Microwave absorbing properties and enhanced infrared reflectance of FeAl mixture synthesized by two-step ball-milling method. J Magn Magn Mater 374:225–229
Shang C, Ji G, Liu W, Zhang X, Lv H, Du Y (2015) One-pot in situ molten salt synthesis of octahedral Fe3O4 for efficient microwave absorption application. Rsc Adv 5:80450–80456
Zhao B, Shao G, Fan B, Zhao W, Zhang R (2015) Facile synthesis and enhanced microwave absorption properties of novel hierarchical heterostructures based on a Ni microsphere-CuO nano-rice core-shell composite. Phys Chem Chem Phys 17:6044–6052
Zhang H, Xie A, Wang C, Wang H, Shen Y, Tian X (2014) Room temperature fabrication of an RGO–Fe3O4 composite hydrogel and its excellent wave absorption properties. Rsc Adv 4:14441–14446
Zhang S, Jiao Q, Hua J, Li J, Zhao Y, Li H, Wu Q (2015) Vapor diffusion synthesis of rugby-shaped CoFe2O4/graphene composites as absorbing materials. J Alloy Compd 630:195–201
Fu M, Jiao Q, Zhao Y (2013) Preparation of NiFe2O4 nanorod–graphene composites via an ionic liquid assisted one-step hydrothermal approach and their microwave absorbing properties. J Mater Chem A 1:5577–5586
Ji R, Cao C, Chen Z, Zhai H, Bai J (2014) Solvothermal synthesis of CoxFe3−xO4 spheres and their microwave absorption properties. J Mater Chem C 2:5944–5953
Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339
Wang LN, Jia XL, Li YF, Yang F, Zhang LQ, Liu LP (2014) Synthesis and microwave absorption property of flexible magnetic film based on graphene oxide/carbon nanotubes and Fe3O4 nanoparticles. J Mater Chem A 2:14940–14946
Kim SS, Jo SB, Gueon KI, Choi KK, Kim JM, Churn KS (1991) Complex permeability and permittivity and microwave absorption of ferrite-rubber composite at X-band frequencies. IEEE Trans Magn 27:5462–5464
Zhao B, Zhao WY, Shao G, Fan BB, Zhang R (2015) Morphology-control synthesis of a core-shell structured NiCu alloy with tunable electromagnetic-wave absorption capabilities. ACS Appl Mater Interfaces 7:12951–12960
Peng Z, Hwang JY (2015) Microwave-assisted metallurgy. Int Mater Rev 60:30–63
Wu M, Zhang Y, Hui S, Xiao T, Ge S, Hines W, Budnick J, Taylor G (2002) Microwave magnetic properties of Co50/(SiO2)50 nanoparticles. Appl Phys Lett 80:4404–4406
Qu B, Zhu C, Li C, Zhang X, Chen Y (2016) Coupling hollow Fe3O4-Fe nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material. ACS Appl Mater Interfaces 8:3730–3735
Liu P, Yao Z, Ng, VMH, Zhou J, Yang Z, Kong L (2017) Enhanced microwave absorption properties of double-layer absorbers based on spherical NiO and Co0.2Ni0.4Zn0.4Fe2O4 ferrite composites. Acta Metallurgica Sinica https://doi.org/10.1007/s40195-017-0612-5
Tong SY, Wu JM, Tung MJ, Ko WS, Huang YT, Wang YP (2012) Effect of Ni concentration on electromagnetic wave absorption of (Ni, Mn, Zn)Fe2O4/resin particulate composites. J Alloy Compd 525:143–148
Bueno AR, Gregori ML, No´brega MCS (2008) Microwave-absorbing properties of Ni0.50−xZn0.50−xMe2xFe2O4 (Me = Cu, Mn, Mg) ferrite-wax composite in X-band frequencies. J Magn Magn Mater 320:864–870
Zheng Y, Wang X, Wei S, Zhang B, Yu M, Zhao W, Liu J (2017) Fabrication of porous graphene-Fe3O4 hybrid composites with outstanding microwave absorption performance. Compos A 95:237–247
Fu M, Jiao Q, Zhao Y, Li H (2014) Vapor diffusion synthesis of CoFe2O4 hollow sphere/graphene composites as absorbing materials. J Mater Chem A 2:735–744
Acknowledgements
This work was partially supported by the National Natural Science Foundation of China under Grant 51774337, the innovation-driven Program of Central South University under Grant 2016CXS021 and the Shenghua Lieying Program of Central South University under Grant 502035001.
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Peng, Z. et al. (2018). Microwave Synthesis of Co–Ni Ferrite/Graphene Nanocomposite for Microwave Absorption. In: Li, B., et al. Characterization of Minerals, Metals, and Materials 2018 . TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72484-3_38
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DOI: https://doi.org/10.1007/978-3-319-72484-3_38
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