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Evaluation of the Occurrence of Fouling and Scaling on the Membrane HDX 200 for the Treatment of the Effluent of Brass Electrodeposition with EDTA as Complexing Agent

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Energy Technology 2018 (TMS 2018)

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

Considering the risks involving the use of cyanide, other complexing agents have been evaluated for the treatment by electrodialysis of the effluent of brass electrodeposition and among them, EDTA is interesting since it has been already tested for many years to separate ions. The main objective of the present paper was to evaluate the occurrence of fouling and scaling on the surface of the anion-exchange membrane HDX 200 by the construction of chronopotentiometric curves and speciation diagrams in different conditions (pH between 10–12 and proportion of cupric ions of 30%, 50%, 70%). According to the results, the chronopotentiometric curves did not show additional inflexion points typical for the cases which occurs fouling and scaling for the pH values evaluated, which is in accordance with the speciation diagrams of the solutions constructed with the aid of Hydra-Medusa software. Hence, the pH and the proportion of cupric ions did not show influence on the curves behavior.

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Acknowledgements

The authors gratefully acknowledge the financial support given by funding agencies CNPq (Process 141346/2016-7) and FAPESP (Process 2012/51871-9).

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Authors and Affiliations

  1. Department of Chemical Engineering, São Paulo University, Avenida Professor Lineu Prestes, 580, Conjunto Das Químicas, Bloco 18, São Paulo, SP, 05508-000, Brazil

    K. S. Barros, J. A. S. Tenório & D. C. R. Espinosa

Authors
  1. K. S. Barros
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  2. J. A. S. Tenório
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  3. D. C. R. Espinosa
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Corresponding author

Correspondence to K. S. Barros .

Editor information

Editors and Affiliations

  1. Queensland University of Technology, Brisbane, Queensland, Australia

    Ziqi Sun

  2. Northeastern University, Shenyamg, China

    Cong Wang

  3. Idaho National Laboratory, Idaho Falls, Idaho, USA

    Donna Post Guillen

  4. IND LLC, South Jordan, Utah, USA

    Neale R Neelameggham

  5. University of Alaska Fairbanks, Fairbanks, Alaska, USA

    Lei Zhang

  6. Purdue University, West Lafayette, Indiana, USA

    John A. Howarter

  7. Nucor Steel, Blytheville, Arkansas, USA

    Tao Wang

  8. Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

    Elsa Olivetti

  9. ArcelorMittal Global R&D, East Chicago, Indiana, USA

    Mingming Zhang

  10. Reno, Nevada, USA

    Dirk Verhulst

  11. Harvard University , Watertown, Massachusetts, USA

    Xiaofei Guan

  12. Gopher Resource, Tampa, Florida, USA

    Allie Anderson

  13. Al Isra University, Amman, Jordan

    Shadia Ikhmayies

  14. University of Utah, Salt Lake City, Utah, USA

    York R. Smith

  15. LG Fuel Cell Systems, North Canton, Ohio, USA

    Amit Pandey

  16. The Pennsylvania State University, University Park, Pennsylvania, USA

    Sarma Pisupati

  17. Beihang University, Beijing, China

    Huimin Lu

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Barros, K.S., Tenório, J.A.S., Espinosa, D.C.R. (2018). Evaluation of the Occurrence of Fouling and Scaling on the Membrane HDX 200 for the Treatment of the Effluent of Brass Electrodeposition with EDTA as Complexing Agent. In: Sun, Z., et al. Energy Technology 2018 . TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72362-4_35

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