Abstract
Mg(OH)2 is usually used as a flame retardant agent, a heavy metal removing agent and a flue gas desulfurization agent in the field of environmental protection. In this work, Mg(OH)2 was prepared by electrolytic method using MgCl2 aqueous solution as the main raw materials. And the X-ray diffraction results proved that pure Mg(OH)2 crystals can be fabricated by the electrolysis method. The Mg(OH)2 prepared has two microscopic forms, shaped in block and elongated fibrous. The effects of concentration of MgCl2 solution, current density, temperature and time of electrolysis on the current efficiency and energy consumption in the electrolysis process were studied in this paper. Within the experimental range, current efficiency increased but energy consumption decreased with the increase of MgCl2 solution concentration, electrolysis temperature and time. The effects of current density on the current efficiency and energy consumption rested on the concentration of the MgCl2 solution and electrolysis temperature.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
X. Feng, Y. Z. Liu, H. Y. Shen, J. H. Bai. Research status of superfine magnesium hydroxide flame retardant [J]. China Plastics Industry, 2013, 41(02):7–10 + 69.
Z. L. Zu, Q. Sun, H. Li, P. Ye. Research progress in preparation and application of magnesium hydroxide flame retardant material [J]. China Powder Science and Technology, 2013, 19(06):37–40.
L. M. Ji, L. J. Li, F. Nie, Z. M. Zeng. Research status of magnesium hydroxide flame retardant in China [J]. Journal of Salt Lake Research, 2007, (02):62–72.
Z. Y. Zhao, X. G. Li, S. R. Wang, Y. Xiao. Study on the priority growth of (001) plane of hexagonal magnesium hydroxide [J]. Journal of Synthetic Crystals, 2014, 43(07):1611–1619. https://doi.org/10.16553/j.cnki.issn1000-985x.2014.07.014.
M. Y. Su, H. J. Wang, L. S. Tang. Application situation and research progress of magnesium hydroxide flame retardants [J]. Contemporary Chemical Industry, 2015, 44(01):114–116+119.
H. Shen. The research on multiplexing of modified magnesium hydroxide/expandable graphite [D]. Chengdu University of Technology, 2013.
Northeastern University. A method for converting magnesium chloride into high-purity Magnesium Oxide [P]. China patent, 201710324299.X.
Y. Y. Wang, W. J. Peng. A study of the cathodic current efficiency in zincate zinc plating [J]. Electroplating & Pollution Control, 2003, (06):12–16.
Chun Rong Wang, Sha Chang, Min Ye, Qin Yi Ren. Current Efficiency and Energy Consumption of Electrochemical Oxidation for Ammonia Removal from Coking Wastewater Using Boron-Doped Diamond Electrodes [J]. Applied Mechanics and Materials, 2013, 2301(295).
M. G. Pavlovic, N. D. Nikolic, K. I. Popov. The current efficiency during the cathodic period of reversing current in copper powder deposition and the overall current efficiency [J]. Journal of the Serbian Chemical Society, 2003, 68(8–9):.
Geir Martin Haarberg. The Current Efficiency for Aluminium Deposition from Molten Fluoride Electrolytes with Dissolved Alumina [M]. Springer International Publishing: 2016.
V.M. Volgin, V.V. Lyubimov, I.V. Gnidina, A.D. Davydov, T.B. Kabanova. Effect of Current Efficiency on Electrochemical Micromachining by Moving Electrode [J]. Procedia CIRP, 2016, 55:.
Élen Rufino, Mario Santana, Luiz Faria, Leonardo Silva. Influence of lead dioxide electrodes morphology on kinetics and current efficiency of oxygen-ozone evolution reactions [J]. Chemical Papers, 2010, 64(6).
X. Z. Deng, Y. W. Wang, J. P. Peng, K. J. Liu, N. X. Feng and Y. Z. Di. Surface area control of nanocomposites Mg(OH)2/graphene using a cathodic electrodeposition process: high adsorption capability of methyl orange [J]. RSC Advances, 2016, 91(6):88315–88320. https://doi.org/10.1039/c6ra15804h.
Q. X. Tan, S. L. Liu. Current efficiencies of electroplating bath and measurement method thereof [J]. Plating & Finishing, 2008, 30(4):27–29.
Acknowledgements
This research was supported by the National Natural Science Foundation of China (U1508217), the Fundamental Research Funds for the Central Universities (N162505002).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Pan, X. et al. (2018). Fabrication of Mg(OH)2 by Electrolysis Using MgCl2 Aqueous Solution. In: Orlov, D., Joshi, V., Solanki, K., Neelameggham, N. (eds) Magnesium Technology 2018. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72332-7_23
Download citation
DOI: https://doi.org/10.1007/978-3-319-72332-7_23
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-72331-0
Online ISBN: 978-3-319-72332-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)