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Analytical Investigations and Advanced Materials for Damage Diagnosis and Conservation of Monument’s Stucco

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Advanced Materials for the Conservation of Stone
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Abstract

Stone monuments with façade decorations and stuccoes represent an important part of the world’s cultural heritage. Due to human activities or natural weather events, stucco has endured damaging processes that are responsible for their deterioration. Stucco is a porous material that collects dirt and absorbs stains, both indoors and outdoors, which requires frequent cleaning. To preserve them for future generations, it is important to have good evidence for a scientific diagnosis of their deterioration stage (stone material types, surface structure, mineral composition, chemical composition, porosity properties, thermal and photochemical properties, mechanical properties, and their response to freeze-thaw and salt crystallization). Also, new and revolutionary treatment methods with nanomaterials (hydroxyapatite and derivatives, calcium and magnesium hydroxides) are able to offer stucco consolidation which is valuable for different surfaces. All these aspects are discussed in this chapter.

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References

  1. Brimblecombe P. History of air pollution and deterioration of heritage. In: Zezza F, editor. Weathering and air pollution: Primo corso della Scuola universitaria C.U.M.conservazione dei monumenti, Lago di Garda (Portese), Venezia, Milano, 2–9 September 1991. Bari: Mario Adda Editore; 1992. p. 23–32.

    Google Scholar 

  2. Camuffo D, Del Monte M, Sabbioni C, Vittori O. Wetting, deterioration and visual features of stone surfaces in an urban area. Atmos Environ. 1982;16(9):2253–9.

    Article  Google Scholar 

  3. Brimblecombe P, Grossi CM. Damage to buildings from future climate and pollution. APT Bull. 2007;38(2–3):13–8.

    Google Scholar 

  4. Ashurst J, Dimes FG, editors. Conservation of building and decorative stone. Butterworth-Heinemann series in conservation and museology. Oxford and Woburn, MA: Butterworth-Heinemann; 1998.

    Google Scholar 

  5. Fitzner B. Documentation and evaluation of stone damage on monuments. In: Kwiatkowski D, Lofvendahl R, editors. Proceedings of the 10th international congress on deterioration and conservation of stone, Stockholm, June 27–July 2, 2004, vol. 2. Stockholm: ICOMOS; 2004. p. 677–90.

    Google Scholar 

  6. Fitzner B, Heinrichs K. Damage diagnosis on stone monuments: weathering forms, damage categories and damage indices. In: Přikryl R, Viles HA, editors. Understanding and managing of stone decay (SWAPNET), vol. 2001. Prague: Charles University, The Karolinum Press; 2002. p. 11–56.

    Google Scholar 

  7. Doehne E. Building material decay and salt weathering: a selected bibliography. In: Siegesmund S, Weiss T, Vollbrecht A, editors. Supplement to natural stone, weathering phenomena, conservation strategies and case studies, Geological Society Special Publication 205. London: Geological Society of London; 2003. www.geolsoc.org.uk/webdav/site/GSL/shared/Sup_pubs/2003/SUP18182.rtf. Accessed Aug 2017.

    Google Scholar 

  8. Fitzner B, Heinrichs K. Damage diagnosis on stone monuments – weathering forms, damage categories and damage indices. In: Prikryl R, Viles HA, editors. Understanding and managing stone decay, proceeding of the international conference “stone weathering and atmospheric pollution network (SWAPNET 2001)”. Prague: The Karolinum Press, Charles University; 2002. p. 11–56.

    Google Scholar 

  9. Sharma RK, Gupta HO. Dust pollution at the Taj Mahal: a case study. Conservation of stone and other materials. In: RILEM proceedings, vol. 21. Paris: E&F.N. Spon; 1993. p. 11–8.

    Google Scholar 

  10. Baedecker PA, Reddy MM. The erosion of carbonate stone by acid rain: laboratory and field investigations. J Chem Educ. 1993;70(2):104–8.

    Article  Google Scholar 

  11. Camaiti M, Bugani S, Bernardi E, Morselli L, Matteini M. Effects of atmospheric NOx on biocalcarenite coated with different conservation products. Appl Geochem. 2007;22(6):1248–54.

    Article  Google Scholar 

  12. Bai Y, Thompson GE, Martinez-Ramirez S. Effects of NO2 on oxidation mechanisms of atmospheric pollutant SO2 over Baumberger sandstone. Build Environ. 2006;41(4):486–91.

    Article  Google Scholar 

  13. Ion RM, Ion ML, Radu A, Suica Bunghjez IE, Fiearscu RC, Fierascu I, Teodorescu S. Mortar pe bază de nanomateriale pentru conservarea fațadelor construcţiilor. Rom J Mat. 2016;46(4):412–8.

    Google Scholar 

  14. Ciliberto E, Ioppolo S, Manuella F. Ettringite and thaumasite: a chemical route for their removal from cementious artefacts. J Cult Herit. 2008;9(1):30–7.

    Article  Google Scholar 

  15. Steiger M, Siegesmund S. Special issue on salt decay. Environ Geol. 2007;52(2):185–6.

    Article  Google Scholar 

  16. Binda L, Lualdi M, Saisi A. Non-destructive testing techniques applied for diagnostic investigation: Syracuse Cathedral in Sicily, Italy. Int J Archit Herit. 2007;1(4):380–402.

    Article  Google Scholar 

  17. Blauer Bohm C. Techniques and tools for conservation investigations. In: Kwiatkowski D, Lofvendahl R, editors. Proceedings of the 10th international congress on deterioration and conservation of stone, Stockholm, June 27–July 2, 2004, vol. 2. Stockholm: ICOMOS Sweden; 2004. p. 549–59.

    Google Scholar 

  18. Hamilton A, Hall C, Pel L. Sodium sulfate heptahydrate: direct observation of crystallization in a porous material. J Phys D Appl Phys. 2008;41(21):212002.

    Article  Google Scholar 

  19. Ambrosi M, Dei L, Giorgi R, Neto C, Baglioni P. Colloidal particles of Ca(OH)2: properties and applications to restoration of frescoes. Langmuir. 2001;17(14):4251–5.

    Article  Google Scholar 

  20. Bracci S, Delgado Rodrigues J, Ferreira Pinto A, Matteini M, Pinna D, Porcinai S, Sacchi B, Salvadori B. Development and evaluation of new treatments for the conservation of outdoor stone monuments. In: Lukaszewicz JW, Niemcewicz P, editors. Proceedings of the 11th international congress on deterioration and conservation of stone, 15–20 September 2008, Toruń, Poland. Toruń: Nicolaus Copernicus University; 2008. p. 811–8.

    Google Scholar 

  21. Brajer I, Kalsbeek N. Limewater absorption and calcite crystal formation on a limewater-impregnated secco wall painting. Stud Conserv. 1999;44(3):145–56.

    Google Scholar 

  22. Espinosa Marzal RM, Scherer GW. Crystallization of sodium sulfate salts in limestone. Environ Geol. 2008a;56(3–4):605–21.

    Article  Google Scholar 

  23. Fidler J. Lime treatments: lime watering and shelter coating of friable historic masonry. APT Bull. 1995;26(4):50–6.

    Article  Google Scholar 

  24. Giorgi R, Dei L, Baglioni P. A new method for consolidating wall paintings based on dispersions of lime in alcohol. Stud Conserv. 2000;45(3):154–61.

    Google Scholar 

  25. Ion RM, Fierascu RC, Fierascu I, Bunghez IR, Ion ML, Caruṭiu-Turcanu D, Teodorescu S, Raditoiu V. Stone monuments consolidation with nanomaterials. Key Eng Mater. 2015;660:383–8.

    Article  Google Scholar 

  26. Hansen E, Doehne E, Fidler J, Larson J, Martin B, Matteini M, et al. A review of selected inorganic consolidants and protective treatments for porous calcareous materials. Rev Conserv. 2003;4:13–25.

    Google Scholar 

  27. Giorgi R, Bozzi C, Dei L, Gabbiani C, Ninham BW, Baglioni P. Nanoparticles of Mg(OH)2: synthesis and application to paper conservation. Langmuir. 2005;21:8495–501.

    Article  Google Scholar 

  28. Ion RM, Turcanu-Caruţiu D, Fierăscu RC, Fierăscu I, Bunghez IR, Ion ML, Teodorescu S, Vasilievici G, Rădiţoiu V. Caoxite-hydroxyapatite composition as consolidating material for the chalk stone from Basarabi-Murfatlar churches ensemble. Appl Surf Sci. 2015;358:612–8.

    Article  Google Scholar 

  29. Ion RM, Turcanu-Carutiu D, Fierascu RC, Fierascu I. Chalk stone restoration with hydroxyapatite–based nanoparticles. The Scientific Bulletin of Valahia University – Materials and Mechanics. 2014;12(9):24–8.

    Google Scholar 

  30. Sassoni E, Naidu S, Scherer GW. Preliminary results of the use of hydroxyapatite as a consolidant for carbonate stones. MRS Proceedings: Cambridge University Press; 2011.

    Google Scholar 

  31. Sassoni E, Franzoni E. Evaluation of hydroxyapatite effects in marble consolidation and behaviour towards thermal weathering. In: Proceedings of Built Heritage–Monitoring Conservation Management, Milan, Italy. 2013. pp. 1287–95.

    Google Scholar 

  32. Charola AE, Munich G, Ceteno SA. Conclusions and recommendations resulting from the colloquium on historic and archaeological mortars: analysis and characterization. US/ICOMOS Scientific J III. 2001;1:15.

    Google Scholar 

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Acknowledgment

This paper received financial support from MEN-UEFISCDI through the projects PNII 261/2014 and PN 16.31.02.04.04.

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Correspondence to Rodica-Mariana Ion .

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Ion, RM. (2018). Analytical Investigations and Advanced Materials for Damage Diagnosis and Conservation of Monument’s Stucco. In: Hosseini, M., Karapanagiotis, I. (eds) Advanced Materials for the Conservation of Stone. Springer, Cham. https://doi.org/10.1007/978-3-319-72260-3_10

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