Abstract
A new microwave roasting technology for the removal of Cl from zinc oxide dust is proposed in this paper. The effect of important parameters, such as roasting temperature, holding time and stirring speed, were investigated and the process conditions were optimized using response surface methodology (RSM). The experimental results show that zinc oxide dust dechlorination rate can reach more than 95.66% and meet the requirements of wet smelting electrolysis when controlling the stirring speed of 60 r/min,roasting temperature of 650 ℃, holding time of 30 min. In addition, the effect of roasting temperature and holding time on removal efficiency of Cl was most significant. As a result, the Cl content was decreased without the risk of pollution. This makes it as a good choice for a more ecological treatment of zinc secondary resources.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ma AY et al (2014) Dielectric properties and temperature increase of zinc oxide dust derived from volatilization in rotary kilns. J Microwave Power Electromagn Energy 48:25–34
Zhang YL, Yu XJ, Li XB (2012) Kinetics of simultaneous leaching of Ag and Pb from hydrometallurgical zinc residues by chloride. Rare Met 31(4):402–409
Ma AY et al (2017) Dechlorination of zinc oxide dust derived from zinc leaching residue by microwave roasting in a rotary kiln. Braz. J Chem Eng 34(1):193–202
Rabah MA, El-Sayed AS (1995) Recovery of zinc and some of its valuable salts from secondary resources and wastes. Hydrometallurgy 37(1):23–32
Sahin FC, Derin B, Yücel O (2000) Chloride removal from zinc ash. Scand J Metall 29:224–230
Jiang L, Fu GF, Wang DQ (2001) Removal of F and Cl from zinc oxide dust using selective chlorination roasting process. Nonferrous Met (in Chinese) 53(3):28–31
Qiu YY et al (2008) Chlorine removal from zinc bearing wastes in alkaline leaching electrowinning process. J Saf. Environ (in Chinese) 8(1):62–64
Wang MH, Wei LQ, Guo TL (2012) Process study on removing chlorine from zinc oxide materials. Non-ferrous Min Metall (in Chinese) 28(4):26–28
Chen WS et al (2011) Removal of chloride from electric arc furnace dust. J Hazard Mater 190(1–3):639–344
Al-Harahsheh M, Kingman SW (2004) Microwave-assisted leaching - a review. Hydrometallurgy 73(3–4):189–203
Onol K, Saridede MN (2013) Investigation on microwave heating for direct leaching of chalcopyrite ores and concentrates. Int J Miner Metall Mater 20(3):228–223
Zenki M, Iwadou Y (2002) Repetitive determination of chloride using the circulation of the reagent solution in closed flow-through system. Talanta 58:1055–1061
Acknowledgements
The authors are grateful for the financial support from the National Natural Science Foundation (No.51104073)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Ma, A., Xie, T., Li, G., Zheng, X., Zhang, L., Peng, J. (2018). Dechlorination of Zinc Oxide Dust by Microwave Roasting with RSM Optimization. In: Hwang, JY., et al. 9th International Symposium on High-Temperature Metallurgical Processing. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72138-5_68
Download citation
DOI: https://doi.org/10.1007/978-3-319-72138-5_68
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-72137-8
Online ISBN: 978-3-319-72138-5
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)