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Study on the Volatilization of Sb2S3 in Vacuum

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9th International Symposium on High-Temperature Metallurgical Processing (TMS 2018)

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Abstract

The thermogravimetric method was selected for investigating the evaporation of Sb2S3 in the pressure range of 50–300 Pa and in the temperature range of 823–1123 K, the gas phase diffusion was the rate-determining step for Sb2S3. The volatilization rate was related to the temperature and pressure, that the logarithm of volatilization rate yielded a line with the reciprocal of temperature and pressure. The volatilization rate for Sb2S3 was between 0–0.023 g·cm−2·s. The apparent activation energy was between 65.8 and 60.6 kJ/mol.

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Acknowledgements

This research work is supported by State Key Laboratory of Complex Nonferrous Metal Resource Clean Utilization, under Grant No. Kunming 650093, Personnel Training Project of Kunming University of Science and Technology under Grant No. KXZ3201752042, the Education Department of Yunnan province under the Grant No. KKJB201663013, Science and technological talent cultivation plan of Yunnan province, China under Grant No. 2017HB009.

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Authors and Affiliations

  1. State Key Laboratory of Complex Nonferrous Metal Resources Clear Utilization in Yunnan Province, Kunming University of Science and Technology, No. 68 Wenchang Road 121 Street, Kunming, Yunnan, 650093, China

    Heng Xiong, Bin Yang, Baoqiang Xu & Jia Yang

  2. National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, No. 68 Wenchang Road 121 Street, Kunming, Yunnan, 650093, China

    Heng Xiong, Zhengen Zhou, Bin Yang, Dachun Liu, Baoqiang Xu, Yong Deng & Jia Yang

  3. Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, No. 68 Wenchang Road 121 Street, Kunming, Yunnan, 650093, China

    Heng Xiong, Zhengen Zhou, Bin Yang, Dachun Liu, Baoqiang Xu, Yong Deng & Jia Yang

Authors
  1. Heng Xiong
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  2. Zhengen Zhou
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  3. Bin Yang
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  4. Dachun Liu
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  5. Baoqiang Xu
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  6. Yong Deng
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  7. Jia Yang
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Corresponding author

Correspondence to Bin Yang .

Editor information

Editors and Affiliations

  1. Michigan Technological University, Houghton, Michigan, USA

    Jiann-Yang Hwang

  2. Central South University, Changsha, China

    Tao Jiang

  3. Proval Partners SA, Lausanne, Switzerland

    Mark William Kennedy

  4. RHI AG, Leoben, Austria

    Dean Gregurek

  5. Rio Tinto Kennecott Utah Copper Corp, South Jordan, Utah, USA

    Shijie Wang

  6. The University of Queensland, Brisbane, Queensland, Australia

    Baojun Zhao

  7. Istanbul Technical University, Istanbul, Turkey

    Onuralp Yücel

  8. Atilim University, Ankara, Turkey

    Ender Keskinkilic

  9. Montana Tech of the University of Montana, Butte, Montana, USA

    Jerome P Downey

  10. Central South University, Changsha, China

    Zhiwei Peng

  11. University of Concepción, Concepción, Chile

    Rafael. Padilla

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Xiong, H. et al. (2018). Study on the Volatilization of Sb2S3 in Vacuum. In: Hwang, JY., et al. 9th International Symposium on High-Temperature Metallurgical Processing. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72138-5_62

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