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Limestone Powder

  • Luc Courard
  • Duncan Herfort
  • Yury Villagrán
Chapter
Part of the RILEM State-of-the-Art Reports book series (RILEM State Art Reports, volume 25)

Abstract

Limestone has been successfully used as a constituent of cement and concrete for decades. Fine limestone is commonly included in Portland cement by intergrinding, resulting in an optimal particle size distribution of the modified cement. In other applications, limestone powder is added separately from cement, for producing more stable and robust mixes, especially self-compacting concrete. This chapter examines the performance of limestone modified Portland cement and concrete. The review comprises the effects on cement hydration in relation with the fineness of the limestone, on the fresh properties of mortar and concrete (including its role in self-compacting concrete), and on the strength development in the hardened state. Complementarily, comments regarding sulphate attack and environmental benefits of the use of limestone modified cement are included. Limestone is an effective constituent of cement and concrete, and comparative analyses should always be made to mixes produced to the same strength. In this way, it has to be regarded as a supplementary cementitious material when included by intergrinding with cement clinker, or as a filler when added separately to concrete.

Keywords

Limestone Filler Concrete Cement Durability Hydration SCC 

References

  1. Alonso MM, Palacios M, Puertas F, De la Torre AG, Aranda MAG (2007) Effect of polycarboxylate admixture structure on cement paste rheology. Materiales de Construcción 57(286):65–81Google Scholar
  2. Antoni M, Martirena F, Scrivener K (2012) Cement substitution by a combination of metakaolin and limestone. Cem Concr Res 42(12):1579–1589CrossRefGoogle Scholar
  3. Artelt C, Garcia E (2008) Impact of superplasticizer concentration and of ultra-fine particles on the rheological behaviour of dense mortar suspensions. Cem Concr Res 38:633–642CrossRefGoogle Scholar
  4. Arvaniti EC, Juenger M, Bernal SA, Duchesne J, Courard L, Leroy S, Provis J, Klemm A, De Belie N (2015) Physical characterization methods for supplementary cementitious materials. Mater Struct 48(11):3675–3686CrossRefGoogle Scholar
  5. Banfill PFG (2011) Additivity effects in the rheology of fresh concrete containing water-reducing admixtures. Constr Build Mater 25(6):2955–2960CrossRefGoogle Scholar
  6. Bensted J (1980) Some hydration investigations involving Portland cement—effect of calcium carbonate substitution of gypsum. World Cem Technol 11(8):395–406Google Scholar
  7. Bentz DP, Garboczi EJ (1991) Percolation of phases in a three dimensional cement paste microstructure model. Cem Concr Res 21:325–344CrossRefGoogle Scholar
  8. Bentz DP, Sato T, de la Varga I, Weiss WJ (2012) Fine limestone additions to regulate setting in high volume fly ash mixtures. Cem Concr Compos 34:11–17CrossRefGoogle Scholar
  9. Berodier E (2013) Nanocem CP9 report (April)Google Scholar
  10. Bokan Bosiljkov V (2003) SCC mixes with poorly graded aggregate and high volume of limestone filler. Cem Concr Res 33:1279–1286CrossRefGoogle Scholar
  11. Borgholm HE, Herfort D, Rasmussen S (1995) A new blended cement based on mineralised clinker. World Cem Res Dev 27–33Google Scholar
  12. Burgos-Montes O, Palacios M, Rivilla P, Puertas F (2012) Compatibility between superplasticizer admixtures and cements with mineral additions. Constr Build Mater 31:300–309Google Scholar
  13. CEMBUREAU Activity report (2008) 44 pGoogle Scholar
  14. CemCalc (2011–2013) Ternary blended cement with high limestone filler content and low GBFS content. Scientific and Technical report (BBRI Belgian Building Research Center, CRIC Belgian Research Center for Cement Industry, ULg University of Liège), 348 pGoogle Scholar
  15. Courard L, Michel F (2014) Limestone fillers cement based composites: effects of blast furnace slags on fresh and hardened properties. Constr Build Mater 51:439–445CrossRefGoogle Scholar
  16. Courard L, Degeimbre R, Darimont A, Michel F, Willem X, Flamant S (2005) Some effects of limestone fillers as a partial substitute for cement in mortar composition. In: Banthia N (ed) ConMat’05 third international conference on construction materials: performance, innovations and structural implications. Vancouver, Canada (August 22–24, 2005) (Theme 3—Chapter 5), 10 pGoogle Scholar
  17. Courard L, Michel F, Pierard J (2011) Influence of clay in limestone fillers for self-compacting cement based composites. Constr Build Mater 25:1356–1361CrossRefGoogle Scholar
  18. Czarnecki L, Klemm AJ, Sikora K (2010) The effects of mineral fillers and superplasticizers on rheology and the heat of hydration of cementitious mortars. In: Proceeding of international RILEM conference on use of superabsorbent polymers and other new additives in concrete, 15–18 August 2010, Lyngby, Denmark, pp 23–32Google Scholar
  19. Damtoft JS, Lukasik J, Herfort D, Gartner E, Sorrentino D (2008) Sustainable development and climate change initiatives. Cem Concr Res 38:115–127CrossRefGoogle Scholar
  20. De Weerdt K, Kjellsen KO, Sellevold E, Justnes H (2010) Synergy between fly ash and limestone powder in ternary cements. Cem Concr Compos 33(1):30–38CrossRefGoogle Scholar
  21. Diamantonis N, Marinos I, Katsiotis MS, Sakellariou A, Papathanasiou A, Kaloidas V, Katsioti M (2010) Investigations about the influence of fine additives on the viscosity of cement paste for self-compacting concrete. Constr Build Mater 24:1518–1522CrossRefGoogle Scholar
  22. Diederich P, Mouret M, de Ryck A, Ponchon F, Escadeillas G (2012) The nature of limestone filler and self-consolidating feasibility—relationships between physical, chemical and mineralogical properties of fillers and the flow at different states, from powder to cement-based suspension. Powder Technol 218:90–101CrossRefGoogle Scholar
  23. El Hilali A, Ghorbel E, Gonnon P (2006) Influence des fillers sur l’ouvrabilité des bétons autoplaçants, 24èmes Rencontres Universitaires de Génie Civil “Construire: les nouveaux défis”, 1 et 2 juin 2006. Association Universitaire de Génie Civil, La Grande Motte (France), p 8Google Scholar
  24. Emdadi A, Ali Libre N, Mehdipour I, Vahdani M, Dara S (2007) SCC mixtures with different aggregate gradation and limestone powder. In: Proceeding of 5th international RILEM symposium on self-compacting concrete, 3–5 September 2007, Ghent, Belgium, pp 155–162Google Scholar
  25. Esping O (2008) Effect of limestone filler BET(H2O)-area on the fresh and hardened properties of self compacting concrete. Cem Concr Res 38(7):938–944CrossRefGoogle Scholar
  26. Ezziane K, Kadri EH, Hallal A, Duval R (2010) Effect of mineral additives on the setting of blended cement by the maturity method. Mater Struct 43:393–401CrossRefGoogle Scholar
  27. García A, Castro-Fresno D, Polanco JA (2008) Evolution of penetration resistance in fresh concrete. Cem Concr Res 38:649–659CrossRefGoogle Scholar
  28. Georgiadis AS, Sideris KK, Anagnostopoulos NS (2010) Properties of SCC produced with limestone filler or viscosity modifying admixture. J Mater Civ Eng 22:352–360CrossRefGoogle Scholar
  29. Gesoğlu M, Güneyisi E, Kocabağ ME, Bayram V, Mermerdaş K (2012) Fresh and hardened characteristics of self compacting concretes made with combined use of marble powder, limestone filler, and fly ash. Constr Build Mater 37:160–170CrossRefGoogle Scholar
  30. Ghezal A, Khayat KH (2002) Optimizing self-consolidating concrete with limestone filler by using statistical factorial design methods. ACI Mater J 99(3):264–272Google Scholar
  31. Hallal A, Kadri EH, Ezziane K, Kadri A, Khelafi H (2010) Combined effect of mineral admixtures with superplasticizers on the fluidity of the blended cement paste. Constr Build Mater 24:1418–1423CrossRefGoogle Scholar
  32. Hawkins P, Tennis P, Detwiler R (2003) The use of limestone in Portland cement. A state of the art review. Portland Cement Association, Engineering Bulletin 227, ISBN: 0–89312-229-7Google Scholar
  33. Heirman G, Vandewalle L, Van Gemert D, Feys D, De Schutter G, Desmet B, Vantomme J (2007) Influence of mineral additions and chemical admixtures on the rheological behaviour of powder type SCC. In Proceeding of 5th international RILEM symposium on self-compacting concrete, 3–5 September 2007, Ghent, Belgium, pp 329–334Google Scholar
  34. Herfort D (2008) Developments needed in the production and use of cement for large reductions in CO2 emissions by 2050. In: Proceedings of the Anna Maria workshop IX sustainable cements: challenges, opportunities & applications (November 11–14)Google Scholar
  35. Herfort D, Lothenbach B (2015) A practical guide to microstructural analysis of cementitious materials. In: SrivenerK (ed) Taylor & Francis IncGoogle Scholar
  36. Jones MR, Zheng L, Newlands MD (2003) Estimation of the filler content required to minimise voids ratio in concrete. Mag Concr Res 55(2):193–202CrossRefGoogle Scholar
  37. Josserand L, Coussy O, de Larrard F (2006) Bleeding of concrete as an ageing consolidation process. Cem Concr Res 36:1603–1608CrossRefGoogle Scholar
  38. Joudi-Bahri I, Lecomte A, Ben Ouezdou M, Achour T (2012) Use of limestone sands and fillers in concrete without superplasticizer. Cement Concr Compos 34:771–780CrossRefGoogle Scholar
  39. Juel I, Herfort D, Gollop R, Konnerup-Madsen J, Jakobsen HJ, Skibsted J (2003) A thermodynamic model for predicting the stability of thaumasite. Cem Concr Compos 25(8):867–872CrossRefGoogle Scholar
  40. Khaleel OR, Abdul Razak H (2014) Mix design method for self compacting metakaolin concrete with different properties of coarse aggregate. Mater Des 53:691–700CrossRefGoogle Scholar
  41. Khanh VB (1999) Developement of limestone modified cements for high performance concretes. Ph.D. thesis, Department of Civil, Mining and Environmental Engineering, University of Wollongong, 1999. http://rouow.edu.au/theses/1238
  42. Kristensen T (2008) Characterisation of Portland cement including limestone additions by solid state MAS NMR spectroscopy, instrument centre for solid‐state NMR spectroscopy and interdisciplinary nanoscience center, Department of Chemistry, University of Aarhus (March)Google Scholar
  43. Lea FM (1998) The chemistry of cement and concrete, 4th edn. Chemical Publishing Company, 740 pGoogle Scholar
  44. Livesey P (1991) Strength characteristics of Portland-limestone cements. Constr Build Mater 5(3):147–150CrossRefGoogle Scholar
  45. Lothenbach B, Le Saout G, Gallucci E, Scrivener K (2008) Influence of limestone on the hydration of portland cements. Cem Concr Res 38:848–860CrossRefGoogle Scholar
  46. Magarotto R, Torresan I, Zeminian N (2003) Influence of the molecular weight of polycarboxylate superplasticizers on the rheological properties of fresh cement pastes, mortar and concrete. In: Proceeding 11th international congress on the chemistry of cement, Durban, South Africa, 11–16 May 2003, vol 2, pp 514–526Google Scholar
  47. Matschei T, Lothenbach B, Glasser FP (2007) Thermodynamic properties of Portland cement hydrates in the system CaO–Al2O3–SiO2–CaSO4–CaCO3–H2O. Cem Concr Res 37:1379–1410CrossRefGoogle Scholar
  48. Michel F, Piérard J, Courard L, Pollet V (2007) Influence of physico-chemical characteristics of limestone fillers on fresh and hardened mortar performances. In: Proceedinf 5th international RILEM symposium on self-compacting concrete, 3–5 September 2007, Ghent, Belgium, pp 205–210Google Scholar
  49. Mikanovic N, Jolicoeur C (2008) Influence of superplasticizers on the rheology and stability of limestone and cement pastes. Cem Concr Res 38:907–919CrossRefGoogle Scholar
  50. Moir GK, Kelham S (1993) Durability: performance of limestone-filled cements. Report of joint BRE/BCA/Cement industry working party, 27 Nov 1989, Building Research Establishment, GarstonGoogle Scholar
  51. Moir GK, Kelham S (1997) Developments in the manufacture and use of Portland limstone cements. In: Proceedings of the ACI international conference on high performance concrete: design and material and recent advances in concrete technology, December, Kuala Lumpur, MalaysiaGoogle Scholar
  52. Nepomuceno M, Oliveira L, Lopes SMR (2012) Methodology for mix design of the mortar phase of self-compacting concrete using different mineral additions in binary blends of powders. Constr Build Mater 26:317–326CrossRefGoogle Scholar
  53. Nielsen EP, Herfort D, Geiker M, Hooton RD (2003) Effect of solid solution of AFm phases on Chloride Binding. In: 11th international congress on the chemistry of cement, Durban, South Africa, vol 3, pp 1497–1506Google Scholar
  54. Perrot A, Lecompte T, Khelifi H, Brumaud C, Hot J, Roussel N (2012) Yield stress and bleeding of fresh cement pastes. Cem Concr Res 42:937–944CrossRefGoogle Scholar
  55. Petit J-Y, Wirquin E (2010) Effect of limestone filler content and superplasticizer dosage on rheological parameters of highly flowable mortar under light pressure conditions. Cem Concr Res 40:235–241CrossRefGoogle Scholar
  56. Pera J, Husson S, Guilhot B (1999) Influence of finely ground limestone on cement hydration. Cem Concr Compos 21(2):99–105CrossRefGoogle Scholar
  57. Plank J, Sachsenhauser B, de Reese J (2010) Experimental determination of the thermodynamic parameters affecting the adsorption behaviour and dispersion effectiveness of PCE superplasticizers. Cem Concr Res 40:699–709CrossRefGoogle Scholar
  58. Rubio-Hernández FJ, Morales-Alcalde JM, Gómez-Merino AI (2013) Limestone filler/cement ratio effect on the flow behaviour of a SCC cement paste. Adv Cem Res 25(5):262–272CrossRefGoogle Scholar
  59. Rossomme J (2010) Effects of the interaction between superplasticizer, cement and limestone fillers on the rheology of cement based slurries. Master thesis, University of LiègeGoogle Scholar
  60. Şahmaran M, Christianti HA, Yaman IO (2006) The effect of chemical admixtures and mineral additives on the properties of self-compacting mortars. Cem Concr Compos 28:432–440CrossRefGoogle Scholar
  61. Sato T, Beaudoin JJ (2011) Effect of nano-CaCO3 on hydration of cement containing supplementary cementitious materials. Adv Cem Res 23(1):33–43CrossRefGoogle Scholar
  62. Schmidt T, Lothenbach B, Romer M, Scrivener K, Rentsch D, RenFigi R (2008) A thermodynamic and experimental study of the conditions of thaumasite formation. Cem Concr Res 38:337–349CrossRefGoogle Scholar
  63. Soria EA, Rahhal VF (2003) Cast in place temperature’s influence on fresh concrete made with limestone filler and blended cement. Materiales de Construcción 53(271–272):27–36CrossRefGoogle Scholar
  64. Steenberg M, Herfort D, Poulsen S, Skibsted J, Damtoft JS (2011) Composite cement based on Portland cement clinker, limestone and calcined clay. In: XIII international congress on the chemistry of cement, July 2011, p 97Google Scholar
  65. Tennis PD, Thomas MDA, Weiss WJ (2011) State of the art report on use of limestone in cements at levels of up to 15%, Portland Cement Association, PCA R&D Serial No. SN3148Google Scholar
  66. Tobes JM, López A, Giaccio G, Barragán B, Zerbino R (2007) Effect of sand particle size distribution on fluidity and passing ability of highly flowable mortars. In: Proceeding of 5th international RILEM symposium on self-compacting concrete, 3–5 September 2007, Ghent, Belgium, pp 163–168Google Scholar
  67. Torres SM, Leal AF, Vieira APP, Barbosa NP (2011) Thaumasite form of sulphate attack in a tropical climate weather. In: Palomo A (ed) 13th ICCC international congress on the chemistry of cement, Madrid (paper 901), p 401Google Scholar
  68. Torresan I, Magarotto R, Zeminian N (2000) Interaction between superplasticizers and limestone blended cements rheological study. ACI Special Publication 195:229–248Google Scholar
  69. Uysal M, Yilmaz K (2011) Effect of mineral admixtures on properties of self-compacting concrete. Cem Concr Compos 33:771–776Google Scholar
  70. Valcuende M, Parra C, Marco E, Garrido A, Martínez E, Cánoves J (2012) Influence of limestone filler and viscosity-modifying admixture on the porous structure of self-compacting concrete. Constr Build Mater 28:122–128CrossRefGoogle Scholar
  71. Vieira M, Bettencourt A (2007) Rheology of pastes and mortars with fines resulting from ornamental rock waste. In: Proceeding of 5th international RILEM symposium on self-compacting concrete, 3–5 September 2007, Ghent, Belgium, pp 279–284Google Scholar
  72. Voglis N, Kakali G, Chaniotakis E, Tsivilis S (2005) Portland-limestone cements. Their properties and hydration compared to those of other composite cements. Cem Concr Compos 27:191–196CrossRefGoogle Scholar
  73. Wong HHC, Kwan AKH (2008) Packing density of cementitious materials: part 1—measurement using a wet packing method. Mater Struct 41:689–701CrossRefGoogle Scholar
  74. Yahia A, Tanimura M, Shimoyama Y (2005a) Rheological properties of highly flowable mortar containing limestone filler-effect of powder content and W/C ratio. Cem Concr Res 35:532–539CrossRefGoogle Scholar
  75. Yahia A, Tanimura M, Khayat KH (2005b) Experiment design to evaluate the effect of mixture parameters on rheological properties of self-comsolidating concrete equivalent mortar. In: Proceeding of 1st international symposium on design, performance and use of self-consolidating concrete, 26–28 May 2005, Changsha, China, pp 271–282Google Scholar

Standards

  1. ASTM C150/C150M-15, Standard Specification for Portland Cement, ASTM International, West Conshohocken, PA, 2015, www.astm.org
  2. ASTM C595/C595M-09, Standard Specification for Blended Hydraulic Cements, ASTM International, West Conshohocken, PA, 2009, www.astm.org
  3. ASTM C230/C230M-14, Standard Specification for Flow Table for Use in Tests of Hydraulic Cement, ASTM International, West Conshohocken, PA, 2014, www.astm.orgBS 8500-1:2015. Concrete. Complementary British Standard to BS EN 206. Method of specifying and guidance for the specifier
  4. BS 8500-2:2015. Concrete. Complementary British Standard to BS EN 206. Specification for constituent materials and concreteGoogle Scholar
  5. DS/INF 158:2004, Concrete technology—Compilation of DS/EN 206-1 and DS 2426 together with DS/EN 206-1/A1 (in Danish)Google Scholar
  6. EN 197-1:2011. Cement—Part 1: Composition, specifications and conformity criteria for common cements.Google Scholar
  7. EN 206-1:2000. Concrete—Part 1: Specification, performance, production and conformityGoogle Scholar
  8. EN 933-9+A1: 2013. Tests for geometrical properties of aggregates. Assessment of fines. Methylene blue testGoogle Scholar

Copyright information

© RILEM 2018

Authors and Affiliations

  1. 1.Department of Architecture, Geology, Environment and ConstructionsUniversity of LiègeLiegeBelgium
  2. 2.Aalborg Portland A/SAalborgDenmark
  3. 3.Department of Concrete TechnologyLEMITLa PlataArgentina
  4. 4.Magnel Laboratory for Concrete ResearchGhent UniversityZwijnaardeBelgium

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