Abstract
Carbohydrates or saccharides (from the Greek word sakkharon meaning sugar) occur in plant and animal tissues as well as in microorganisms; as macronutrients they are the human body’s preferred energy source, providing fuel for the central nervous system and energy for working muscles. Carbohydrates also serve as (1) a short-term energy source for all organisms, (2) structural molecules in plants, and (3) storage forms of foods in plants and animals. Carbohydrates are technically hydrates of carbon with the empirical formula Cm(H2O)n (where m could be different from n), but structurally they are more accurately viewed as polyhydroxy aldehydes and ketones. Carbohydrates can be divided into three chemical groups: monosaccharides, oligosaccharides, and polysaccharides, with the first being small (lower molecular weight) and commonly referred to as simple sugars. Carbohydrates in food can also be classified as simple or complex, with the difference between the two forms being the chemical structure and how quickly they are absorbed and digested. In animal organisms, the main sugar is glucose and the storage carbohydrate is glycogen; in milk, the main sugar is almost exclusively the disaccharide lactose. In plant organisms, a wide variety of monosaccharides and oligosaccharides occur, as well as storage polysaccharides such as starch, and structural polysaccharides such as cellulose and hemicellulose. Gums are a varied group of polysaccharides obtained from plants, seaweeds, and microorganisms. Because of their useful physical properties, the gums have found widespread application in food processing. The main carbohydrates that occur in a number of example food products are listed in Table 4.1.
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References
Anon. (2017). Glycemic index. Wikipedia. Retrieved from https://en.wikipedia.org/wiki/Glycemic_index.
Angyal, S. J. (1976). Conformational analysis in carbohydrate chemistry III. The 13C NMR spectra of hexuloses. Australian Journal of Chemistry, 29, 1249–1265.
Angyal, S. J. (1984). The composition of reducing sugars in solution. Advances in Carbohydrate Chemistry and Biochemistry, 42, 15–68.
Ao, M., Franco, O. E., Park, D., Raman, D., Williams, K., & Hayward, S. W. (2007). Cross-talk between paracrine-acting cytokine and chemokine pathways promotes malignancy in benign human prostatic epithelium. Cancer Research, 67(9), 4244–4253.
Association of Official Analytical Chemists Collaborative Study. (1984). Total dietary fiber method. Washington, DC: Association of Official Analytical Chemists.
Astray, G., Gonzalez-Barreiro, C., Mejuto, J. C., & Rial-Otero, R. (2009). A review on the use of cyclodextrins in foods. Food Hydrocolloids, 23, 1631–1640.
Barcza, A., Rohonczy, J., Rozlosnik, N., Lovas, G., Braun, T., Samu, J., & Barcza, L. (2001). Aqueous solubilization of [60] fullerene via inclusion complex formation and the hydration of C60. Journal of the Chemical Society, Perkin Transactions, 2, 191–196.
BeMiller, J. N., Huber, K. C., Damodaran, K. L., Parkin, O. R., Food, S., & Fourth, C. (2008). Fennema’s food chemistry. In S. Damodaran, K. L. Parkin, & O. R. Fennema (Eds.), (4th ed., pp. 84–151). Boca Raton, FL: CRC/Taylor and Francis.
Bertoft, E. (2004). On the nature of categories of chains in amylopectin and their connection to the super helix model. Carbohydrate Polymers, 57, 211–224.
Bertoft, E., Piyachomkwan, K., Chatakanonda, P., & Sriroth, K. (2008). Internal unit chain composition in amylopectins. Carbohydrate Polymers, 74, 527–543.
Blankers, I. (1995). Properties and applications of lactitol. Food Technology, 49, 66–68.
Blazek, J. D., Gaddy, A., Meyer, R., Roper, R. J., & Li, J. (2011). Disruption of bone development and homeostasis by trisomy in Ts65Dn Down syndrome mice. Bone, 48(2), 275–280.
Boyd, W. (2016). Color it natural. Prepared Foods, June edition, 90–102.
Buléon, A., Colonna, P., Planchot, V., & Ball, S. (1998). Starch granules: structure and biosynthesis. International Journal of Biological Macromolecules, 23(2), 85–112.
Campbell, L. A., & Palmer, G. H. (1978). Pectin. In G. A. Spiller & R. J. Amen (Eds.), Topics in dietary fiber research. New York: Plenum Press.
Chung, H., & Liu, Q. (2009). Impact of molecular structure of amylopectin and amylose on amylose chain association during cooling. Carbohydrate Polymers, 770, 807–815.
Clarke, M., Edye, L., & Eggleston, G. (1997). Sucrose decomposition in aqueous solution and product loss in sugar manufacture and refining. Advances in Carbohydrate Chemistry and Biochemistry, 52, 441–470.
Cole, M., Eggleston, G., Gilbert, A., & Chung, Y. (2016). Development of an analytical method to measure insoluble and soluble starch in sugarcane and sweet sorghum products. Food Chemistry, 190, 50–59.
Commerford, J. D. (1974). Com sweetener industry. In I. E. Inglett (Ed.), Symposium: Sweeteners. Westport, CT: AVI Publishing.
Copeland, L., Blazek, J., Salman, H., & Tang, M. C. (2009). Form and functionality of starch. Food Hydrocolloids, 23, 1527–1534.
Cunningham, M., & Dorée, C. (1917). Contributions to the chemistry of caramel. Part I. Caramelan. Journal of the Chemical Society, Transactions, 111, 589–608.
Damager, I., Engelsen, S. B., Blennow, A., Møller, B. L., & Motawia, M. S. (2010). First principles insight into the alpha-glucan structures of starch: their synthesis, conformation, and hydration. Chemical Reviews, 110(4), 2049–2080.
D’Appolonia, B. L., et al. (1971). Carbohydrates. In Y. Pomeranz (Ed.), Wheat: chemistry and technology. St. Paul, MN: American Association of Cereal Chemists.
Dea, I. C. M., Morris, E. R., Rees, D. A., Welsh, E. J., Barnes, H. A., & Price, J. (1977). Associations of like and unlike polysaccharides: Mechanism and specificity in galactomannans, interacting bacterial polysaccharides, and related systems. Carbohydrate Research, 57, 249.
Dea, I. C. M., & Morrison, A. (1975). Chemistry and interactions of seed galactomannans. Advances in Carbohydrate Chemistry and Biochemistry, 31, 241–312.
deMan, J. M., Stanley, D. W., & Rasper, V. (1975). Composition of Ontario soybeans and soymilk. Canadian Institute of Food Science and Technology Journal, 8, 1–8.
deMan, L., deMan, J. M., & Buzzell, R. I. (1987). Composition and properties of soymilk and tofu made from Ontario light hilum soybeans. Canadian Institute of Food Science and Technology Journal, 20, 363–367.
Descamps, O., Langevin, P., & Combs, D. H. (1986). Physical effect of starch/carrageenan interactions in water and milk. Food Technology, 40(4), 81–88.
Dreher, M. L. (1987). Handbook of dietary fiber: An applied approach. New York: Marcel Dekker.
Dziezak, J. D. (1987). Crystalline fructose: A breakthrough in corn sweetener process technology. Food Technology, 41(1), 66–67, 72.
Eggleston, G. (2008). Sucrose and related oligosaccharides. In K. T. Fraser-Reid & J. Thiem (Eds.), Glycoscience (pp. 1163–1182). Berlin: Springer-Verlag. Chapter 5.
Eggleston, G., & Côté, G. (2003). Oligosaccharides in food and agriculture. In G. Eggleston & G. Côté (Eds.), Oligosaccharides in food and agriculture, ACS Symposium Series 849 (pp. 1–64). Oxford: Oxford University Press. Chapter 1.
Eggleston, G., Monge, A., & Ogier, B. (2003). Sugarcane factory performance of cold, intermediate, and hot lime clarification systems. Journal of Food Processing and Preservation, 26, 433–454.
Eggleston, G., Legendre, B. L., & Godshall, M. A. (2017). Sugars and other sweeteners. In Handbook of industrial chemistry and biotechnology (13th ed.). Boston, MA: Springer. in press.
Englyst, H. N., Kingman, S. M., & Cummings, J. H. (1992). Classification and measurement of nutritionally important starch fractions. European Journal of Clinical Nutrition, 46(2), 33–35.
Englyst, H. N., Trowell, H., Southgate, D. A. T., & Cummings, J. H. (1987). Dietary fiber and resistant starch. The American Journal of Clinical Nutrition, 46, 873.
Feather, M. S., & Harris, J. F. (1973). Dehydration reactions of carbohydrates. Advances in Carbohydrate Chemistry and Biochemistry, 28, 161–224.
Furda, I. (1981). Simultaneous analysis of soluble and insoluble dietary fiber. In W. P. I. James & O. Theander (Eds.), The analysis of dietary fiber in food. New York: Marcel Dekker.
Gelis, M. A. (1858). Technical study of caramel. Annales de Chimie Physique, 3, 352–404.
Gidley, M. J., Hanashiro, I., Hani, N. M., Hill, S. E., Huber, A., Jane, J.-L., Liu, Q., Morris, G. A., Striegel, A. M., & Gilbert, R. G. (2010). Reliable measurements of the size distributions of starch molecules in solution: Current dilemmas and recommendations. Carbohydrate Polymers, 79, 255–261.
Glicksman, M. (1969). Gum technology in the food industry. New York: Academic Press.
Hedges, A. R. (1998). Industrial applications of cyclodextrins. Chemical Reviews, 98(5), 2035–2044.
Heume, M., & Rapaille, A. (1996). Versatility of maltitol in different forms as a sugar substitute. In T. H. Grenby (Ed.), Advances in sweeteners. London: Blackie Academic and Professional.
Hoover, R. (2001). Composition, molecular structure, and physicochemical properties of tuber and root starches: A review. Carbohydrate Polymers, 45, 253–267.
Hoseny, R. C. (1984). Functional properties of pentosans in baked foods. Food Technology, 38(1), 114–117.
Hudson, C. S. (1907). Catalysis by acids and bases of the mutarotation of glucose. Journal of the American Chemical Society, 29, 1571–1574.
Imbert, A., Chanzy, H., Pérez, S., Buléon, A., & Tran, V. (1988). The double-helical nature of the crystalline part of A-starch. Journal of Molecular Biology, 201(2), 365–378.
Ink, S. L., & Hurt, H. D. (1987). Nutritional implications of gums. Food Technology, 41(1), 77–82.
Jansson, P. E., Kenne, L., & Lindberg, B. (1975). Structure of the extracellular polysaccharide from Xanthomonas campestris. Carbohydrate Research, 45, 275–282.
Jenness, R. (1959). In S. Patton (Ed.), Principles of dairy chemistry. New York: Wiley.
Jobling, S. (2004). Improving starch for food and industrial applications. Current Opinion in Plant Biology, 7(2), 210–218.
Juna, S., Williams, P. A., & Davies, S. (2011). Determination of molecular mass distribution of amylopectin using asymmetrical flow field-flow fractionation. Carbohydrate Polymers, 83, 1384–1396.
Jurch Jr., G. R., & Tatum, J. H. (1970). Degradation of D-glucose with acetic acid and methyl amine. Carbohydrate Research, 15, 233–239.
Kandler, O., & Hopf, H. (1980). In J. Preiss (Ed.), The biochemistry of plants (Vol. 3, pp. 221–270). New York: Academic Press.
Kennedy, J. F. (1985). Oligosaccharide component composition and storage properties of commercial low DE maltodextrins and their further modification by enzymatic treatment. Starch, 37, 343–351.
Kirkensgaard, K. G., Hägglund, P., Shahpiri, A., Finnie, C., Henriksen, A., & Svensson, B. (2014). A novel twist on molecular interactions between thioredoxin and nicotinamide adenine dinucleotide phosphate-dependent thioredoxin reductase. Proteins, 82(4), 607–619.
Lappalainen, M., Pitkanen, I., Heikkila, H., & Nurmi, J. (2006). Melting behavior and evolved gas analysis of xylose. Journal of Thermal Analysis and Calorimetry, 84, 367–376.
Lehmann, U., & Robin, F. (2007). Slowly digestible starch—Its structure and health implications: A review. Trends in Food Science & Technology, 18, 346–355.
Li, J.-Y., & Yeh, A. I. (2001). Relationships between thermal, rheological characteristics and swelling power for various starches. Journal of Food Engineering, 50, 141–148.
Lomako, J., Lomako, W. M., & Whelan, W. J. (2004). Glycogenin: the primer for mammalian and yeast glycogen synthesis. Biochimica et Biophysica Acta, 1673, 45–55.
Luallen, T. E. (1985). Starch as a functional ingredient. Food Technology, 39(1), 59–63.
Manners, D. J. (1991). Recent developments in our understanding of glycogen structure. Carbohydrate Polymers, 16, 37–82.
Martin, L. F. (1955). Applications of research to problems of candy manufacture. Advances in Food Research, 6, 1–66.
McArdle, W. D., Katch, F. I., & Katch, V. I. (2006). Exercise physiology: energy, nutrition, and human performance (6th ed.p. 12). Baltimore, MD: Lippincott Williams & Wilkins.
Melton, L. D., Mindt, L., Rees, D. A., & Sanderson, G. R. (1976). Covalent structure of the extracelluloar polysaccharide of Xanthomonas campestris: evidence from partial hydrolysis studies. Carbohydrate Research, 46, 245–257.
Mleko, S., Li-Chan, E. C. Y., & Pikus, S. (1997). Interaction of carrageenan with whey proteins in gels formed at different pH. Food Research International, 30, 427–434.
Morris, E. R., Rees, D. A., Young, G., Walkinshaw, M. D., & Darke, A. (1977). Order-disorder transition for a bacterial polysaccharide in solution. A role for polysaccharide conformation in recognition between Xanthomonas pathogen and its plant host. Carbohydrate Research, 110, 1–16.
Oates, C. G. (1997). Towards an understanding of starch granule structure and hydrolysis. Trends in Food Science and Technology, 8, 375–382.
Okenfull, D. G. (1991). The chemistry of high methoyxl pectins. In R. H. Walter (Ed.), The chemistry and technology of pectin. New York: Academic Press.
Olsen, H. S. (1995). Enzymic production of glucose syrups. In M. W. Kearsley & S. Z. Dziedzic (Eds.), Handbook of starch hydrolysis products and their derivatives. London: Chapman and Hall.
Parker, R., & Ring, S. G. (2001). Aspects of the physical chemistry of starch. Journal of Cereal Science, 34, 1–17.
Pictet, A., & Strieker, P. (1924). Constitution and synthesis of isosacchrosan. Helvetica Chimica Acta, 7, 708–713.
Pictet, A., & Adrianoff, N. (1924). De l’action de la chaleur sur le saccharose. Helvetica Chimica Acta, 7, 703–707.
Pollard, A., & Timberlake, C. F. (1971). Fruit juices. In A. C. Hulme, A. Pollard, & C. F. Timberlake (Eds.), The biochemistry of fruits and their products. New York: Academic Press.
Pszczola, D. E. (1988). Production and potential food applications of cyclodextrins. Food Technology, 42(1), 96–100.
Raemy, A., Hurrell, R. F., & Löliger, J. (1983). Thermal behavior of milk powders studied by differential thermal analysis and heat flow calorimetry. Thermochimica Acta, 65, 81–92.
Raghavan, S. L., Ristic, R. I., Sheen, D. B., Sherwood, J. N., Trowbridge, L., & York, P. (2000). Morphology of crystals of α-lactose hydrate grown from aqueous solution. Journal of Physical Chemistry B, 104, 12256–12262.
Ranhotra, G. S., Gelroth, J. A., Astroth, K., & Eisenbraun, G. J. (1991). Effect of resistant starch on intestinal responses in rats. Cereal Chemistry, 68, 130.
Rees, D. (1977). Polysaccharide shapes outline studies in biology. London: Chapman and Hill.
Roos, Y. H., & Karel, M. (1991a). Amorphous state and delayed ice formation in sucrose solutions. International Journal of Food Science and Technology, 26, 553–566.
Roos, Y. H., & Karel, M. (1991b). Phase transitions of amorphous sucrose and frozen sucrose solutions. Journal of Food Science, 56, 266–267.
Roos, Y. H., & Karel, M. (1991c). Phase transitions of mixtures of amorphous polysaccharides and sugars. Biotechnology Progress, 7, 49–53.
Roos, Y. H., & Karel, M. (1991d). Water and molecular weight effects on glass transitions in amorphous carbohydrates and carbohydrate solutions. Journal of Food Science, 56, 1676–1681.
Roos, Y. H., & Karel, M. (1992). Crystallization of amorphous lactose. Journal of Food Science, 57, 775–777.
Roos, Y. H. (1993). Melting and glass transitions of low molecular weight carbohydrates. Carbohydrate Research, 238, 39–48.
Sabadini, E., Cosgrove, T., & Egídio Fdo, C. (2006). Solubility of cyclomaltooligosaccharides (cyclodextrins) in H2O and D2O: a comparative study. Carbohydrate Research, 341(2), 270–274.
Sajilata, G., Singhal, R. S., & Kulkarni, P. R. (2010). Resistant starch. A review. Comprehensive Reviews in Food Science, 5, 1–17.
Sarkanen, K. V., & Ldwig, C. H. (1971). Lignins: Occurrence, formation, structure and reactions. New York: Wiley Interscience.
Schneeman, B. O. (1986). Dietary fiber: Physical and chemical properties, methods of analysis, and physiological effects. Food Technology, 40(2), 104–110.
Sengar, G., & Sharma, H. K. (2014). Food caramels: A review. Journal of Food Science and Technology, 51(9), 1686–1696.
Shallenberger, R. S., & Birch, G. G. (1975). Sugar chemistry. Westport, CT: AVI Publishing.
Singh, N., Singh, J., Kaur, L., Singh Sodhi, N., & Singh Gill, B. (2003). Morphological, thermal and rheological properties of starches from different botanical sources. Food Chemistry, 81, 219–231.
Smidsrod, O. (1974). Molecular basis for some physical properties of alginates in the gel state. Faraday Discussions of the Chemical Society, 57, 263–274.
Smiles, R. E. (1982). The functional applications of polydextrose. In G. Charalambous & G. Inglett (Eds.), Chemistry of foods and beverages: Recent developments. New York: Academic Press.
Smythe, B. M. (1971). Sucrose crystal growth. Sugar Technology Reviews, 1, 191–231.
Southgate, D. A. T. (1981). Use of the Southgate method for unavailable carbohydrate in the measurement of dietary fiber. In W. P. I. James & O. Theander (Eds.), The analysis of dietary fiber in food. New York: Marcel Dekker.
Spiegel, J. E., Rose, R., Karabell, P., Frankos, V. H., & Schmitt, D. F. (1994). Safety and benefits of fructooligosaccharides as food ingredients. Food Technology, 48(1), 85–89.
Stephen, A. M. (1995). Food polysaccharides and their applications. New York: Marcel Dekker.
Szejtli, J. (1984). Highly soluble β-cyclodextrin derivatives. Starch, 36, 429–432.
Tang, H., Mitsunaga, T., & Kawamura, Y. (2006). Molecular arrangement in blocklets and starch granule architecture. Carbohydrate Polymers, 63, 555–560.
Thompson, A. (1954). Acid reversion products from D-glucose. Journal of the American Chemical Society, 76, 1309–1311.
van Soest, P. J. (1963). Use of detergents in the analysis of fibrous seeds. II. A rapid method for the determination of fiber and lignin. Journal of Association of Official Analytical Chemists, 48, 829–835.
van de Velde, F., van Riel, J., & Tromp, R. H. (2002). Visualisation of starch granule morphologies using confocal scanning laser microscopy (CSLM). Journal of the Science of Food and Agriculture, 82(13), 1528–1536.
von Elbe, G. (1936). The nature of sucrose caramel. Journal of the American Chemical Society, 58, 600–601.
Vorwerg, W., Radosta, S., & Leibnitz, E. (2002). Study of a preparative-scale process for the production of amylase. Carbohydrate Polymers, 47, 181–189.
Wang, B., Krafczyk, S., & Follner, H. (2000). Growth mechanism of sucrose in pure solutions and in the presence of glucose and fructose. Crystal Growth, 219, 67–74.
Washüttl, J., Reiderer, P., & Bancher, E. (1973). A qualitative and quantitative study of sugar-alcohols in several foods: A research role. Journal of Food Science, 38, 1262–1263.
Whistler, R. L., & Paschall, E. E. (1967). Starch: Chemistry and technology, Industrial aspects (Vol. 2). New York: Academic Press.
Whistler, R. L., & BeMiller, J. (1973). Industrial gums: Polysaccharides and their derivatives. New York: Academic Press.
Whitcomb, P. J., Ek, B. J., & Macosko, C. W. (1977). Rheology of xanthan gum solutions. Extracellular Microbial Polysaccharides, ACS Symposium Series, 45(12), 160–173.
Wu, H. C., & Sarko, A. (1978). The double helical molecular structure of crystalline A-amylose. Carbohydrate Research, 61, 7.
Wurzburg, O. B. (1995). Modified starches. In A. M. Stephen (Ed.), Food polysaccharides and their applications. New York: Marcel Dekker.
Ziesenitz, S. C. (1996). Basic structure and metabolism of isomalt. In T. H. Grenby (Ed.), Advances in sweeteners. London: Blackie Academic and Professional.
Zilversmit, D. B., Disease, R., Levy, B., & Press, N. Y. (1979). Dietary fiber. In R. Levy, B. Rifkind, B. Dennis, & N. Ernst (Eds.), Nutrition, lipids, and coronary heart disease (pp. 149–174). New York, NY: Raven Press.
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Eggleston, G., Finley, J.W., deMan, J.M. (2018). Carbohydrates. In: Principles of Food Chemistry. Food Science Text Series. Springer, Cham. https://doi.org/10.1007/978-3-319-63607-8_4
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