Skip to main content

Part of the book series: Springer Theses ((Springer Theses))

  • 467 Accesses

Abstract

In this chapter we apply 2DES to the organic material pentacene, which undergoes a novel process known as singlet fission.

Everything should be made as simple as possible, but not simpler.

Albert Einstein

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Hanna, M.C., Nozik, A.J.: Solar conversion efficiency of photovoltaic and photoelectrolysis cells with carrier multiplication absorbers. J. Appl. Phys. 100, 074510 (2006)

    Google Scholar 

  2. Bakulin, A.A., Morgan, S.E., Kehoe, T.B., Wilson, M.W.B., Chin, A.W., Zigmantas, D., Egorova, D., Rao, A.: Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electronic spectroscopy. Nat. Chem. 8, 16–23 (2016)

    Google Scholar 

  3. Wang, C., Dong, H., Hu, W., Liu, Y., Zhu, D.: Semiconducting \(\pi \)-conjugated systems in field-effect transistors: a material odyssey of organic electronics. Chem. Rev. 112, 2208–2267 (2012)

    Google Scholar 

  4. MacGillivray, L.: On substituents, steering, and stacking to control properties of the organic solid state. Cryst. Eng. Commun. 6, 77–78 (2004)

    Google Scholar 

  5. Saeed, Y., Zhao, K., Singh, N., Li, R., Anthony, J., Amassian, A., Schwingenschlögl, U.: Influence of substitution on the optical properties of functionalized pentacene monomers and crystals: experiment and theory. Chem. Phys. Lett. 585, 95–100 (2013)

    Google Scholar 

  6. Anthony, J.E., Eaton, D.L., Parkin, S.R.: A road map to stable, soluble, easily crystallized pentacene derivatives. Org. Lett. 4, 15–18 (2001)

    Google Scholar 

  7. Yost, S.R., Lee, J., Wilson, M.W.B., Wu, T., McMahon, D.P., Parkhurst, R.R., Thompson, N.J., Congreve, D.N., Rao, A., Johnson, K., Sfeir, M.Y., Bawendi, M.G., Swager, T.M., Friend, R.H., Baldo, M.A., Voorhis, T.V.: A transferable model for singlet-fission kinetics. Nat. Chem. 6, 492–497 (2014)

    Google Scholar 

  8. ChemSpider. CSID:10814431 (2015). http://www.chemspider.com/Chemical-Structure.10814431.html

  9. ChemSpider. CSID:28580083 (2015). http://www.chemspider.com/Chemical-Structure.28580083.html

  10. Smith, M.B., Michl, J.: Singlet fission. Chem. Rev. 110, 6891–6936 (2010)

    Google Scholar 

  11. Nozik, A.J. Multiple exciton generation in semiconductor quantum dots. Chem. Phys. Lett. 457, 3–11 (2008)

    Google Scholar 

  12. Wilson, M., Rao, A., Clark, J., Sai Santosh Kumar, R., Brida, D., Cerullo, G., Friend, R.: Ultrafast dynamics of exciton fission in polycrystalline pentacene. J. Am. Chem. Soc. 133, 11830–11833 (2011)

    Google Scholar 

  13. Chan, W.-L., Ligges, M., Zhu, X.-Y. The energy barrier in singlet fission can be overcome through coherent coupling and entropic gain. Nat. Chem. 4, 840–845 (2012)

    Google Scholar 

  14. Walker, B.J., Musser, A.J., Beljonne, D., Friend, R.H.: Singlet exciton fission in solution. Nat. Chem. 5, 1019–1024 (2013)

    Google Scholar 

  15. Zirzlmeier, J., Lehnherr, D., Coto, P.B., Chernick, E.T., Casillas, R., Basel, B.S., Thoss, M., Tykwinski, R.R., Guldi, D.M.: Singlet fission in pentacene dimers. Proc. Natl. Acad. Sci. 112, 5325–5330 (2015)

    Google Scholar 

  16. Merrifield, R.E., Avakian, P., Groff, R.P.: Fission of singlet excitons into pairs of triplet excitons in tetracene crystals. Chem. Phys. Lett. 3, 386–388 (1969)

    Google Scholar 

  17. Beljonne, D., Yamagata, H., Brédas, J.L., Spano, F.C., Olivier, Y.: Charge-transfer excitations steer the Davydov splitting and mediate singlet exciton fission in pentacene. Phys. Rev. Lett. 110, 226402 (2013)

    Google Scholar 

  18. Berkelbach, T.C., Hybertsen, M.S., Reichman, D.R.: Microscopic theory of singlet exciton fission. III. Crystalline pentacene. J. Chem. Phys. 141, 074705 (2014)

    Google Scholar 

  19. Smith, M.B., Michl, J.: Recent advances in singlet fission. Annu. Rev. Phys. Chem. 64, 361–386 (2013)

    Google Scholar 

  20. Král, K.: A note on triplet-triplet fission of singlet excitons in molecular crystals. J. Phys. B 22, 566 (1972)

    Google Scholar 

  21. Chan, W.-L., Ligges, M., Jailaubekov, A., Kaake, L., Miaja-Avila, L., Zhu, X.-Y. Observing the multiexciton state in singlet fission and ensuing ultrafast multielectron transfer. Science 334, 1541–1545 (2011)

    Google Scholar 

  22. Johnson, J.C., Nozik, A.J., Michl, J.: The role of chromophore coupling in singlet fission. Acc. Chem. Res. 46, 1290–1299 (2013)

    Google Scholar 

  23. Zimmerman, P.M., Zhang, Z., Musgrave, C.B.: Singlet fission in pentacene through multi-exciton quantum states. Nat. Chem. 2, 648–652 (2010)

    Google Scholar 

  24. Alguire, E.C., Subotnik, J.E., Damrauer, N.H.: Exploring non-Condon effects in a covalent tetracene dimer: How important are vibrations in determining the electronic coupling for singlet fission? J. Phys. Chem. A 119, 299–311 (2015)

    Google Scholar 

  25. Bayliss, S.L., Chepelianskii, A.D., Sepe, A., Walker, B.J., Ehrler, B., Bruzek, M.J., Anthony, J.E., Greenham, N.C.: Geminate and nongeminate recombination of triplet excitons formed by singlet fission. Phys. Rev. Lett. 112, 238701 (2014)

    Google Scholar 

  26. Wilson, M.W.B., Rao, A., Ehrler, B., Friend, R.H.: Singlet exciton fission in polycrystalline pentacene: from photophysics toward devices. Acc. Chem. Res. 46, 1330–1338 (2013)

    Google Scholar 

  27. Gisslen, L.: Influence of Frenkel excitons and charge transfer states on the spectroscopic properties of organic molecular crystals. Ph.D. thesis, Technische Universität München (2009)

    Google Scholar 

  28. Egorova, D., Thoss, M., Domcke, W., Wang, H.: Modeling of ultrafast electron-transfer processes: validity of multilevel Redfield theory. J. Chem. Phys. 119, 2761–2773 (2003)

    Google Scholar 

  29. Egorova, D., Kühl, A., Domcke, W.: Modeling of ultrafast electron-transfer dynamics: multi-level Redfield theory and validity of approximations. J. Chem. Phys. 268, 105–120 (2001)

    Google Scholar 

  30. Seibt, J., Pullerits, T.: Beating signals in 2D spectroscopy: electronic or nuclear coherences? Application to a quantum dot model system. J. Phys. Chem. C 117, 18728–18737 (2013)

    Google Scholar 

  31. Li, H., Bristow, A.D., Siemens, M.E., Moody, G., Cundiff, S.T.: Unraveling quantum pathways using optical 3D Fourier-transform spectroscopy. Nat. Commun. 4, 1390 (2013)

    Google Scholar 

  32. Song, Y., Hellmann, C., Stingelin, N., Scholes, G.D.: The separation of vibrational coherence from ground- and excited-electronic states in P3HT film. J. Chem. Phys. 142, 212410 (2015)

    Google Scholar 

  33. Musser, A.J., Liebel, M., Schnedermann, C., Wende, T., Kehoe, T.B., Rao, A., Kukura, P.: Evidence for conical intersection dynamics mediating ultrafast singlet exciton fission. Nat. Phys. 11, 352–357 (2015)

    Google Scholar 

  34. Fassioli, F., Nazir, A., Olaya-Castro, A.: Quantum state tuning of energy transfer in a correlated environment. J. Phys. Chem. Lett. 1, 2139–2143 (2010)

    Google Scholar 

  35. Christensson, N., Kauffmann, H.F., Pullerits, T., Mančal, T.: Origin of long-lived coherences in light-harvesting complexes. J. Phys. Chem. B 116, 7449–7454 (2012)

    Google Scholar 

  36. Tiwari, V., Peters, W.K., Jonas, D.M.: Electronic resonance with anticorrelated pigment vibrations drives photosynthetic energy transfer outside the adiabatic framework. Proc. Natl. Acad. Sci. 110, 1203–1208 (2013)

    Google Scholar 

  37. Chin, A., Prior, J., Rosenbach, R., Caycedo-Soler, F., Huelga, S., Plenio, M.: The role of non-equilibrium vibrational structures in electronic coherence and recoherence in pigment-protein complexes. Nat. Phys. 9, 113–118 (2013)

    Google Scholar 

  38. Butkus, V., Zigmantas, D., Abramavicius, D., Valkunas, L.: Distinctive character of electronic and vibrational coherences in disordered molecular aggregates. Chem. Phys. Lett. 587, 93–98 (2013)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sarah Elizabeth Morgan .

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer International Publishing AG

About this chapter

Cite this chapter

Morgan, S.E. (2017). 2D Spectroscopy of Pentacene Thin Films. In: Ultrafast Quantum Effects and Vibrational Dynamics in Organic and Biological Systems. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-63399-2_3

Download citation

Publish with us

Policies and ethics