Abstract
Nanotechnology has successfully gained applications in many areas of life, thereby seen as the modern way of creating products, which results in high efficiency of use. In the petroleum processing industries, this revolution is no exception. The efficiency of a number of conversion processes improves upon application of materials with the nanometer scale dimension, which is caused by improvements and developments of better material properties as the particle size decreases. In this chapter, the applications of nanotechnology through nanocatalysis in petro-refining processes are highlighted. This is exemplified by discussing the applications of nanotechnology in several typical petroleum refining processes, including catalytic cracking, oxidative dehydrogenation of alkanes, and desulfurization. Other processes for the production of clean fuels are also briefly reviewed. The key benefits of “nano-tech” application in catalysis are based on the exposure of a large surface area for reaction, thereby reducing the tendencies to adverse and side reactions. The desire for an improved catalyst with high activity, low deactivation, and low coke formation to meet the growing demand for chemicals and fuels necessitates the increasing exploitation of nanoparticles as catalysts.
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References
Askari S, Halladj R, Sohrabi M (2012) Methanol conversion to light olefins over sonochemically prepared SAPO-34 nanocatalyst. Micropor Mesopor Mater 163:334–342
Askari S, Alipour SM, Halladj R, Farahani MHDA (2013) Effects of ultrasound on the synthesis of zeolites: a review. J Porous Mater 20:285–302
Baghbanian SM, Farhang M, Vahdat SM, Tajbakhsh M (2015) Hydrogenation of arenes, nitroarenes, and alkenes catalyzed by rhodium nanoparticles supported on natural nanozeolite clinoptilolite. J Mol Catal A Chem 407:128–136
Bell AT (2003) The impact of nanoscience on heterogeneous catalysis. Science 299:1688–1691
Besenbacher F, Chorkendorff I, Clausen B, Hammer B, Molenbroek A, Nørskov JK, Stensgaard I (1998) Design of a surface alloy catalyst for steam reforming. Science 279:1913–1915
Bezemer GL, Bitter JH, Kuipers HP, Oosterbeek H, Holewijn JE, Xu X, Kapteijn F, van Dillen AJ, de Jong KP (2006) Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts. J Am Chem Soc 128:3956–3964
Busca G (2014) Metal oxides as acid-base catalytic materials. Elsevier, Amsterdam
Cheng K, Zhang L, Kang J, Peng X, Zhang Q, Wang Y (2015) Selective transformation of syngas into gasoline-range hydrocarbons over mesoporous H-ZSM-5-supported cobalt nanoparticles. Chem Eur J 21:1928–1937
Corma A, Lopez-Nieto J, Paredes N, Perez M, Shen Y, Cao H, Suib S (1992) Oxidative dehydrogenation of propane over supported-vanadium oxide catalysts. Stud Surf Sci Catal 72:213–220
Covarrubias C, Quijada R, Rojas R (2009) Synthesis of nanosized ZSM-2 zeolite with potential acid catalytic properties. Micropor Mesopor Mater 117:118–125
Database of Zeolite Structures. http://www.iza-structure.org/databases/
Davis ME, García-Martínez J, Li K (2015) Mesoporous zeolites: preparation, characterization and applications. Wiley, Weinheim
Farcasiu M, Degnan TF (1988) The role of external surface activity in the effectiveness of zeolites. Ind Eng Chem Res 27:45–47
Galvis HMT, Bitter JH, Khare CB, Ruitenbeek M, Dugulan AI, de Jong KP (2012) Supported iron nanoparticles as catalysts for sustainable production of lower olefins. Science 335:835–838
Gao Y, Wu G, Ma F, Liu C, Jiang F, Wang Y, Wang A (2016) Modified seeding method for preparing hierarchical nanocrystalline ZSM-5 catalysts for methanol aromatisation. Micropor Mesopor Mater 226:251–259
Grunes J, Zhu J, Somorjai GA (2003) Catalysis and nanoscience. Chem Commun 9(18):2257–2260
Guo K, Gu M, Yu Z (2017) Carbon nanocatalysts for aquathermolysis of heavy crude oil: insights into thiophene hydrodesulfurization. Energy Technol. doi:10.1002/ente.201600522
Haruta M, Daté M (2001) Advances in the catalysis of Au nanoparticles. Appl Catal A Gen 222:427–437
Hauser JL, Tran DT, Conley ET, Saunders JM, Bustillo KC, Oliver SR (2016) Plasma treatment of silver impregnated mesoporous aluminosilicate nanoparticles for adsorptive desulfurization. Chem Mater 28:474–479
Hirota Y, Murata K, Miyamoto M, Egashira Y, Nishiyama N (2010) Light olefins synthesis from methanol and dimethylether over SAPO-34 nanocrystals. Catal Lett 140:22–26
Hu Y, Liu C, Zhang Y, Ren N, Tang Y (2009) Microwave-assisted hydrothermal synthesis of nanozeolites with controllable size. Micropor Mesopor Mater 119:306–314
Inayat A, Knoke I, Spiecker E, Schwieger W (2012) Assemblies of mesoporous FAU-type zeolite nanosheets. Angew Chem Int Ed 51:1962–1965
Jacobsen CJ, Madsen C, Houzvicka J, Schmidt I, Carlsson A (2000a) Mesoporous zeolite single crystals. J Am Chem Soc 122:7116–7117
Jacobsen CJ, Madsen C, Janssens TV, Jakobsen HJ, Skibsted J (2000b) Zeolites by confined space synthesis—characterization of the acid sites in nanosized ZSM-5 by ammonia desorption and 27Al/29Si-MAS NMR spectroscopy. Micropor Mesopor Mater 39:393–401
Jiao F, Li J, Pan X, Xiao J, Li H, Ma H, Wei M, Pan Y, Zhou Z, Li M (2016) Selective conversion of syngas to light olefins. Science 351:1065–1068
Jo C, Jung J, Shin HS, Kim J, Ryoo R (2013) Capping with multivalent surfactants for zeolite nanocrystal synthesis. Angew Chem 125:10198–10201
Kamigaito O (1991) What can be improved by nanometer composites? J Jpn Soc Powder Powder Metall 38:315–321
Karakoulia SA, Triantafyllidis KS, Tsilomelekis G, Boghosian S, Lemonidou AA (2009) Propane oxidative dehydrogenation over vanadia catalysts supported on mesoporous silicas with varying pore structure and size. Catal Today 141:245–253
Khalil M, Lee RL, Liu N (2015) Hematite nanoparticles in aquathermolysis: a desulfurization study of thiophene. Fuel 145:214–220
Khodakov A, Yang J, Su S, Iglesia E, Bell AT (1998) Structure and properties of vanadium oxide-zirconia catalysts for propane oxidative dehydrogenation. J Catal 177:343–351
Khodakov A, Olthof B, Bell AT, Iglesia E (1999) Structure and catalytic properties of supported vanadium oxides: support effects on oxidative dehydrogenation reactions. J Catal 181:205–216
Konno H, Okamura T, Kawahara T, Nakasaka Y, Tago T, Masuda T (2012) Kinetics of n-hexane cracking over ZSM-5 zeolites—effect of crystal size on effectiveness factor and catalyst lifetime. Chem Eng J 207:490–496
Konno H, Tago T, Nakasaka Y, Ohnaka R, J-i N, Masuda T (2013) Effectiveness of nano-scale ZSM-5 zeolite and its deactivation mechanism on catalytic cracking of representative hydrocarbons of naphtha. Micropor Mesopor Mater 175:25–33
Kore R, Srivastava R, Satpati B (2014) ZSM-5 zeolite nanosheets with improved catalytic activity synthesized using a new class of structure-directing agents. Chem Eur J 20:11511–11521
Lei Y, Mehmood F, Lee S, Greeley J, Lee B, Seifert S, Winans RE, Elam JW, Meyer RJ, Redfern PC (2010) Increased silver activity for direct propylene epoxidation via subnanometer size effects. Science 328:224–228
Li YH, Zhu YQ (2012) Research progress of unsupported nano catalyst. Adv Mater Res 550–553:284–291. Trans Tech Publ
Li G, Jones CA, Grassian VH, Larsen SC (2005) Selective catalytic reduction of NO2 with urea in nanocrystalline NaY zeolite. J Catal 234:401–413
Lindsay S (2009) Introduction to nanoscience. Oxford University Press, New York
López C, Corma A (2012) Supported iron nanoparticles as catalysts for sustainable production of lower olefins. ChemCatChem 4:751–752
Lv Y, Qian X, Tu B, Zhao D (2013) Generalized synthesis of core-shell structured nano-zeolite@ ordered mesoporous silica composites. Catal Today 204:2–7
McHale J, Auroux A, Perrotta A, Navrotsky A (1997) Surface energies and thermodynamic phase stability in nanocrystalline aluminas. Science 277:788–791
Mehlhorn D, Inayat A, Schwieger W, Valiullin R, Kärger J (2014) Probing mass transfer in mesoporous faujasite-type zeolite nanosheet assemblies. ChemPhysChem 15:1681–1686
Mintova S, Olson NH, Valtchev V, Bein T (1999) Mechanism of zeolite A nanocrystal growth from colloids at room temperature. Science 283:958–960
Mintova S, Grand J, Valtchev V (2016) Nanosized zeolites: Quo Vadis? C R Chim 19:183–191
Mohajeri A, Rashidi A, Jozani KJ, Khorami P, Amini B, Parviz D, Kalbasi M (2010) Hydrodesulphurization nanocatalyst, its use and a process for its production. U.S. Patent No. 20100167915
Mohammed MI, Razak AAA, Shehab MA (2017) Synthesis of nanocatalyst for hydrodesulfurization of gasoil using laboratory hydrothermal rig. Arab J Sci Eng 42(4):1381–1387
Morales-Pacheco P, Domínguez J, Bucio L, Alvarez F, Sedran U, Falco M (2011) Synthesis of FAU (Y)-and MFI (ZSM5)-nanosized crystallites for catalytic cracking of 1, 3, 5-triisopropylbenzene. Catal Today 166:25–38
Ng E-P, Chateigner D, Bein T, Valtchev V, Mintova S (2012a) Capturing ultrasmall EMT zeolite from template-free systems. Science 335:70–73
Ng E-P, Goupil J-M, Al V, Fernandez C, Retoux R, Valtchev V, Mintova S (2012b) Nucleation and Crystal Growth Features of EMT-Type Zeolite Synthesized from an Organic-Template-Free System. Chem Mater 24:4758–4765
Pan Y, Ju M, Yao J, Zhang L, Xu N (2009) Preparation of uniform nano-sized zeolite A crystals in microstructured reactors using manipulated organic template-free synthesis solutions. Chem Commun 7233–7235. doi: 10.1039/b917949f
Park HJ, Jeon J-K, Kim JM, Lee HI, Yim J-H, Park J, Park Y-K (2008) Synthesis of nanoporous material from zeolite USY and catalytic application to bio-oil conversion. J Nanosci Nanotechnol 8:5439–5444
Peng X, Cheng K, Kang J, Gu B, Yu X, Zhang Q, Wang Y (2015) Impact of hydrogenolysis on the selectivity of the Fischer-Tropsch synthesis: diesel fuel production over mesoporous zeolite-Y-supported cobalt nanoparticles. Angew Chem 127:4636–4639
Persson AE, Schoeman BJ, Sterte J, Otterstedt JE (1994) The synthesis of discrete colloidal particles of TPA-silicalite-1. Zeolites 14:557–567
Rafiee E, Rezaei S (2016) Deep extractive desulfurization and denitrogenation of various model oils by H 3+nPMo12-nVnO40 supported on silica-encapsulated γ-Fe2O3 nanoparticles for industrial effluents applications. J Taiwan Inst Chem Eng 61:174–180
Rajagopalan K, Peters AW, Edwards GC (1986) Influence of zeolite particle size on selectivity during fluid catalytic cracking. Appl Catal 23:69–80
Rao C, Kulkarni G, Thomas PJ, Edwards PP (2002) Size-dependent chemistry: properties of nanocrystals. Chem Eur J 8:28–35
Rezvani MA, Shojaei AF, Zonoz FM (2014) Anatase titania–vanadium polyphosphomolybdate as an efficient and reusable nano catalyst for the desulphurization of gas oil. J Serb Chem Soc 79:1099–1110
Sakthivel A, Iida A, Komura K, Sugi Y, Chary KV (2009) Nanosized β-zeolites with tunable particle sizes: synthesis by the dry gel conversion (DGC) method in the presence of surfactants, characterization and catalytic properties. Micropor Mesopor Mater 119:322–330
Sartipi S, Alberts M, Santos VP, Nasalevich M, Gascon J, Kapteijn F (2014) Insights into the catalytic performance of mesoporous H-ZSM-5-supported cobalt in Fischer-Tropsch synthesis. ChemCatChem 6:142–151
Schlögl R, Abd Hamid SB (2004) Nanocatalysis: mature science revisited or something really new? Angew Chem Int Ed 43:1628–1637
Schmidt I, Madsen C, Jacobsen CJ (2000) Confined space synthesis. A novel route to nanosized zeolites. Inorg Chem 39:2279–2283
Schoeman B, Sterte J, Otterstedt J-E (1994) Colloidal zeolite suspensions. Zeolites 14:110–116
Serrano DP, van Grieken R, Melero JA, García A, Vargas C (2010) Nanocrystalline ZSM-5: a catalyst with high activity and selectivity for epoxide rearrangement reactions. J Mol Catal A Chem 318:68–74
Shroff MD, Kalakkad DS, Coulter KE, Kohler SD, Harrington MS, Jackson NB, Sault AG, Datye AK (1995) Activation of precipitated iron Fischer-Tropsch synthesis catalysts. J Catal 156:185–207
Steynberg A, Dry M (2004) Fischer-Tropsch technology. Elsevier, Amsterdam
Sudhakar C (1998) Selective hydrodesulfurization of cracked naphtha using novel catalysts. U.S Patent No. 5770046
Sun W, Wang L, Zhang X, Liu G (2015) Controllable synthesis of hierarchical beta nanozeolites from tailorable seeds. Micropor Mesopor Mater 201:219–227
Tang T, Zhang L, Fu W, Ma Y, Xu J, Jiang J, Fang G, Xiao F-S (2013) Design and synthesis of metal sulfide catalysts supported on zeolite nanofiber bundles with unprecedented hydrodesulfurization activities. J Am Chem Soc 135:11437–11440
Vajda S, Pellin MJ, Greeley JP, Marshall CL, Curtiss LA, Ballentine GA, Elam JW, Catillon-Mucherie S, Redfern PC, Mehmood F, Zapol P (2009) Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane. Nat Mater 8:213–216
Valden M, Lai X, Goodman DW (1998) Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science 281:1647–1650
Valtchev V, Tosheva L (2013) Porous nanosized particles: preparation, properties, and applications. Chem Rev 113:6734–6760
Vuong G-T, Hoang V-T, Nguyen D-T, Do T-O (2010) Synthesis of nanozeolites and nanozeolite-based FCC catalysts, and their catalytic activity in gas oil cracking reaction. Appl Catal A Gen 382:231–239
Wachs IE, Weckhuysen BM (1997) Structure and reactivity of surface vanadium oxide species on oxide supports. Appl Catal A Gen 157:67–90
Weisz PB (1995) Molecular diffusion in microporous materials: formalisms and mechanisms. Ind Eng Chem Res 34:2692–2699
Yang F, Deng D, Pan X, Fu Q, Bao X (2015) Understanding nano effects in catalysis. Natl Sci Rev 2:183–201
Yaripour F, Shariatinia Z, Sahebdelfar S, Irandoukht A (2015) Effect of boron incorporation on the structure, products selectivities and lifetime of H-ZSM-5 nanocatalyst designed for application in methanol-to-olefins (MTO) reaction. Micropor Mesopor Mater 203:41–53
Yin H, Zhou T, Liu Y, Chai Y, Liu C (2011) NiMo/Al2O3 catalyst containing nano-sized zeolite Y for deep hydrodesulfurization and hydrodenitrogenation of diesel. J Nat Gas Chem 20:441–448
Yin X, Chu N, Yang J, Wang J, Li Z (2014) Synthesis of the nanosized MCM-22 zeolite and its catalytic performance in methane dehydro-aromatization reaction. Catal Commun 43:218–222
Yin H, Liu X, Yao Y, Zhou T (2015) Nanosized HY zeolite-alumina composite support for hydrodesulfurization of FCC diesel. J Porous Mater 22:29–36
Yutthalekha T, Wattanakit C, Warakulwit C, Wannapakdee W, Rodponthukwaji K, Witoon T, Limtrakul J (2016) Hierarchical FAU-type zeolite nanosheets as green and sustainable catalysts for benzylation of toluene. J Clean Prod 142:1244–1251
Zhang YL, Jin XJ, Rong YH, Hsu TY, Jiang DY, Shi JL (2006) The size dependence of structural stability in nano-sized ZrO2 particles. Mater Sci Eng A 438–440:399–402
Zhang H, Chen B, Banfield JF (2009) The size dependence of the surface free energy of titania nanocrystals. Phys Chem Chem Phys 11:2553–2558
Zhang L, Fu W, Xiang M, Wang W, He M, Tang T (2015) MgO Nanosheet assemblies supported CoMo catalyst with high activity in hydrodesulfurization of dibenzothiophene. Ind Eng Chem Res 54:5580–5588
Zheng N, Stucky GD (2006) A general synthetic strategy for oxide-supported metal nanoparticle catalysts. J Am Chem Soc 128:14278–14280
Zhou B (2007) Nanotechnology in catalysis volumes 3. Springer, New York
Zhou X, Xu W, Liu G, Panda D, Chen P (2009) Size-dependent catalytic activity and dynamics of gold nanoparticles at the single-molecule level. J Am Chem Soc 132:138–146
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Etim, U.J., Bai, P., Yan, Z. (2018). Nanotechnology Applications in Petroleum Refining. In: Saleh, T. (eds) Nanotechnology in Oil and Gas Industries. Topics in Mining, Metallurgy and Materials Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-60630-9_2
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