Abstract
In the last decade, the organic–inorganic nanocomposite polymer electrolyte membranes (PEM) have gained high technical relevance in a wide range of fuel cells applications. The significance of nanocomposite membranes fabrication is particularly highlighted by the fact that one of the major challenges of this century is to provide well-performing and cost-effective membrane materials for fuel cells applications. Many efforts have been made in the development of advanced membranes with the aim to outperform the most commonly used polymer membranes. With the advances in nanomaterials and polymer chemistry, the innovative nanocomposite membranes with superior properties can be designed by various techniques including blending of nanoparticles in a polymer matrix, doping, or infiltration and precipitation of nanoparticles and precursors, self-assembly of nanoparticles, layer-by-layer fabrication method, and nonequilibrium impregnation reduction. This study presents a brief overview of these techniques and discusses the encountered challenges, the problems to be overcome, the major findings and guidance for future developments.
Keywords
- Nanocomposite
- Synthesis
- Membrane
- Preparation
- Fuel cell
This is a preview of subscription content, access via your institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Kim DJ, Jo MJ, Nam SY (2015) A review of polymer-nanocomposite electrolyte membranes for fuel cell application. J Ind Eng Chem 21:36–52
Hashemi F, Rowshanzamir S, Rezakazemi M (2012) CFD simulation of PEM fuel cell performance: effect of straight and serpentine flow fields. Math Comput Model 55:1540–1557
Kraytsberg A, Ein-Eli Y (2014) Review of advanced materials for proton exchange membrane fuel cells. Energy Fuels 28:7303–7330
Ng LY, Mohammad AW, Leo CP, Hilal N (2013) Polymeric membranes incorporated with metal/metal oxide nanoparticles: a comprehensive review. Desalination 308:15–33
Tripathi BP, Shahi VK (2011) Organic–inorganic nanocomposite polymer electrolyte membranes for fuel cell applications. Prog Polym Sci 36:945–979
Zhang H, Mao H, Wang J, Ding R, Du Z, Liu J, Cao S (2014) Mineralization-inspired preparation of composite membranes with polyethyleneimine–nanoparticle hybrid active layer for solvent resistant nanofiltration. J Membr Sci 470:70–79
Rezakazemi M, Ebadi Amooghin A, Montazer-Rahmati MM, Ismail AF, Matsuura T (2014) State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions. Prog Polym Sci 39:817–861
Rezakazemi M, Vatani A, Mohammadi T (2015) Synergistic interactions between POSS and fumed silica and their effect on the properties of crosslinked PDMS nanocomposite membranes. RSC Advances 5:82460–82470
Rezakazemi M, Vatani A, Mohammadi T. Synthesis and gas transport properties of crosslinked poly(dimethylsiloxane) nanocomposite membranes using octatrimethylsiloxy POSS nanoparticles. J Nat Gas Sci Eng
Rezakazemi M, Iravaninia M, Shirazian S, Mohammadi T (2013) Transient computational fluid dynamics (CFD) modeling of pervaporation separation of aromatic/aliphatic hydrocarbon mixtures using polymer composite membrane. Polym Eng Sci 53:1494–1501
Rezakazemi M, Shahverdi M, Shirazian S, Mohammadi T, Pak A (2011) CFD simulation of water removal from water/ethylene glycol mixtures by pervaporation. Chem Eng J 168:60–67
Rezakazemi M, Razavi S, Mohammadi T, Nazari AG (2011) Simulation and determination of optimum conditions of pervaporative dehydration of isopropanol process using synthesized PVA–APTEOS/TEOS nanocomposite membranes by means of expert systems. J Membr Sci 379:224–232
Rostamizadeh M, Rezakazemi M, Shahidi K, Mohammadi T (2013) Gas permeation through H2-selective mixed matrix membranes: Experimental and neural network modeling. Int J Hydrogen Energy 38:1128–1135
Rezakazemi M, Mohammadi T (2013) Gas sorption in H2-selective mixed matrix membranes: Experimental and neural network modeling. Int J Hydrogen Energy 38:14035–14041
Rezakazemi M, Shahidi K, Mohammadi T (2012) Hydrogen separation and purification using crosslinkable PDMS/zeolite A nanoparticles mixed matrix membranes. Int J Hydrogen Energy 37:14576–14589
Shahverdi M, Baheri B, Rezakazemi M, Motaee E, Mohammadi T (2013) Pervaporation study of ethylene glycol dehydration through synthesized (PVA–4A)/polypropylene mixed matrix composite membranes. Polym Eng Sci 53:1487–1493
Rezakazemi M, Shahidi K, Mohammadi T (2012) Sorption properties of hydrogen-selective PDMS/zeolite 4A mixed matrix membrane. Int J Hydrogen Energy 37:17275–17284
Basile A, Gallucci F (2011) Membranes for membrane reactors: preparation, optimization and selection. Wiley, UK
Baheri B, Shahverdi M, Rezakazemi M, Motaee E, Mohammadi T (2015) Performance of PVA/NaA mixed matrix membrane for removal of water from ethylene glycol solutions by pervaporation. Chem Eng Commun 202:316–321
Mulder M (1996) Basic principles of membrane technology, 2nd edn. Kluwer Academic Publishers, The Netherlands
Khulbe KC, Feng C, Matsuura T (2008) Synthetic polymeric membranes: characterization by atomic force microscopy. Springer, Berlin
Sadhukhan S (2011) Preparation and characterization of polymer electrolyte. National Institute of Technology, Rourkela
Caseri W (2007) Nanocomposites of polymers and inorganic particles. In: Hybrid materials, Wiley-VCH Verlag GmbH & Co. KGaA, pp 49–86
Tripathi BP (2010) Organic–inorganic nanocomposite polymer electrolyte membranes for electrochemical processes. Chemistry Department, Bhavnagar University
Hay JN, Raval HM (2001) Synthesis of organic−inorganic hybrids via the non-hydrolytic sol−gel process. Chem Mater 13:3396–3403
Pethaiah SS, Ulaganathan M, Ramalinga Viswanathan M, Chan SH (2015) Fabrication and electrochemical characterization of Pt–Pd impregnated nanocomposite polymer electrolyte membranes for high concentration DMFCs. RSC Adv 5:981–987
Koh JK, Jeon Y, Cho YI, Kim JH, Shul Y-G (2014) A facile preparation method of surface patterned polymer electrolyte membranes for fuel cell applications. J Mater Chem A 2:8652–8659
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2017 Springer International Publishing AG
About this chapter
Cite this chapter
Rezakazemi, M., Sadrzadeh, M., Mohammadi, T., Matsuura, T. (2017). Methods for the Preparation of Organic–Inorganic Nanocomposite Polymer Electrolyte Membranes for Fuel Cells. In: Inamuddin, D., Mohammad, A., Asiri, A. (eds) Organic-Inorganic Composite Polymer Electrolyte Membranes. Springer, Cham. https://doi.org/10.1007/978-3-319-52739-0_11
Download citation
DOI: https://doi.org/10.1007/978-3-319-52739-0_11
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-52738-3
Online ISBN: 978-3-319-52739-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)