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Amorphous Semiconductors: Structure, Optical, and Electrical Properties

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Springer Handbook of Electronic and Photonic Materials

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Abstract

This chapter is devoted to a survey of the structural, optical and electrical properties of amorphous semiconductors on the basis of their fundamental understanding. These properties are important for various types of applications using amorphous semiconductors.

First, we review general aspects of the electronic states and defects in amorphous semiconductors , i. e., a-Si:H and related materials, and chalcogenide glasses, and their structural, optical and electrical properties.

Further, we survey the two types of phenomena associated with amorphous structure, i. e., light-induced phenomena, and quantum phenomena associated with nanosized amorphous structure. The former are important from the viewpoint of amorphous-silicon solar cells. The latter phenomena promise novel applications of amorphous semiconductors from the viewpoint of nanotechnology.

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References

  1. N.F. Mott, E.A. Davis: Electronic Processes in Non-crystalline Materials, 2nd edn. (Clarendon, Oxford 1979)

    Google Scholar 

  2. K. Morigaki: Physics of Amorphous Semiconductors (World Scientific, Imperial College Press, Singapore, London 1999)

    Google Scholar 

  3. J. Singh, K. Shimakawa: Advances in Amorphous Semiconductors (Taylor Francis, London 2003)

    Google Scholar 

  4. S. Kugler, P.R. Surján, G. Náray-Szabó: Phys. Rev. B 37, 9069 (1988)

    CAS  Google Scholar 

  5. L. Ley, J. Reichardt, R.L. Johnson: Phys. Rev. Lett. 49, 1664 (1982)

    CAS  Google Scholar 

  6. L. Brey, C. Tejedor, J.A. Verges: Phys. Rev. Lett. 52, 1840 (1984)

    CAS  Google Scholar 

  7. L. Ley, S. Kawalczyk, R. Pollak, D.A. Shirley: Phys. Rev. Lett. 29, 1088 (1972)

    CAS  Google Scholar 

  8. M. Kastner, D. Adler, H. Fritzsche: Phys. Rev. Lett. 37, 1504 (1976)

    CAS  Google Scholar 

  9. K. Morigaki, M. Yamaguchi, I. Hirabayashi, R. Hayashi: Disordered Semiconductors, ed. by M.A. Kastner, G.A. Thomas, S.R. Ovshinsky (Plenum, New York 1987) p. 415

    Google Scholar 

  10. G.D. Cody: In: Semiconductors and Semimetals, Vol. 21, ed. by J.I. Pankove (Academic, Orlando 1984) p. 1 Part B

    Google Scholar 

  11. T. Tiedje: In: Semiconductors and Semimetals, Vol. 21, ed. by J.I. Pankove (Academic, Orlando 1984) p. 207 Part C

    Google Scholar 

  12. K. Winer, I. Hirabayashi, L. Ley: Phys. Rev. B 38, 7680 (1988)

    CAS  Google Scholar 

  13. K. Winer, I. Hirabayashi, L. Ley: Phys. Rev. Lett. 60, 2697 (1988)

    CAS  Google Scholar 

  14. K. Morigaki: In: Semiconductors and Semimetals, Vol. 21, ed. by J.I. Pankove (Academic, Orlando 1984) p. 155 Part C

    Google Scholar 

  15. K. Morigaki, M. Kondo: Solid State Phenom. 44-46, 731 (1995)

    CAS  Google Scholar 

  16. K. Morigaki, H. Hikita, M. Kondo: J. Non-Cryst. Solids 190, 38 (1995)

    CAS  Google Scholar 

  17. M. Yamaguchi, K. Morigaki, S. Nitta: J. Phys. Soc. Jpn. 58, 3828 (1989)

    CAS  Google Scholar 

  18. M. Yamaguchi, K. Morigaki, S. Nitta: J. Phys. Soc. Jpn. 60, 1769 (1991)

    CAS  Google Scholar 

  19. S.C. Moss, J.F. Graczyk: Proc. 10th Int. Conf. Phys. Semicond., ed. by J.C. Hensel, F. Stern (US AEC Div. Tech. Inform., Springfield 1970) p. 658

    Google Scholar 

  20. S. Kugler, G. Molnár, G. Petö, E. Zsoldos, L. Rosta, A. Menelle, R. Bellissent: Phys. Rev. B 40, 8030 (1989)

    CAS  Google Scholar 

  21. D.E. Polk: J. Non-Cryst. Solids 5, 365 (1971)

    CAS  Google Scholar 

  22. F. Wooten, K. Winer, D. Weaire: Phys. Rev. Lett. 54, 1392 (1985)

    CAS  Google Scholar 

  23. R. Car, M. Parrinello: Phys. Rev. Lett. 60, 204 (1988)

    CAS  Google Scholar 

  24. S. Kugler, L. Pusztai, L. Rosta, P. Chieux, R. Bellissent: Phys. Rev. B 48, 7685 (1993)

    CAS  Google Scholar 

  25. L. Pusztai: J. Non-Cryst. Solids 227-230, 88 (1998)

    CAS  Google Scholar 

  26. S. Kugler, K. Kohary, K. Kádas, L. Pusztai: Solid State Commun. 127, 305 (2003)

    CAS  Google Scholar 

  27. J.A. Reimer: J. Phys. (Paris) 42, C4–715 (1981)

    Google Scholar 

  28. K.K. Gleason, M.A. Petrich, J.A. Reimer: Phys. Rev. B 36, 3259 (1987)

    CAS  Google Scholar 

  29. G. Lucovsky, R.J. Nemanich, J.C. Knights: Phys. Rev. B 19, 2064 (1979)

    CAS  Google Scholar 

  30. R. Bellissent, A. Menelle, W.S. Howells, A.C. Wright, T.M. Brunier, R.N. Sinclair, F. Jansen: Physica B 156/157, 217 (1989)

    Google Scholar 

  31. A. Menelle: Thése Doctorat Ser. (Université Piere et Marie Curie, Paris 1987)

    Google Scholar 

  32. J.H. Zhou, K. Ikuta, T. Yasuda, T. Umeda, S. Yamasaki, K. Tanaka: J. Non-Cryst. Solids 227–230, 857 (1998)

    Google Scholar 

  33. T. Uchino: Kotai Butsuri (Solid State Physics) 37, 965 (2002)

    CAS  Google Scholar 

  34. G. Lucovsky, F.L. Galeener, R.H. Geils, R.C. Keezer: Proc. Int. Conf. Amorph. Liq. Semicond., ed. by W.E. Spear (University of Edinburgh, Edinburgh 1977) p. 127

    Google Scholar 

  35. J. Tauc: In: Amorphous and Liquid Semiconductors, ed. by J. Tauc (Plenum, New York 1974) p. 159

    Google Scholar 

  36. C. Tsang, R.A. Street: Phys. Rev. B 19, 3027 (1979)

    CAS  Google Scholar 

  37. K. Morigaki, Y. Sano, I. Hirabayashi: J. Phys. Soc. Jpn. 51, 147 (1982)

    CAS  Google Scholar 

  38. K. Morigaki, Y. Sano, I. Hirabayashi: In: Amorphous Semiconductor Technologies and Devices—1983, ed. by Y. Hamakawa (Ohomsha, Tokio 1983), Chap. 3.2

    Google Scholar 

  39. I. Hirabayashi, K. Morigaki, M. Yoshida: Sol. Ener. Mat. 8, 153 (1982)

    CAS  Google Scholar 

  40. M. Yamaguchi, K. Morigaki: Philos. Mag. B 79, 387 (1999)

    CAS  Google Scholar 

  41. G.H. Bauer: Solid State Phenom. 44-46, 365 (1995)

    CAS  Google Scholar 

  42. W. Paul: In: Amorphous Silicon and Related Materials, ed. by H. Fritzsche (World Scientific, Singapore 1989) p. 63

    Google Scholar 

  43. Y. Tawada: In: Amorphous Semiconductors – Technologies and Devices, ed. by Y. Hamakawa (Ohmusha, North Holland, Tokyo, Amsterdam 1983), Chap. 4.2

    Google Scholar 

  44. F. Demichelis, C.F. Pirri: Solid State Phenom. 44-46, 385 (1995)

    CAS  Google Scholar 

  45. K. Maeda, I. Umezu: J. Appl. Phys. 70, 2745 (1991)

    CAS  Google Scholar 

  46. M. Yamaguchi, K. Morigaki: Philos. Mag. B 79, 387 (1999)

    CAS  Google Scholar 

  47. B. Dunnett, D.I. Jones, A.D. Stewart: Philos. Mag. B 53, 159 (1986)

    CAS  Google Scholar 

  48. M. Hirose: Jpn. J. Appl. Phys. 21(suppl. 21-1), 297 (1981)

    Google Scholar 

  49. D. Engemann, R. Fischer: In: Amorphous and Liquid Semiconductors, ed. by J. Stuke, W. Brenig (Taylor Francis, London 1974) p. 947

    Google Scholar 

  50. D. Engemann, R. Fischer: Proc. 12th Int. Conf. Phys. Semicond., ed. by M.H. Pilkuhn (B.G. Teubner, Stuttgart 1974) p. 1042

    Google Scholar 

  51. R.A. Street, J.C. Knights, D.K. Biegelsen: Phys. Rev. B 18, 1880 (1978)

    CAS  Google Scholar 

  52. D.J. Dunstan, F. Boulitrop: Phys. Rev. B 30, 5945 (1984)

    CAS  Google Scholar 

  53. K. Morigaki: J. Non-Cryst. Solids 141, 166 (1992)

    CAS  Google Scholar 

  54. R. Stachowitz, M. Schubert, W. Fuhs: J. Non-Cryst. Solids 227--230, 190 (1998)

    Google Scholar 

  55. C. Ogihara: J. Non-Cryst. Solids 227--230, 517 (1998)

    Google Scholar 

  56. T. Aoki, T. Shimizu, S. Komedoori, S. Kobayashi, K. Shimakawa: J. Non-Cryst. Solids 338--340, 456 (2004)

    Google Scholar 

  57. M. Yoshida, M. Yamaguchi, K. Morigaki: J. Non-Cryst. Solids 114, 319 (1989)

    CAS  Google Scholar 

  58. M. Yoshida, K. Morigaki: J. Phys. Soc. Jpn. 58, 3371 (1989)

    CAS  Google Scholar 

  59. B.A. Wilson, P. Hu, T.M. Jedju, J.P. Harbison: Phys. Rev. B 28, 5901 (1983)

    CAS  Google Scholar 

  60. C. Ogihara, H. Takemura, H. Yoshida, K. Morigaki: J. Non-Cryst. Solids 266--269, 574 (2000)

    Google Scholar 

  61. H. Takemura, C. Ogihara, K. Morigaki: J. Phys. Soc. Jpn. 71, 625 (2002)

    CAS  Google Scholar 

  62. M. Yoshida, K. Morigaki: J. Non-Cryst. Solids 59/60, 357 (1983)

    Google Scholar 

  63. G. Pfister, H. Scher: Adv. Phys. 27, 747 (1978)

    CAS  Google Scholar 

  64. H. Scher, E.W. Montroll: Phys. Rev. B 12, 2455 (1975)

    CAS  Google Scholar 

  65. A. Feltz: Amorphous Inorganic Materials and Glasses (VCH, Weinheim 1993)

    Google Scholar 

  66. S.R. Elliott: In: Material Science and Technology, Vol. 9, ed. by R.W. Cahn et al. (VCH, Weinheim 1991) p. 376

    Google Scholar 

  67. H. Hosono, H. Maeda, Y. Kameshima, H. Kawazoe: J. Non-Cryst. Solids 227--230, 804 (1998)

    Google Scholar 

  68. I. Solomon: In: Amorphous Semiconductors, ed. by M.H. Brodsky (Springer, Berlin, Heidelberg, New York 1979) p. 189

    Google Scholar 

  69. K. Lips, C. Lerner, W. Fuhs: J. Non-Cryst. Solids 198-200, 267 (1996)

    CAS  Google Scholar 

  70. M. Stutzmann, M.S. Brandt, M.W. Bayerl: J. Non-Cryst. Solids 266--269, 1 (2000)

    Google Scholar 

  71. R.A. Street: Adv. Phys. 25, 397 (1976)

    CAS  Google Scholar 

  72. B.C. Cavenett: J. Non-Cryst. Solids 59/60, 125 (1983)

    Google Scholar 

  73. J. Ristein, P.C. Taylor, W.D. Ohlsen, G. Weiser: Phys. Rev. B 42, 11845 (1990)

    CAS  Google Scholar 

  74. D. Mao, W.D. Ohlsen, P.C. Taylor: Phys. Rev. B 48, 4428 (1993)

    CAS  Google Scholar 

  75. P.G. LeComber, D.I. Jones, W.E. Spear: Philos. Mag. 35, 1173 (1977)

    CAS  Google Scholar 

  76. H. Overhof, W. Beyer: Philos. Mag. B 44, 317 (1983)

    Google Scholar 

  77. N. Kishimoto, K. Morigaki: J. Phys. Soc. Jpn. 46, 846 (1979)

    CAS  Google Scholar 

  78. W. Beyer, J. Stuke: Proc. Int. Conf. Amorph. Liq. Semicond., 1973, ed. by J. Stuke (Taylor Francis, London 1974) p. 251

    Google Scholar 

  79. D.I. Jones, W.E. Spear, P.G. LeComber: J. Non-Cryst. Solids 20, 259 (1976)

    CAS  Google Scholar 

  80. N.F. Mott: J. Phys. C 13, 5433 (1980)

    CAS  Google Scholar 

  81. W.E. Spear, P.G. LeComber: Philos. Mag. 33, 935 (1976)

    CAS  Google Scholar 

  82. L. Friedman: J. Non-Cryst. Solids 6, 329 (1971)

    CAS  Google Scholar 

  83. D. Emin: Philos. Mag. 35, 1189 (1977)

    CAS  Google Scholar 

  84. N. Tohge, T. Minami, Y. Yamamoto, M. Tanaka: J. Appl. Phys. 51, 1048 (1980)

    CAS  Google Scholar 

  85. L. Tichy, H. Ticha, A. Triska, P. Nagels: Solid State Commun. 53, 399 (1985)

    CAS  Google Scholar 

  86. K. Shimakawa, A. Kolobov, S.R. Elliott: Adv. Phys. 44, 475 (1995)

    CAS  Google Scholar 

  87. K. Kimura, K. Murayama, T. Ninomiya: J. Non-Cryst. Solids 77/78, 1203 (1985)

    Google Scholar 

  88. D.L. Staebler, C.R. Wronski: Appl. Phys. Lett. 31, 292 (1977)

    CAS  Google Scholar 

  89. I. Hirabayashi, K. Morigaki, S. Nitta: Jpn. J. Appl. Phys. 19, L357 (1980)

    CAS  Google Scholar 

  90. H. Dersch, J. Stuke, J. Beichler: Appl. Phys. Lett. 38, 456 (1981)

    CAS  Google Scholar 

  91. M. Stutzmann, W.B. Jackson, C.C. Tsai: Phys. Rev. B 32, 23 (1985)

    CAS  Google Scholar 

  92. C. Godet, P. Roca i Cabarrocas: J. Appl. Phys. 80, 97 (1996)

    CAS  Google Scholar 

  93. H.M. Branz: Phys. Rev. B 59, 5498 (1999)

    CAS  Google Scholar 

  94. K. Morigaki, H. Hikita: Solid State Commun. 114, 69 (2000)

    CAS  Google Scholar 

  95. K. Morigaki, H. Hikita: J. Non-Cryst. Solids 266-269, 410 (2000)

    CAS  Google Scholar 

  96. K. Morigaki, H. Hikita: Proc. Int. Conf. Phys. Semicond., ed. by T. Ando, N. Miura (Springer, Berlin, Heidelberg, New York 2000) p. 1485

    Google Scholar 

  97. C. Ogihara, H. Takemura, T. Yoshimura, K. Morigaki: J. Non-Cryst. Solids 299-302, 637 (2002)

    CAS  Google Scholar 

  98. K. Morigaki, H. Hikita, H. Takemura, T. Yoshimura, C. Ogihara: Philos. Mag. Lett. 83, 341 (2003)

    CAS  Google Scholar 

  99. K. Morigaki, H. Hikita: J. Non-Cryst. Solids 299-302, 455 (2002)

    CAS  Google Scholar 

  100. T. Gotoh, S. Nonomura, M. Nishio, S. Nitta, M. Kondo, A. Matsuda: Appl. Phys. Lett. 72, 2978 (1998)

    CAS  Google Scholar 

  101. Y. Zhao, D. Zhang, G. Kong, G. Pan, X. Liao: Phys. Rev. Lett. 74, 558 (1995)

    Google Scholar 

  102. H. Fritzsche: Solid State Commun. 94, 953 (1995)

    CAS  Google Scholar 

  103. R. Biswas, Y.P. Li: Phys. Rev. Lett. 82, 2512 (1999)

    CAS  Google Scholar 

  104. K. Morigaki: Res. Bull. Hiroshima Inst. Tech. 35, 47 (2001)

    Google Scholar 

  105. K. Morigaki, H. Hikita, C. Ogihara: Light-Induced Defects in Semiconductors (Pan Stanford, Singapore 2014)

    Google Scholar 

  106. M. Yamaguchi, K. Morigaki: Phys. Rev. B 55, 2368 (1997)

    CAS  Google Scholar 

  107. C. Ogihara, H. Ohta, M. Yamaguchi, K. Morigaki: Philos. Mag. B 62, 261 (1990)

    CAS  Google Scholar 

  108. M. Yamaguchi, C. Ogihara, K. Morigaki: Mat. Sci. Eng. B 97, 135 (2003)

    Google Scholar 

  109. A.C. Gossard, M. Sundaram, P.F. Hopkins: In: Semiconductors and Semimetals, Vol. 40, ed. by A.C. Gossard (Academic, Boston, Tokio 1994), Chap. 2

    Google Scholar 

  110. N.-M. Park, C.-J. Choi, T.-Y. Seong, S.-J. Park: Phys. Rev. Lett. 86, 1355 (2001)

    CAS  Google Scholar 

  111. J. Koga, K. Nishio, T. Yamaguchi, F. Yonezawa: J. Phys. Soc. Jpn. 70, 3143 (2001)

    CAS  Google Scholar 

  112. R. Ionov, D. Nesheva, D. Arsova: J. Non-Cryst. Solids 137/138, 1151 (1991)

    Google Scholar 

  113. R. Ionov: Ph.D. Thesis (Technical Univ., Sofia 1993)

    Google Scholar 

  114. H. Hamanaka, S. Konagai, K. Murayama, M. Yamaguchi, K. Morigaki: J. Non-Cryst. Solids 198-200, 808 (1996)

    CAS  Google Scholar 

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Acknowledgements

We wish to thank M. Ichihara, K. Suzuki and M. Yamaguchi, Institute for Solid State Physics, University of Tokyo, for providing us with their unpublished materials (Fig. 24.7a,b). Stimulating and helpful discussions were held with Prof. S. Kugler during the stay of one of us (K.M.) at the Budapest University of Technology and Economics, for which K.M. is grateful.

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Authors and Affiliations

  1. University of Tokyo, Tokyo, Japan

    Kazuo Morigaki

  2. Graduate School of Science and Engineering, Yamaguchi University, Yamaguchi, Japan

    Chisato Ogihara

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  1. Kazuo Morigaki
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  2. Chisato Ogihara
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Correspondence to Kazuo Morigaki .

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Editors and Affiliations

  1. University of Saskatchewan, Saskatoon, Canada

    Safa Kasap

  2. Formerly with Leonardo MW Ltd, Southampton, UK

    Peter Capper

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Morigaki, K., Ogihara, C. (2017). Amorphous Semiconductors: Structure, Optical, and Electrical Properties. In: Kasap, S., Capper, P. (eds) Springer Handbook of Electronic and Photonic Materials. Springer Handbooks. Springer, Cham. https://doi.org/10.1007/978-3-319-48933-9_24

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