Abstract
Cellular composite products with a glassy matrix were produced in a single-step process using mixtures of clay with sludge obtained from the flocculation process for drinking water potabilisation. At high temperatures, where a sufficient amount of viscous liquid phase is present, porosity is generated spontaneously, presumably by the release of H2O from hydroxyl-containing minerals. This allows the trapping of gas bubbles in the liquid without the use foaming agents or templates. Two variants of the process were tested, one producing the material in a mould and the second one without mould. In the first case, the retaining pressure exercised by the mould limits the escape of gas trough the liquid phase and a highly porous material is produced. Without mould, more gas can escape and less porosity is generated, resulting in a lightweight, high strength material consisting of non-connected pores in a composite of mineral grains in a glassy matrix.
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References
J.M. Gómez de Salazar, M.I. Barrena, G. Morales, L. Matesanz, and N. Merino “Compression strength and wear resistance of ceramic foams-polymer composites.” Mater. Letters 60 (2006), 1687–1692.
H. Tian, and S. Ma, “Effects of exterior gas pressure on the structure and properties of highly porous SiOC ceramics derived from silicone resin,” Mater Letters 66 (2012), 13–15.
X. Zhu, D. Jiang, and S. Tan, “Improvement in the strength of reticulated porous ceramics by vacuum degassing,” Mater Letters 51 (2001), 363–367.
F. Yang, C. Li, Y. Lin, and C.A. Wang, “Effects of sintering temperature on properties of porous mullite/corundum ceramics,” Mater Letters, 73, (2012), 36–39.
A.R. Studart, U.T. Gonzenbach, E. Tervoort, and L.J. Gauckler, “Processing routes to macroporous ceramics: a review,” J Am Ceram Soc 89 (2006), 1771–1789.
Q. Z. Chen, I. D. Thompson, and A.R. Boccaccini, “45S5 Bioglass®-derived glass-ceramic scaffolds for bone tissue engineering,” Biomaterials 27 (2006), 2414–2425.
R.D. Rawlings, J. P. Wu, and A.R. Boccaccini, “Glass-ceramics: Their production from wastes—A review,” J. mater. Sci. 41 (2006), 733–761.
E. Bernardo, “Micro-and macro-cellular sintered glass-ceramics from wastes,” Journal of the European ceramic Society, 27 (2007), 2415–2422.
E. Bernardo, and F. Albertini, “Glass foams from dismantled cathode ray tubes,” Ceramics international, 32 (2006), 603–608.
R.M. Ramirez Zamora, F. Espejel Ayala. L. Chavez Garcia, A. Duran Moreno, and R. Schouwenaars, “Optimization of the preparation conditions of ceramic products using drinking water treatment sludges,” J Environ Sci Health A 43 (2008), 1562–1568.
I. Demir, “Effect of organic residues addition on the technological properties of clays bricks,” Waste Management 28 (2007), 622–627.
I. Demir, M. Serhat Baspinar, and M. Orhan, “Utilization of kraft pulp production residues in clay brick production,” Building and Environment 40 (2007), 1533–1537.
M. Sutcu, and S. Akkurt, “Utilization of recycled paper processing residues and clay of different sources for the production of porous anorthite ceramics,” Journal of the European Ceramic Society 30 (2009), 1785–1793.
M. Sutcu, and S. Akkurt, “The use of recycled paper processing residues in making porous brick with reduced thermal conductivity” Ceramics International 35 (2009), 2625–2631.
K. L. Lin, “Feasibility study of using brick made from municipal solid waste incinerator fly ash slag,” Journal of Hazardous Materials. B137 (2006), 1810–1816.
K. Koseoglu, M. Polat, and H. Polat, “Encapsulating fly ash and acidic process waste water in brick structure,” Journal of Hazardous Materials 176 (2010), 957–964.
C. H. Weng, D. Fong, C. Pen-Chi, “Utilization of sludge as brickmaterials,” Advances in Environmental Research 7 (2003), 679–685.
K.Y. Chiang, P.H. Chou, C.R. Hua, K.L. Chien, and C. Cheeseman, “Lightweight bricks manufactured from water treatment sludge and rice husks,” Journal of Hazardous Materials 171 (2009), 76–82.
M. Samara, Z. Lafhaj, and C. Chapiseau, “Valorization of stabilized river sediments in fired clay bricks: Factory scale experiment,” Journal of Hazardous Materials 163 (2009), 701–710.
Y.C. Liao, and C.Y. Huang, “Glass foam from the mixture reservoir sediment and Na2CO3,” Ceramics International 38 (2002), 4415–4420.
H.W. Guo, Y.X. Cong, and S.Y. Gao, “Preparation of high strength foam glass-ceramics from waste cathode ray tube,” Mater Letters 64 (2010), 997–999.
T.W. Cheng, T.H. Ueng, Y.S. Chen, and J.P. Chiu, “Production of glass-ceramic from incinerator fly ash,” Ceramics International 28 (2002) 779–783.
C. van der Zee, D.R. Roberts, D.G. Rancourt, and C.P. Slomp, “Nanogoethite is the dominant reactive oxyhydroxide phase in lake and marine sediments,” Geology 31 (2003), 993–996.
L. Maritan, L. Nodari, C. Mazzoli, A. Milano, and U. Russo, “Influence of firing conditions on ceramic products: experimental study on clay rich in organic matter”, App Clay Sci 31 (2006), 1–15.
K.J.D. MacKenzie, and C.M. Cardile, “A 57Fe Mössbauer study of black coring phenomena in clay-based ceramic materials,” J Mater Sci 25 (1990), 2937–2942.
J. Yang, T. Mori, and M. Kuwabara, “Mechanism of Carbothermic Reduction of Hematite in Hematite-Carbon Composite Pellets,” ISIJ International 47 (2007), 1394–1400.
O. Castelein, B. Soulestin, J.P. Bonnet, and P. Blanchart, “The influence of heating rate on the thermal behaviour and mullite formation from a kaolin raw material,” Ceramics International 27 (2001) 517–522.
C.J. Goss, “The kinetics and reaction mechanism of the goethite to hematite transformation,” MineralMag 51 (1987)437–451.
M. Prat, “Percolation model of drying under isothermal conditions in porous media,” International Journal of Multiphase Flow, 19 (1993), 691–704.
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Espejel-Ayala, F., Ramírez-Zamora, R.M., González-Barceló, O., Schouwenaars, R. (2013). Novel Self-Foaming Cellular Composites Produced from Recycled Water Potabilisation Sludge. In: Marquis, F. (eds) Proceedings of the 8th Pacific Rim International Congress on Advanced Materials and Processing. Springer, Cham. https://doi.org/10.1007/978-3-319-48764-9_34
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DOI: https://doi.org/10.1007/978-3-319-48764-9_34
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