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Aragonite Precipitated Calcium Carbonate: A New Versatile Functional Filler for Light Weight Plastic

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Proceedings of the 8th Pacific Rim International Congress on Advanced Materials and Processing

Abstract

This study was carried out to investigate the how aragonite precipitated calcium carbonate (PCC) with specific needle shape morphology prepared from natural limestone and how it is effectively worked as versatile functional filler to light weight plastic. Aragonite was synthesized from limestone by ecofriendly carbonation process under optimal experimental conditions. The synthesized needle like aragonite precipitated calcium carbonate (PCC) was influenced mechanical properties such as tensile strength, impact resistance, flexural modulus, young’s modulus and thermal properties of polypropylene composites. The effects of CaCO3 of varying particle sizes (0.1µm ~ 80 µm) content (0–40 wt%) on the crystallization and mechanical properties, and process ability of CaCO3-filled s-PP were investigated.

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References

  1. G.T. Zhou, et al., Controlled crystallization of unstable vaterite with distinct morphologies and their polymorphic transition to stable calcite, Eur. J. Mineral, 22(2), (2010) 259–269.

    Article  Google Scholar 

  2. J.W. Ahn, et al., Synthesis of single phase aragonite precipitated calcium carbonate in Ca(OH)2 and Na2CO3-NaOH reaction system, Korean J. Chem. Eng., 22(6), (2005) 852–856.

    Article  Google Scholar 

  3. J.W. Ahn, Jeong Hwan Kim and Sang Jin Ko, WO 2007/078018 Al, July 12.

    Google Scholar 

  4. J.W. Ahn, et al., Novel manufacturing Method of Aragonite Calcium Carbonate, WO 2007/078017 Al, 12 July 2007.

    Google Scholar 

  5. J.K. Park, et al., Synthesis of aragonite precipitated calcium carbonate by homogeneous precipitate reaction of Ca(OH)2 and Na2CO3. Journal of Korean Crystal Growth and Crystal Technology, 14(3), (2004)110–114.

    Google Scholar 

  6. E. Dalas, P. Klepetsanis, and P. G. Koutsoukos, The Overgrowth of Calcium Carbonate on Poly(vinylchloride-co-vinyl acetate- co- maleic acid, Langmuir, 15(23) (1999), 8322–8327.

    Article  Google Scholar 

  7. H.D. Yu, et al., Bioinspired Fabrication of 3D hierarchical porous nano micro structures of calcium carbonate for bone regeneration, Chemical Communications. 46(35)(2010)6578–6580.

    Article  Google Scholar 

  8. D. Walsh and S. Mann, Fabrication of hollow porous shells of calcium carbonate from self- organizing media, Nature, 377(6547)(1995)320–323.

    Article  Google Scholar 

  9. K. Yang, et al., Mechanical properties and morphologies of polypropylene/single-filler or hybrid-filler calcium carbonate composites, Polymer Engineering and Science, 95(2007)95–102.

    Article  Google Scholar 

  10. D. Z. Wu, et al., Nanocomposites of poly(vinyl chloride) and nanometric calcium carbonate particles: Effects of chlorinated polyethylene on mechanical properties, morphology, and rheology, Journal of Applied Polymer Science, 92(4) (2004)2714–2723.

    Article  Google Scholar 

  11. Q. Shi, et al., A Novel Epoxy Resin/CaCO3 Nanocomposite and Mechanism of Toughness Improvement, Macromolecular Materials Engineering, 291(1)(2006)53–58.

    Article  Google Scholar 

  12. F. L. Jin and S. J. Park, Interfacial toughness properties of trifunctional epoxy resins/calcium carbonate nanocomposites, Materials Science and Engineering: A, 475(1–2)(2008)190–193.

    Article  Google Scholar 

  13. C.G. Ma et al., Irradiation-induced surface graft polymerization onto calcium carbonate nanoparticles and its toughening effects on polypropylene composites, Polymer Engineering Science, 45(4)(2005)529–538.

    Article  Google Scholar 

  14. J.F. Chen, et al., Toughening of polypropylene-ethylene copolymer with nanosized CaCO3 and styrene-butadiene-styrene, Journal of Applied Polymer Science, 94(2) (2004) 796–802.

    Article  Google Scholar 

  15. Y.S. et al., Toughening of isotactic polypropylene with CaCO3 particles. Polymer, 43(13) (2002) 3661–3674.

    Article  Google Scholar 

  16. W.C. Zuiderduin et al., Toughening of polypropylene with CaCO3 particles, Polymer, 44(1)(2003) 261–275.

    Article  Google Scholar 

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© 2013 TMS (The Minerals, Metals & Materials Society)

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Thriveni, T., Il, U.N., Ahn, J.W. (2013). Aragonite Precipitated Calcium Carbonate: A New Versatile Functional Filler for Light Weight Plastic. In: Marquis, F. (eds) Proceedings of the 8th Pacific Rim International Congress on Advanced Materials and Processing. Springer, Cham. https://doi.org/10.1007/978-3-319-48764-9_31

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