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Selective extraction of vanadium from the APV-precipitated waste water

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REWAS 2013

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Abstract

In the process of precipitating ammonium polyvanadate (APV) to produce vanadium pentoxide in Pan-steel in China, rest waste water usually contains about 24~333mg/L V(V), 2~100g/L Cr(VI),20~500mg/L Si(IV) and 20~100g/L Na2SO4. In order to recover valuable and also toxic metal ions contained in the waste water, effective extraction method of using anion exchange resin was realized to extract Vanadium selectively, leading to effective separation between vanadium and chromium. To ensure vanadium was absorbed by the resin, V(V) and Cr(VI) were reduced to V(IV) and Cr(III) by NaHSO3, respectively, and then V(IV) was oxidized by H2O2 to V(V) anions. Effects of temperature, solution pH, concentration of ions and absorbing time on vanadium absorption rate were investigated. Chromium was precipitated from rest solution while vanadium was eluted from resin by NaOH solution and then precipitated. Results showed that vanadium recovery of 73% could be obtained in optimized condition. The resin could be regenerated by 3% hydrochloric acid, which indicated the recyclability of the resin and thus low cost of this established method.

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Author information

Authors and Affiliations

  1. College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, China

    Cui Li, Hong-Yi Li, Chun-Bin Tu, Tao Zhang, Hai-Xing Fang & Bing Xie

Authors
  1. Cui Li
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  2. Hong-Yi Li
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  3. Chun-Bin Tu
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  4. Tao Zhang
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  5. Hai-Xing Fang
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  6. Bing Xie
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Editor information

Editors and Affiliations

  1. SINTEF, Trondheim, Norway

    Anne Kvithyld (a senior research scientist) (a senior research scientist)

  2. Umicore Precious Metals Refining, Hoboken, Belgium

    Christina Meskers (leads the business development and marketing team) (leads the business development and marketing team)

  3. Energy Systems Division, Argonne National Laboratory, USA

    Gregory Krumdick (principal systems engineer) (principal systems engineer)

  4. Kroll Institute for Extractive Metallurgy in Metallurgical & Materials Engineering, Colorado School of Mines, USA

    Brajendra Mishra (professor and the Assoc. Director) (professor and the Assoc. Director)

  5. Outotec Finland, Finland

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  6. Aalto University, Finland

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  7. University of Melbourne, Australia

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  8. Central South University Changsha, China

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  9. TU Delft, Netherlands

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  10. University of Stellenbosch, South Africa

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  11. Saint-Gobain Innovative Materials R&D, Belgium

    Cong Wang (Senior Research Engineer) (Senior Research Engineer)

  12. Missouri University of Science and Technology, USA

    Mark Schlesinger (Professor of Metallurgical Engineering) (Professor of Metallurgical Engineering)

  13. Golisano Institute for Sustainability, USA

    Gabrielle Gaustad Ph.D. (Assistant Professor) (Assistant Professor)

  14. Rochester Institute of Technology, USA

    Gabrielle Gaustad Ph.D. (Assistant Professor) (Assistant Professor)

  15. Worcester Polytechnic Institute (WPI), USA

    Diana Lados (Associate Professor, Founding Director) (Associate Professor, Founding Director)

  16. Integrative Materials Design Center (iMdc), USA

    Diana Lados (Associate Professor, Founding Director) (Associate Professor, Founding Director)

  17. Argonne National Laboratory, USA

    Jeffrey Spangenberger (Engineering Specialist, Senior) (Engineering Specialist, Senior)

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© 2013 TMS (The Minerals, Metals & Materials Society)

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Li, C., Li, HY., Tu, CB., Zhang, T., Fang, HX., Xie, B. (2013). Selective extraction of vanadium from the APV-precipitated waste water. In: Kvithyld, A., et al. REWAS 2013. Springer, Cham. https://doi.org/10.1007/978-3-319-48763-2_32

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