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Abstract

The electrochemical behavior of alloy 718 in a chloride-containing boric acid solution was studied to determine the influence of chloride ions as contaminants of pool water of nuclear power plants on the corrosion behavior of the alloy. Experiments were performed at 20°C and 60°C with chloride concentrations from 1.5 to 15 000 ppm, using stationary measurements i.e. OCP versus time measurements and plotting of current-potential curves. After the electrochemical tests, the samples were observed using optical microscopy. Immersion tests in chloride-containing boric acid solutions were also carried out: samples were immersed for a time as long as 17 weeks at open circuit potential and their residual mechanical properties were measured. Results showed that, whatever the chloride concentration, there was no corrosion for samples immersed at open circuit potential. However, when the samples were polarized at high potentials, intergranular corrosion might be observed in occluded zones.

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References

  1. A. Machet, A. Galtayries, S. Zanna, L. Klein, V. Maurice, P. Jolivet, M. Foucault, P. Combrade, P. Scott, and P. Marcus, “XPS and STM study of the growth and structure of passive films in high temperature water on a nickel-base alloy,” Electrochimica Acta, 49, 3957–3964, 2004.

    Article  Google Scholar 

  2. H. Hirano, H. Takaku, and T. Kurosawa, “The relationship between the characteristics of oxide film and stress corrosion susceptibility of Ni-Cr-Fe alloy in high temperature water,” Corrosion Science, 31, 557–562, 1990.

    Article  Google Scholar 

  3. I.-J. Yang, “Effect of sulphate and chloride ions on the crevice chemistry and stress corrosion cracking of alloy 600 in high temperature aqueous solutions,” Corrosion Science, 33, (1), 25–29, 31–37, 1992.

    Article  Google Scholar 

  4. M. Cardoso, S. Amaral, and E. Martini, “Temperature effect in the corrosion resistance of Ni-Cr-Fe alloy in chloride medium,” Corrosion Science, 50, 2429–2436, 2008.

    Article  Google Scholar 

  5. M. Bojinov, G. Fabricius, P. Kinnunen, T. Laitinen, K. Mäkelä, T. Saario, and G. Sundholm, “The mechanism of transpassive dissolution of Ni-Cr alloys in sulphate solutions,” Electrochimica Acta,45, 2791–2802, 2000.

    Article  Google Scholar 

  6. M. Bojinov, G. Fabricius, P. Kinnunen, T. Laitinen, K. Mäkelä, T. Saario, and G. Sundholm, “Electrochemical study of the passive behaviour of Ni-Cr alloys in a borate solution–a mixed-conduction model approach,” Journal of Electroanalytical Chemistry, 504, 29–44, 2001.

    Article  Google Scholar 

  7. Y. Chen, L. Chou, and H. Shih, “Factors affecting the electrochemical behavior and stress corrosion cracking of alloy 690 in chloride environments,” Materials Chemistry and Physics, 97,37–49, 2006.

    Article  Google Scholar 

  8. A. M. Olmedo, M. Villegas, and M. G. Alvarez, “Corrosion behaviour of alloy 800 in high temperature aqueous solutions: Electrochemical studies,” Journal of Nuclear Materials, 229, 102–114, 1996.

    Article  Google Scholar 

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© 2011 TMS (The Minerals, Metals & Materials Society)

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Hugues, J., Andrieu, E., Blanc, C., Cloué, JM. (2011). Influence of Chloride Ions as Contaminants on the Corrosion Behavior of Alloy 718 in Pool Water of Nuclear Power Plants. In: Busby, J.T., Ilevbare, G., Andresen, P.L. (eds) Proceedings of the 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems — Water Reactors. Springer, Cham. https://doi.org/10.1007/978-3-319-48760-1_49

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