Abstract
The ASTM A262 Practice A procedure is frequently used to assess whether Type 304/304L austenitic stainless steels are “sensitized”. In this study, Type 304L steel containing 18 ppm boron examined in the as-received (mill solution-annealed) condition exhibited a “dual” structure after the Practice A test despite its low C content. Detailed characterization of this alloy was performed to assess the precipitation behavior in this steel. Intergranular, Cr-rich M2B- borides, identified by electron diffraction, were observed in the as-received condition. Samples aged at 700°C (nominally “sensitized”) produced fully “ditched” grain boundaries having Cr levels in excess of 14 wt.% and concomitant Cr-depleted zones less than 50 nm in extent. Despite exhibiting fully “ditched” grain boundaries, Cr levels of ∼18–20 wt.% with no Cr-depleted zones were detected in specimens aged at 900°C (nominally “stabilized”). These results show the Practice A test can be mis-used/mis-interpreted for assessing sensitization.
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© 2011 TMS (The Minerals, Metals & Materials Society)
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Miller, B.D., Burke, M.G. (2011). Characterization of Type 304L Stainless Steel: Comparison of ASTM A262 Practice A and Analytical Electron Microscopy Techniques. In: Busby, J.T., Ilevbare, G., Andresen, P.L. (eds) Proceedings of the 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems — Water Reactors. Springer, Cham. https://doi.org/10.1007/978-3-319-48760-1_29
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DOI: https://doi.org/10.1007/978-3-319-48760-1_29
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-48760-1
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