Decomposition of Methane During Oxide Reduction with Natural Gas

  • Halvor Dalaker
  • Pål Tetlie


The decomposition of methane has been studied experimentally in contact with various oxides at elevated temperatures. For each oxide, the temperature at which the cracking starts has been determined. No correlation was found to exist between the temperature for the onset of cracking for a given oxide and the affinity for carbon of the oxide’s metallic component. In terms of potential for using methane as a reducing agent, calculations are presented that indicate that the suitability of an oxide for such reduction depends on the desired methane+oxide reaction being more energetically favourable than the methane+methane=ethylene/acetylene reactions.


Metal production oxide reduction methane natural gas cracking thermal decomposition 


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Copyright information

© TMS (The Minerals, Metals & Materials Society) 2014

Authors and Affiliations

  • Halvor Dalaker
    • 1
  • Pål Tetlie
    • 1
  1. 1.SINTEF Materials and ChemistryTrondheimNorway

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