Skip to main content

Utilization of Pine Nut Shell for Preparation of High Surface Area Activated Carbon by Microwave Heating and KOH Activation

  • Chapter
7th International Symposium on High-Temperature Metallurgical Processing

Abstract

Pine nut shell is as raw material for preparation of high surface area activated carbon (HSAAC) by microwave induced KOH activation. The effects of microwave power, activation duration and KOH/C mass rate (R) on the iodine adsorption capability and activated carbon yield were investigated. Additionally the surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms and SEM The operating variables were optimized utilizing the response surface methodology and were identified microwave power 738W, activation duration 17 min, and R 4, corresponding to a yield of 46.28 % and an iodine number of 2154 mg/g. The key pore structure parameters of HSAAC such as the Brunauer-Emmett-Teller (BET) surface area and total pore volume were estimated to be 3819 m2/g and 2.09 mL/g, respectively. The findings strongly support the feasibility of microwave heating for preparation of HSAAC from spent pine nut shell by microwave induced KOH activation.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 239.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. H.L. Mudoga, H. Yucel, and N.S. Kincal, “Decolorization of sugar syrups using commercial and sugar beet pulp based activated carbons,” Bioresourc e Technology, 99 (9) (2008), 3528–3533.

    Article  Google Scholar 

  2. S.L Liu, Y.N. Wang and K.T. Lu, “Preparation and pore characterization of activated carbon from Ma bamboo (Dendrocalamus latiflorus) by H3PO4 chemical activation,” Journal of Porous Materials, 21 (4) (2014), 459–466.

    Article  Google Scholar 

  3. A. Policicchio et al., “Higher methane storage at low pressure and room temperature in new easily scalable large-scale production activated carbon for static and vehicular applications,” Fuel, 104 (2) (2013), 813–821.

    Article  Google Scholar 

  4. G.M. WALKER and L.R. WEATHERLEY, “Textile Wastewater Treatment Using Granular Activated Carbon Adsorption in Fixed Beds,” Separation Science & Technology, 35 (9) (2000), 1329–1341.

    Article  Google Scholar 

  5. E. Kaçan and C. Kütahyal, “Adsorption of strontium from aqueous solution using activated carbon produced from textile sewage sludges,” Journal of Analytical & Applied Pyrolysis, 97 (2012), 149–157.

    Article  Google Scholar 

  6. Y.H Li et al., “Preparation of activated carbon from Enteromorpha prolifera and its use on cationic red X-GRL removal,” Applied Surface Science, 257 (24) (2011), 10621–10627.

    Article  Google Scholar 

  7. B. Kastening and M. Heins, “Properties of electrolytes in the micropores of activated carbon,” Electrochimica Acta, 50 (12) (2005), 2487–2498.

    Article  Google Scholar 

  8. Y.J. Kim et al., “Preparation and characterization of bamboo-based activated carbons as electrode materials for electric double layer capacitors,” Carbon, 44 (8) (2006), 1592–1595.

    Article  Google Scholar 

  9. C. Nieto-Delgado and J.R. Rangel-Mendez, “Production of activated carbon from organic by-products from the alcoholic beverage industry: Surface area and hardness optimization by using the response surface methodology,” Industrial Crops & Products, 34 (3) (2011), 1528–1537.

    Article  Google Scholar 

  10. Q.S Liu et al., “Preparation and characterization of activated carbon from bamboo by microwave-induced phosphoric acid activation,” Industrial Crops & Products, 31 (2) (2010), 233–238.

    Article  Google Scholar 

  11. A.L Cazetta et al., “Thermal regeneration study of high surface area activated carbon obtained from coconut shell: Characterization and application of response surface methodology,” Journal of Analytical & Applied Pyrolysis, 101 (5) (2013), 53–60.

    Article  Google Scholar 

  12. Y.P Guo et al., “Performance of electrical double layer capacitors with porous carbons derived from rice husk,” Materials Chemistry & Physics, 80 (3) (2003), 704–709.

    Article  Google Scholar 

  13. B. Karimi, M.H Ehrampoush, A. Ebrahimi et al., “The study of leachate treatment by using three advanced oxidation process based wet air oxidation,” Iranian Journal of Environmental Health Science & Engineering, 10 (1) (2013), 119–124.

    Google Scholar 

  14. G. Hermosilla-Lara, G. Momen, P.H Marty et al., “Hydrogen storage by adsorption on activated carbon: Investigation of the thermal effects during the charging process,” International Journal of Hydrogen Energy, 32 (2007), 1542–1553.

    Article  Google Scholar 

  15. J.W Zondlo, and M.R. Velez, “Development of surface area and pore structure for activation of anthracite coal,” Fuel Processing Technology, 88 (4) (2007), 369–374.

    Article  Google Scholar 

  16. J.L Lim, and M. Okada, “Regeneration of granular activated carbon using ultrasound,” Ultrasonics Sonochemistry, 12 (4) (2005), 277–82.

    Article  Google Scholar 

  17. B. Kastening, and M. Heins, “Properties of electrolytes in the micropores of activated carbon,” Electrochimica Acta, 50 (12) (2005), 2487–2498.

    Article  Google Scholar 

  18. C.O Ania, J.B Parra, J.A. Menéndez et al., “Microwave-assisted regeneration of activated carbons loaded with pharmaceuticals,” Water Research, 41 (15) (2007), 3299–3306.

    Article  Google Scholar 

  19. M Kubota, A. Hata, and H. Matsuda, “Preparation of activated carbon from phenolic resin by KOH chemical activation under microwave heating,” Carbon, 47 (12) (2009), 2805–2811.

    Article  Google Scholar 

  20. X.H Duan, C. Srinivasakannan, J.H Peng et al., “Comparison of activated carbon prepared from Jatropha hull by conventional heating and microwave heating,” Biomass & Bioenergy, 35 (9) (2011), 3920–3926.

    Article  Google Scholar 

  21. X.H Duan, C. Srinivasakannan et al., “Regeneration of microwave assisted spent activated carbon: Process optimization, adsorption isotherms and kinetics,” Chemical Engineering & Processing, 53 (2012), 53–62.

    Article  Google Scholar 

  22. A.S Mestre, A.S Bexiga et al., “Activated carbons from sisal waste by chemical activation with K2CO3: Kinetics of paracetamol and ibuprofen removal from aqueous solution,” Bioresource Technology, 102 (17) (2011), 8253–8260.

    Article  Google Scholar 

  23. X.H Duan, C. Srinivasakannan, and J.S. Liang, “Process optimization of thermal regeneration of spent coal based activated carbon using steam and application to methylene blue dye adsorption,” Journal of the Taiwan Institute of Chemical Engineers, 45 (2014), 1618–1627.

    Article  Google Scholar 

  24. A.C Lua, and T. Yang, “Effect of activation temperature on the textural and chemical properties of02potassium hydroxide activated carbon prepared from pistachio-nut shell,” Journal of Colloid & Interface Science, 274 (2) (2004), 594–601.

    Article  Google Scholar 

  25. X.H Duan, Z.B. Zhang, C. Srinivasakannan, F. Wang et al., “Regeneration of spent catalyst from vinyl acetate synthesis as porous carbon: Process optimization using RSM,” Chemical Engineering Research & Design, 92 (7) (2014), 1249–1256.

    Article  Google Scholar 

  26. X.H Duan, C. Srinivasakannan, J.H Peng et al., “Preparation of activated carbon from Jatropha hull with microwave heating: Optimization using response surface methodology,” Fuel Processing Technology, 92 (3) (2011), 394–400.

    Article  Google Scholar 

  27. R.M Suzuki, A.D Andrade, J.C Sousa et al., “Preparation and characterization of activated carbon from rice bran,” Bioresource Technology, 98 (10) (2007), 1985–1991.

    Article  Google Scholar 

  28. K.Y Foo, and B.H. Hameed, “Adsorption characteristics of industrial solid waste derived activated carbon prepared by microwave heating for methylene blue,” Fuel Processing Technology, 99 (7) (2012), 103–109.

    Article  Google Scholar 

  29. K.Y Foo, and B.H. Hameed, “Porous structure and adsorptive properties of pineapple peel based activated carbons prepared via microwave assisted KOH and K2CO3 activation,” Microporous & Mesoporous Materials, 148 (1) (2012), 191–195.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Liao, X. et al. (2016). Utilization of Pine Nut Shell for Preparation of High Surface Area Activated Carbon by Microwave Heating and KOH Activation. In: Hwang, JY., et al. 7th International Symposium on High-Temperature Metallurgical Processing. Springer, Cham. https://doi.org/10.1007/978-3-319-48093-0_7

Download citation

Publish with us

Policies and ethics