Freestanding Silicene

  • Seymur Cahangirov
  • Hasan Sahin
  • Guy Le Lay
  • Angel Rubio
Part of the Lecture Notes in Physics book series (LNP, volume 930)


Obtaining a freestanding 2D graphene flake is relatively easy because it has a naturally occurring 3D layered parent material, graphite, made up of graphene layers weakly bound to each other by van der Waals interaction. In fact, graphite is energetically more favorable than diamond (one the most stable and hard materials on Earth) that is the sp 3 hybridized allotrope of carbon. To prepare freestanding graphene, it is enough to come up with a smart procedure for isolating the weakly bound layers of graphite. The same is also true for other layered materials like hexagonal boron nitride, black phosphorus, metal dichalcogenides and oxides. Silicene, on the other hand, doesn’t have a naturally occurring 3D parent material since silicon atoms prefer sp 3 hybridization over sp 2 hybridization. This makes the synthesis of freestanding silicene very hard, if not impossible. However, it is possible to epitaxially grow silicene on metal substrates and make use of its intrinsic properties by transferring it to an insulating substrate (Tao et al. Nat Nanotechnol 10: 227–231, 2015). In this Chapter, we focus on intrinsic properties of freestanding silicene in the absence of the metallic substrate.


Cohesive Energy Phonon Dispersion Topological Insulator Black Phosphorus Oxygen Adatoms 
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Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  • Seymur Cahangirov
    • 1
  • Hasan Sahin
    • 2
  • Guy Le Lay
    • 3
  • Angel Rubio
    • 4
  1. 1.University of the Basque Country, Materials Unit Joint CenterDonostiaSpain
  2. 2.Department of PhotonicsIzmir Institute of TechnologyIzmirTurkey
  3. 3.Aix Marseille Université CNRSMarseille CedexFrance
  4. 4.Basque Country, Materials Unit Joint CenterDonostiaSpain

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