Abstract
The present paper describes the successful synthesis of hierarchical ZSM-5 zeolite nanosurfaces with high porosity from the rice straw ash (RSA) by means of the hydrothermal method at varying time intervals in the presence of small amount of tetrapropylammonium bromide as a single template. The synthesized samples were characterized by X‐ray diffraction (XRD ), Fourier transform infrared spectroscopy (FT-IR), high resolution scanning electron microscopy (HR-SEM), and nitrogen adsorption–desorption analysis (BET). The XRD pattern confirms the formation of pure ZSM‐5 zeolite crystalline phase without any impurity phases. The IR spectrum shows a vibration band at 548 cm−1, which is assigned to the double 5-rings of MFI-type zeolites. The surface area results reveal the formation of additional mesoporosity without destroying the intensive microporosity in a hierarchical ZSM-5 zeolite, which is due to the addition of TPABr during the synthesis. The characterization results conclude that the long time process of hierarchical ZSM-5 zeolite nanosurfaces with high porosity have produced high crystallinity .
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References
Dey, K.P., Ghosh, S., Naskar, M.K.: Organic template-free synthesis of ZSM-5 zeolite particles using rice husk ash as silica source. Ceram. Int. 39, 2153–2157 (2013)
Jiang, J., Duanmu, C., Yang, Y., Gu, X., Chen, J.: Synthesis and characterization of high siliceous ZSM-5 zeolite from acid-treated palygorskite. Powder Technol. 251, 9–14 (2014)
Motsi, T., Rowson, N.A., Simmons, M.J.H.: Kinetic studies of the removal of heavy metals from acid mine drainage by natural zeolite. Int. J. Miner. Process. 101, 42–49 (2011)
Egeblad, K., Christensen, C.H., Kustova, M., Christensen, C.H.: Templating mesoporous zeolites. Chem. Mater. 20, 946–960 (2008)
Argauer, R.J., Landolt G.R.: US Patent 3 702 886 A. (1972)
Narayanan, S., Vijaya, J.J., Sivasanker, S., Yang, S., Kennedy, L.J.: Hierarchical ZSM-5 catalyst synthesized by a Triton X-100 assisted hydrothermal method. Chinese J. Catal. 35, 1892–1899 (2014)
Pan, F., Lu, X., Wang, Y., Chen, S., Wang, T., Yan, Y.: Synthesis and crystallization kinetics of ZSM-5 without organic template from coal-series kaolinite. Micropor. Mesopor. Mater. 184, 134–140 (2014)
Azizi, S., Yousefpour, M.: Synthesis of zeolites NaA and analcime using rice husk ash as silica source without using organic template. J. Mater. Sci. 45, 5692–5697 (2010)
Gadde, B., Menke, C., Wassmann, R.: Rice straw as a renewable energy source in India, Thailand, and the Philippines: overall potential and limitations for energy contribution and greenhouse gas mitigation. Biomass Bioenerg. 33, 1532–1546 (2009)
Hamdan, H., Muhid, M.N.M., Endud, S., Listiorini, E., Ramli, Z.: 29Si MAS NMR, XRD and FESEM studies of rice husk silica for the synthesis of zeolites. J. Non-Cryst. Solids 211, 126–131 (1997)
Azizi, S.N., Yousefpour, M.: Spectroscopic studies of different kind of rice husk samples grown in North of Iran and the extracted silica by using XRD, XRF, IR, AA and NMR techniques. Eurasian J. Anal. Chem. 3, 298–306 (2008)
Yusof, A.M., Nizam, N.A., Rashid, N.A.A.: Hydrothermal conversion of rice husk ash to faujasite-types and NaA-type of zeolites. J. Porous Mater. 17, 39–47 (2010)
Barrer, R.M.: The hydrothermal chemistry of zeolites. Academic Press, London (1982)
Wang, L., Yin, C., Shan, Z., Liu, S., Du, Y., Xiao, F.S.: Bread-template synthesis of hierarchical mesoporous ZSM-5 zeolite with hydrothermally stable mesoporosity. Colloids Surf. A 340, 126–130 (2009)
Becheri, A., Dürr, M., Nostro, P.L., Baglioni, P.: Synthesis and characterization of zinc oxide nanoparticles: Application to textiles as UV-absorbers. J. Nanopart. Res. 10, 679–689 (2008)
Guo, Y.P., Wang, H.J., Guo, Y.J., Guo, L.H., Chu, L.F., Guo, C.X.: Fabrication and characterization of hierarchical ZSM-5 zeolites by using organosilanes as additives. Chem. Eng. J. 166, 391–400 (2011)
Narayanan, S., Vijaya, J.J., Sivasanker, S., Yang, S., Kennedy, L.J.: Hierarchical ZSM-5 catalyst synthesized by a Triton X-100 assisted hydrothermal method. Chinese J. Catal. 35, 1892–1899 (2014)
Chester, A.W., Derouane, E.G.: Zeolite Characterization and Catalysis: A Tutorial. Springer, (2009)
Vijaya, J.J., Kennedy, L.J., Sekaran, G., Nagaraja, K.S.: Synthesis, characterization and humidity sensing properties of Cu–Sr–Al mixed metal oxide composites. Mater. Res. Bull. 43, 473–482 (2008)
Schmidt, F., Lohe, M.R., Buchner, B., Giordanino, F., Bonino, F., Kaskel, S.: Improved catalytic performance of hierarchical ZSM-5 synthesized by desilication with surfactants. Micropor. Mesopor. Mater. 165, 148–157 (2013)
Sang, Y., Liu, H., He, S., Li, H., Jiao, Q., Wu, Q., Sun, K.: Catalytic performance of hierarchical H-ZSM-5/MCM-41 for methanol dehydration to dimethyl ether. J. Energy Chem. 22, 769–777 (2013)
Wang, Y.Y., Gin, G.Q., Guo, X.Y.: Growth of ZSM-5 coating on biomorphic porous silicon carbide derived from durra. Micropor. Mesopor. Mater. 118, 302–306 (2009)
Fernandez, C., Stan, I., Gilson, J.P., Thomas, K., Vicente, A., Bonilla, A., Ramirez, J.P.: Hierarchical ZSM-5 zeolites in shape-selective xylene isomerization: Role of mesoporosity and acid site speciation. Chem. Eur. J. 16, 6224–6233 (2010)
Acknowledgements
The authors duly acknowledge the financial support rendered by Loyola college, Tamil Nadu, India through Loyola College-Times of India (LC-TOI) Major Research Project scheme vide (Project Code: 2LCTOI14CHM003, dated 25.11.2014) to the first author.
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Jesudoss, S.K., Judith Vijaya, J., Anancia Grace, A., John Kennedy, L., Sivasanker, S., Kathirgamanathan, P. (2017). Hierarchical ZSM-5 Zeolite Nanosurfaces with High Porosity—Structural, Morphological and Textural Investigations. In: Ebenezar, J. (eds) Recent Trends in Materials Science and Applications. Springer Proceedings in Physics, vol 189. Springer, Cham. https://doi.org/10.1007/978-3-319-44890-9_11
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