Abstract
When a solution turns into a gel, namely a solid-like material, determination of its mechanical properties is among the first investigations to be performed. Since the gel contains a large amount of solvent, the science dealing with these systems is rheology which encompasses several properties such as elasticity, viscosity, plasticity, thixotropy, and the like.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Notes
- 1.
Effect similar to the fusion-recrystallization of water under stress.
- 2.
“Monomers” are basic bricks that can be defined as wished.
References
Doi, M.; Edwards, S.F. The Theory of Polymer Dynamics, 1986, Oxford University Press, Oxford
Dammer, C., Maldivi, P., Terech, P., Guenet, J.M.: Rheological Study of a Bicopper Tetracarboxylate/Decalin Jelly. Langmuir 11, 1500 (1995)
McKenna, G.B., Guenet, J.M.: The effects of the solvent type on the concentration dependence of the compression modulus of thermoreversible isotactic polystyrene gels. J. Polym. Sci. Polym. Phys. Ed. 26, 267 (1988)
Lescanne, M., Colin, A., Mondain-Monval, O., Fages, F., Pozzo, J.L.: Structural Aspects of the Gelation Process Observed with Low Molecular Mass Organogelators. Langmuir 2003, 19 (2013)
Collin, D., Covis, R., Allix, F., Jamart-Grégoire, B., Martinoty, P.: Jamming transition in solutions containing organogelator molecules of amino-acid type: rheological and calorimetry experiments. Soft Matter 9, 2947 (2013)
Hammersley, J.M.: Percolation processes: lower bounds for the critical probability Ann. Math. Stat. 28, 790 (1957)
Stauffer, D.: ‘Gelation in concentrated critically branched polymer solutions. J. Chem. Soc., Faraday Trans. 2 72, 1354 (1976)
de Gennes, P.G.: On a relation between percolation theory and the elasticity of gels. J. Phys. France Lett. 37, 1 (1976)
Stauffer, D.: Introduction to Percolation Theory. Taylor and Francis, London (1985)
Daoud, M., Family, F., Jannink, G.: Dilution and polydispersity in branched polymers. J. Phys. France Lett. 45, 199 (1984)
Martin, J., Ackerson, B.J.: Static and dynamic scattering from fractals Phys. Rev. A 31, 1180 (1985)
Adam, M.; Lairez, D. Sol-gel transition, in The Physical Properties of Polymeric Gels, 1996, 84, ed. J. P. Cohen-Addad, Wiley, New York
Guenet, J.M.: Structure versus rheological properties in fibrillary thermoreversible gels from polymers and biopolymers. J. Rheol. 44, 947 (2000)
Abied, H., Brulet, A., Guenet, J.M.: Physical gels from PVC: molecular structure of pregels and gels by low-angle neutron scattering Colloid Polym. Sci. 268, 403 (1990)
Dasgupta, D., Srinivasan, S.A., Rochas, C., Ajayaghosh, A., Guenet, J.M.: Solvent-mediated Fiber Growth Organog. Soft Matter 7 9311 (2011); Dasgupta, D., Srinivasan, S.A., Rochas, C., Thierry, A., Schröder, A., Ajayaghosh, A., Guenet, J.M.: Insight into the gelation habit of oligo(para-phenylene vinylene) derivatives: effect of end-groups. Soft Matter 7, 2797 (2011)
Jones, J.L., Marques, C.M.J.: Phys. (les Ulis) 51, 1113 (1990)
Guenet, J.M.: Thermoreversible gels from Polymers and Biopolymers. Academic Press, London (1992)
Terech, P., Pasquier, D., Bordas, V., Rossat, C.: Rheological Properties and Structural Correlations in Molecular Organogels. Langmuir 16, 4485 (2000)
Ramzi, M., Rochas, C., Guenet, J.M.: Structure-Properties Relation for Agarose Thermoreversible Gels in Binary Solvents. Macromolecules 31, 6106 (1998)
Bastide, J., Picot, C., Candau, S.: Influence of pendent chains on the thermodynamic and viscoelastic properties of swollen networks. J. Pol. Sci. B 17, 1441 (1979)
Feng, L., Cavicchi, K.A.: Investigation of the relationships between the thermodynamic phase behavior and gelation behavior of a series of tripodal trisamide compounds. Soft Matter 8, 6483 (2012)
Guenet, J.M.: Polymer-solvent Molecular Compounds. Elsevier, London (2008)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2016 Jean-Michel Guenet
About this chapter
Cite this chapter
Guenet, JM. (2016). Rheological Aspects. In: Organogels. SpringerBriefs in Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-33178-2_6
Download citation
DOI: https://doi.org/10.1007/978-3-319-33178-2_6
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-33176-8
Online ISBN: 978-3-319-33178-2
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)