Abstract
The photoluminescence (PL) spectra of GaS, GaSe, GaTe and InSe semiconductors used as the basis materials to obtain nanocomposite by heat treatment in Zn and Cd vapor were studied. The PL spectra of ZnS–GaS, CdSe–GaSe, CdSe–InSe, ZnSe–InSe composites consist of wide bands covering a wide range of wavelengths in the antistokes region for CdSe, ZnSe and GaS crystallites from composites. The antistokes branches of spectra are interpreted as the shift of PL bands to high energies for nanosized crystallites.
Keywords
- AIIIBVI and AIIBVI semiconductors
- Lamellar semiconductor
- Heat treatment
- Intercalation
- Nanoparticles
- Nanocomposites
- Polycrystalline compound
- Clusters
- Photoluminescence
- Recombination
- Exciton emission
- Impurity band
- Luminescence centers
- Acceptor and donor levels
- Carrier recombination
- Thermal quenching
This is a preview of subscription content, access via your institution.
Buying options

































References
I. Caraman, E. Vatavu, L. Leontie, M. Stamate, D. Untila, Phys. Status Solidi C 12, 70 (2015)
L. Leontie, I. Evtodiev, N. Spalatu, M. Caraman, S. Evtodiev, O. Racovet, M. Girtan, C. Focsa, J. Alloy. Compd. 584, 542 (2014)
D. Untila, V. Cantser, M. Caraman, I. Evtodiev, L. Leontie, L. Dmitroglo, Phys. Status Solidi C 12, 65 (2015)
G.L. Belenkii, M. O. Godzhaev. Phys. Stat. Sol. (b) 85, 453 (1978)
V. Chiricenco, M. Caraman, I.I. Rusu, L. Leontie, J. Lumin. 101, 71 (2003)
S. Shigetomi, K. Sakai, T. Ikari, Phys. Stat. Sol. (b) 241, 2607 (2004)
S. Shigetomi, T. Ikari, J. Lumin. 118, 106 (2006)
T. Aono, K. Kase, A. Kinoshita, J. Appl. Phys. 74, 2818 (1993)
M. Karabulut, G. Bilir, G.M. Mamedov, A. Seyhan, R. Turan, J. Lumin. 128, 1551 (2008)
J.Z. Wan, J.L. Brebner, R. Leonelli, G. Zhao, J.T. Graham, Phys. Rev. B 48, 5197 (1993)
A. Warrier, A.V.R. Warrier, J. Appl. Phys. 53, 5169 (1982)
V. Capozzi, A. Minafra, J. Phys. C: Solid State Phys. 14, 4335 (1981)
V. Capozzi, Phys. Rev. B 23, 836 (1981)
V. Capozzi, Phys. Rev. B 28, 4620 (1983)
S. Shigetomi, T. Ikari, H. Nakashima, J. Appl. Phys. 73, 4686 (1993)
S. Shigetomi, T. Ikari, J. Appl. Phys. 94, 5399 (2003)
S.I. Lee, S.R. Hahn, C.H. Chung, S.H. Yun, W.T. Kim, Solid State Commun. 60, 453 (1986)
C.H. Chung, S.R. Hahn, H.L. Park, W.T. Kim, S.I. Lee, J. Lumin. 40, 405 (1988)
K. Imai, K. Suzuki, T. Haga, Y. Abe, J. Appl. Phys. 60, 3374 (1986)
N. Spalatu, J. Hiie, V. Valdna, M. Caraman, N. Maticiuc, V. Mikli, T. Potlog, M. Krunks, V. Lughi, Energy Procedia 44, 85 (2014)
S.H. Song, J.F. Wang, G.M. Lalev, L. He, M. Isshiki, J. Cryst. Growth 252, 102 (2003)
G. Colibaba, M. Caraman, I. Evtodiev, S. Evtodiev, E. Goncearenco, D. Nedeoglo, N. Nedeoglo, J. Lumin. 145, 237 (2014)
A. Mycielski, E. Lusakowska, A. Szadkowski, L. Kowalczyk, J. Cryst. Growth 184, 1044 (1998)
M.S. Jin, C.D. Kim, W.T. Kim, J. Korean Phys. Soc. 44, 920 (2004)
N. Okamoto, N. Hara, H. Tanaka, IEEE Trans. Electron Dev. 47, 2284 (2000)
S. Shigetomi, T. Ikari, J. Appl. Phys. 95, 6480 (2004)
S. Shigetomi, T. Ikari, J. Lumin. 113, 137 (2005)
N.M. Gasanly, A. Aydinli, H. Ozkan, C. Kocabas, Solid State Commun. 116, 147 (2000)
Y. Sasaki, C. Hamaguchi, J. Nakai, J. Phys. Soc. Jpn. 38, 1698 (1975)
P.T. Landsberg. Recombination in semiconductors. Cambridge, New York, Port Chester, Melbourne (Cambridge University Press, Sydney, 1991). p. 595
I.M. Catalano, R. Cingolani, M. Lepore, Solid State Commun. 60, 385 (1986)
W. Van Gool, A.P. Cleiren, Phil. Res. Rep. 15, 238 (1960)
R.C. Weast. Handbook of Chemistry and Physics. 65. s.l. (CRC Press, 1984), p. 2312
G.B. Abdullaev, V.B. Antonov, T.E. Mekhtiev, EYu. Salaev, Sov. J. Quant. Electron. 4, 80 (1974)
W. van Roosbroeck, W. Shockley, Phys. Rev. 94, 1558 (1954)
J. Pankove. Optical Processes in Semiconductors (Mir, Moscow, 1973)
Y. Depeursinge, C. Depeursinge, J. Phys. C: Solid State Phys. 12, 4851 (1979)
Y.F. Jellinek, H. Hahn, Z. Naturf. 16, 713 (1961)
J. Krustok, H. Collan, K. Hjelt, J. Appl. Phys. 81, 1442 (1997)
K.R. Le Toullec, N. Piccioli, J.C. Chervin, Phys. Rev. B 22, 6162 (1980)
S. Shigetomi, T. Ikari, N. Nishimura, J. Appl. Phys. 69, 7936 (1991)
S. Shigetomi, T. Ikari, H. Nakashima, Phys. Stat. Sol. (a) 160, 159 (1997)
X. Xu, Y. Wang, T. Gule, Q. Luo, L. Zhou, F. Gong, Mater. Res. Bull. 48, 983 (2013)
E.M. Boatman, G.C. Lisensky, K.J. Nordell, J. Chem. Educ. 82, 1697 (2005)
M. Ya, N.V. Valakh, V.V. Vuychik, S.V. Strelchuk, T.V. Sorokin, S. Shubina, V. Ivanov, P.S. Kop’ev. Semiconductors 37, 699 (2003)
X. Peng, Chem. Eur. J. 8, 335 (2002)
M.A. Eliashevich, Atomic and Molecular Spectroscopy (Fizmatgiz, Moscow, 1962)
G.B. Abdullaev, G.L. Belenkii, EYu. Salaev, R.A. Suleisianov, Il Nuovo Cimento 38B, 469 (1977)
G. Micocci, A. Serra, A. Tepore, J. Appl. Phys. 82, 2365 (1997)
G. Micocci, A. Serra, A. Tepore, J. Appl. Phys. 81, 6200 (1997)
B. Pajot, Optical Absorption of Impurities and Defects in Semiconducting Crystals (Springer, Berlin, 2010)
J. Camassel, P. Merle, H. Mathieu, A. Gouskov, Phys. Rev. B 19, 1060 (1979)
N.C. Giles-Taylor, R.N. Bicknell, D.K. Blanks, T.H. Myers, J.F. Schetzina, J. Vac. Sci. Technol. A 3, 76 (1985)
X. Mathew, J.R. Arizmendi, J. Campos, P.J. Sebastian, N.R. Mathews, C.R. Jimenez, M.G. Jimenez, R. Silva-Gonzalez, M.E. Hernandez-Torres, R. Dhere, Sol. Energy Mater. Sol. Cells 70, 379 (2001)
S. Vatavu, H. Zhao, I. Caraman, P. Gaşin, C. Ferekides, Thin Solid Films 517, 2195 (2009)
S. Vatavu, H. Zhao, V. Padma, R. Rudaraju, D.L. Morel, P. Gaşin, Iu Caraman, C.S. Ferekides, Thin Solid Films 515, 6107 (2007)
V. Augelli, C. Manfredotti, R. Murri, R. Piccolo, A. Rizzo, L. Vasanelli, Solid State Commun. 21, 575 (1977)
S. Vatavu, P. Gaşin, Thin Solid Films 515, 6179 (2007)
S. Shigetomi, T. Ikari, Y. Koga, S. Shigetomi, Phys. Stat. Sol. (a) 86, K69 (1984)
G. Micocci, A. Tepore, R. Rella, P. Siciliano, J. Appl. Phys. 71, 2274 (1992)
S. Shigetomi, T. Ikari, Y. Koga, S. Shigetomi. Phys. Stat. Sol. (a) 108, K53 (1988)
G. Micocci, M. Molendini, A. Tepore, F.L. Rella, P. Siciliano, J. Appl. Phys. 70, 6847 (1991)
S. Shigetomi, H. Ohkubo, T. Ikari, J. Phys. Chem. Solids 51, 91 (1990)
M. Di Giulio, G. Micocci, A. Rizzo, A. Tepore, J. Appl. Phys. 54, 5839 (1983)
C.B. Murray, D.J. Norris, M.G. Bawendi, J. Am. Chem. Soc. 115, 8706 (1993)
A.V. Firth, S.W. Haggata, P.K. Khanna, S.J. Williams, J.W. Allen, S.W. Magennis, I.D.W. Samuel, D.J. Cole-Hamilton, J. Lumin. 109, 163 (2004)
A. Chevy, J. Appl. Phys. 56, 978 (1984)
E. Bucher. Physics and Chemistry of Materials with Low-Dimensional Structures, ed. by A. Aruchamy. Photoelectrochemistry and Photovoltaics of Layered Semiconductors (Kluwer Academic Publishers, Dordrecht/Boston/London, 1992), pp. 1–81
T. Ikari, S. Shigetomi, Y. Koga, S. Shigetomi. Phys. Stat. Sol. (b) 109, K81 (1981)
S. Shigetomi, T. Ikari, Y. Koga, S. Shigetomi, Jpn. J. Appl. Phys. 20, L343 (1981)
S. Shigetomi, H. Ohkubo, T. Ikari, H. Nakashyma, J. Appl. Phys. 66, 3647 (1989)
P.J. Dean, A.D. Pitt, M.S. Skolnick, P.J. Wright, B. Cockayne, J. Cryst. Growth 59, 301 (1982)
P.J. Dean, B.J. Fitzpatrick, R.N. Bhargava, Phys. Rev. B 26, 2016 (1982)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Evtodiev, I. et al. (2016). Photoluminescence of Nanocomposites Obtained by Heat Treatment of GaS, GaSe, GaTe and InSe Single Crystals in Cd and Zn Vapor. In: Tiginyanu, I., Topala, P., Ursaki, V. (eds) Nanostructures and Thin Films for Multifunctional Applications. NanoScience and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-30198-3_13
Download citation
DOI: https://doi.org/10.1007/978-3-319-30198-3_13
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-30197-6
Online ISBN: 978-3-319-30198-3
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)