Abstract
The development of analytical system has been focused on two aspects, first in the design of large versatile and robust equipment where operation is performed in a controlled laboratory. The second aspect developed in parallel, is focused on miniaturization and automation of analytical systems that can be used in the place where the sample is taken and generate results in real time. In this work, an automated hydrodynamic system was implemented with miniaturized actuators to provide a micro-flow injection and auto-calibration. The micro-flow injection procedure was operated exploited the multicommutation technique for handling solutions. The auto-calibration was operated by a virtual instrument allowing the response control process in real time. Automated micro-flow injection was developed to perform calibration. The auto-calibration process, the precision and accuracy of the hydrodynamic system was evaluated by spectrophotometric determination of cobalt concentration. A linear response was observed from 0.1 to 3.0 mg L−1. The result was validated with a commercial instrument.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
E.R. Camarillo, R.R. Rodriguez, Microanalyzer with optical detection and wireless communications. Sensors Actuators A Phys. 199, 181–186 (2013)
J. Ruzica, G. Marshall, Sequential injection: a new concept for chemical sensors, process analysis and laboratory assays. Anal. Chim. Acta 237, 329–343 (1990)
B. Reis, M. Giné, E. Zagatto, J. Lima, R. Lapa, Multicommutation in flow analysis. Part 1. Binary sampling: concepts, instrumentation and spectrophotometric determination of iron in plant digests. Anal. Chim. Acta 293, 129–138 (1994)
V. Cerda, J.M. Estela, R. Forteza, A. Cladera, E. Becerra, P. Altamira et al., Flow techniques in water analysis. Talanta 50(4), 695–705 (1999)
J. Ruzicka, Lab on-valve: microflow analyzer based on sequential and bead injection. Analyst 125, 1053–1060 (2000)
R. Lapa, J. Lima, B. Reis, J. Santos, E. Zagatto, Anal. Chim. Acta 466, 125–132 (2002)
Z.M. Da Rocha, C.C. Martinez, A.C. Seabre, R.M. Gongora, C.J. Alonso, Compact and autonomous multiwavelength microanalyzer for in-line and in situ colorimetric determinations. Lab Chip 12, 109–117 (2012)
X. Xiao, T. Zhu, L. Qi, L. Moga, X. Zhang, MS-BWME: A wireless real-time monitoring system for brine well mining equipment. Sensors 14(10), 19877–19896 (2014)
A.M. Bond, 200 years of practical electroanalytical chemistry: past, present and future directions illustrated by reference to the on-line, on-stream and off-line determination of trace metals in zinc plant electrolyte by voltammetric and potentiometric techniques. Anal. Chim. Acta 400, 333–379 (1999)
Y. Izadmanesh, J. Ghasemi, A rapid, automated gradient flow injection-spectrophotometric technique for study of metal complexation reactions. Talanta 128, 511–517 (2014)
T.E. Rodenas, F.R.P. Rocha, F.R. Boaventura, R.A. Morales, M. Guadia, Evaluation of a multicommuted flow system for photometric environmental measurements. J. Autom. Methods Manage. Chem. 2006, 1–9 (2006). ID 20384
N. Ibañez, J. Alonso, C. Martinez, F. Valdes, Green tape ceramics new technological approach for integrating electronic and fluidics in microsystems. Trends Anal. Chem. 7(1), 24–33 (2008)
A. Fonceca, I.M. Raymundo, J.R. Rohwedder, L.O. Ferreire, Construction and evaluation of a flow injection micro-analyzer based on urethane-acrylate resin. Anal. Chim. Acta 603, 159–166 (2007)
S. Silva, R.P. Rocha, A flow injection procedure based in solenoid micro-pump for spectrophotometric determination of free glycerol in biodiesel. Talanta 83, 559–564 (2010)
R.M. Camarillo, J. Alonso, Development of a hydrodynamic system for miniaturized system flow analysis. Rev. Mex. Ing. Quim. 11(2), 299–307 (2012)
P. Gonzalez, M. Knochen, M.K. Sasaki, E. Zagatto, Pulsed flows in flow analysis: potentialities, limitations and applications. Talanta 143, 419–430 (2015)
Y. Hayashibe et al., Method for measuring impurity concentration and removing impurities from electrolytic solution for electrowinning of zinc. USA Patente US005178771A, 12 Jan 1993
B. Purachat, S. Liawruangrath, P. Sooksamitti, S. Rattanaphani, D. Buddhasukh, Univariate and simple optimization for the flow-injection spectrophotometric determination of copper using nitroso-R salt as a complexing agent. Anal. Sci. JSAC 17, 443–447 (2001)
E.R.M. Camarillo, Sistema automatizado de analisis con comunicacion inalambrica utilizando tecnollogia de ceramicas verdes de cocimiento conjunto a bajas temperaturas para mediciones espectrofotometricas in situ y on-line de variables ambientales e industriales. MEX Patente en tramite Mx/a/2013/013751, 25 Noviembre 2013
I. Akyildiz, V.M. Can, Wireless Sensor Networks (Wiley, Torquay, 2010)
D. Reyes, D. Iossidis, P. Aroux, A. Manz, Micrototal analysis system. 1. Introduction, theory and technology. Anal. Chem 7(12), 2623–2636 (2002)
F. Rocha, B. Reis, E. Zagatto, Multicommutation in flow analysis: concepts, applications, potentialities. Anal. Chim. Acta 466, 125–132 (2002)
R. Camarillo, J. García, Automated microanalyzer with auto-calibration and wireless control for in situ and on-line applications. Analytical Instrumentation, 1a edn. (Studium Press LLC, New Delhi, 2015)
N.T. Nguyen, S.T. Wereley, Fundamentals and Applications of Microfluidics, 2dath edn. (Artech House, Boston, 2006)
A. Fonceca, J. Raymundo, M. Ivo, A multichannel photometer based on an array of light emitting diode for use in multivariate calibration. Anal. Chim. Acta 522, 223–229 (2004)
Data Sheet Takasago, Piezoelectric Micropump Driver Board MPD-200A
Data Sheet Takasago, Piezoelectric Micropump SDMP306
Data Sheet NResearch, Microvalves 161T010 2 way NC
Data Sheet LM Technologies, LM 058 RS232 to Bluetooth adapter
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2017 Springer International Publishing Switzerland
About this paper
Cite this paper
Camarillo E., R.M. et al. (2017). Auto-Calibration and Micro-Flow Injection Procedure Based on Automated Hydrodynamic System for Spectrophotometric Determination of Cobalt. In: Martínez-García, A., Furlong, C., Barrientos, B., Pryputniewicz, R. (eds) Emerging Challenges for Experimental Mechanics in Energy and Environmental Applications, Proceedings of the 5th International Symposium on Experimental Mechanics and 9th Symposium on Optics in Industry (ISEM-SOI), 2015. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-28513-9_36
Download citation
DOI: https://doi.org/10.1007/978-3-319-28513-9_36
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-28511-5
Online ISBN: 978-3-319-28513-9
eBook Packages: EngineeringEngineering (R0)