Abstract
Silicene has so far been successfully grown on metallic substrates, like Ag(111), ZrB2(0001) and Ir(111) surfaces. However, characterization of its electronic structure is hampered by the metallic substrate. In addition, potential applications of silicene in nanoelectronic devices will require its growth/integration with semiconducting or insulating substrates. In this chapter, we review recent theoretical works about the interaction of silicene with several non-metallic templates, distinguishing between the weak van der Waals like interaction of silicene with e.g. AlN or layered metal (di)chalcogenides, and the stronger covalent bonding between silicene and e.g. ZnS surfaces. Recent experimental results on the possible growth of silicene on MoS2 are also highlighted and compared to the theoretical predictions.
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Acknowledgments
This work has been financially supported by the European Project 2D-NANOLATTICES, within the Future and Emerging Technologies (FET) program of the European Commission, under the FET-grant number 270749, as well as the KU Leuven Research Funds, project GOA/13/011. We are grateful to A. Molle (MDM Laboratory), A. Dimoulas (NCSR Demokritos), G. Pourtois (imec), E. Scalise (Max Planck Institute), B. van den Broek and K. Iordanidou, (KU Leuven) for their valuable contributions to this work and for stimulating discussions.
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Houssa, M., Stesmans, A., Afanas’ev, V.V. (2016). Interaction Between Silicene and Non-metallic Surfaces. In: Spencer, M., Morishita, T. (eds) Silicene. Springer Series in Materials Science, vol 235. Springer, Cham. https://doi.org/10.1007/978-3-319-28344-9_6
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