Skip to main content

Understanding Stoichiometry: Do Scientific Laws Help in Learning Science?

  • Chapter
  • First Online:

Part of the book series: Science: Philosophy, History and Education ((SPHE))

Abstract

Stoichiometry is considered a difficult topic for students as understanding depends on various other topics, such as the particulate nature of matter, the concept of mole, Avogadro’s number, conservation of matter, balancing chemical equations, and the laws of definite and multiple proportions. Furthermore, according to A. Rocke, from the historical perspective, laws of definite and multiple proportions are nothing more than special cases of the law of equivalent proportions. This chapter reports the design of a teaching strategy based on a history and philosophy of science framework to facilitate high school students’ understanding of stoichiometry. Control group students received instruction in which the laws of definite and multiple proportions were defined as definitive and irrefutable and applied as algorithms. Experimental group students used a dialectic constructivist strategy based on the presentation of hypothetical experimental data, leading to cognitive conflicts and to a critical confrontation of different propositions. Based on the HPS framework (Giere and others), the instructor avoided defining the laws of definite and multiple proportions, unless the students themselves used these terms. Based on a posttest, results obtained revealed that experimental group students performed better than those in the control group, not only on the algorithmic problems but also on problems requiring conceptual understanding. It is concluded that if scientific laws are idealizations, then they do not describe the behavior of actual bodies and hence may not be very helpful in understanding the empirical world.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   89.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   119.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   119.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  • Adey, P., & Shayer, M. (1994). Really raising standards: Cognitive intervention and academic achievement. London: Routledge.

    Google Scholar 

  • Agung, S., & Schwartz, M. S. (2007). Students’ understanding of conservation of matter, stoichiometry and balancing equations in Indonesia. International Journal of Science Education, 29(3), 1679–1702.

    Article  Google Scholar 

  • Bidell, T. (1988). Piaget, Vygotsky and the dialectic of development. Human Development, 31, 329–348.

    Article  Google Scholar 

  • Blanco, R., & Niaz, M. (1997). Epistemological beliefs of students and teachers about the nature of science: From ‘Baconian inductive ascent’ to the ‘irrelevance’ of scientific laws. Instructional Science, 25, 203–231.

    Article  Google Scholar 

  • Blanco, R., & Niaz, M. (1998). Baroque tower on a gothic base: A Lakatosian reconstruction of students’ and teachers’ understanding of structure of the atom. Science & Education, 7, 327–360.

    Article  Google Scholar 

  • BouJaoude, S., & Barakat, H. (2003). Students’ problem solving strategies in stoichiometry and their relationship to conceptual understanding and learning approaches. Electronic Journal of Science Education, 7(3), 1–42.

    Google Scholar 

  • Brown, J. R. (1990). Proof and truth in Lakatos’s masterpiece. International Studies in the Philosophy of Science, 4(2), 117–130.

    Article  Google Scholar 

  • Cartwright, N. (1983). How the laws of physics lie. Oxford: Clarendon Press.

    Book  Google Scholar 

  • Cartwright, N. (1989). Nature’s capacities and their measurement. Oxford: Clarendon Press.

    Google Scholar 

  • Cartwright, N. (1999). The dappled world: A study of the boundaries of science. Cambridge: Cambridge University Press.

    Book  Google Scholar 

  • Chinn, C. A., & Brewer, W. F. (1993). The role of anomalous data in knowledge acquisition: A theoretical framework and implications for science instruction. Review of Educational Research, 63, 1–49.

    Article  Google Scholar 

  • Christie, M. (1994). Philosophers versus chemists concerning ‘laws of nature’. Studies in History and Philosophy of Science, 25, 613–629.

    Article  Google Scholar 

  • Cobb, P., & Steffe, L. (1983). The constructivist researcher as theory and model builder. Journal for Research in Mathematics Education, 14, 83–94.

    Article  Google Scholar 

  • D’Ambrosio, B. S., & Campos, T. M. M. (1992). Preservice teachers’ representation of children’s understanding of mathematical concepts: Conflicts and conflict resolution. Educational Studies in Mathematics, 23, 213–230.

    Article  Google Scholar 

  • Dahsah, C., & Coll, R. K. (2007). Thai grade 10 and 11 students’ conceptual understanding and ability to solve stoichiometry problems. Research in Science and Technological Education, 25(2), 227–241.

    Article  Google Scholar 

  • Duschl, R. A., & Duncan, R. G. (2009). Reply to both questions. In S. Tobias & T. M. Duffy (Eds.), Constructivist instruction: Success or failure? (p. 324). New York: Routledge.

    Google Scholar 

  • Feynman, R. (1967). The character of physical law. Cambridge, MA: MIT Press.

    Google Scholar 

  • Gabel, D. L. (1993). Use of particle nature of matter in developing conceptual understanding. Journal of Chemical Education, 70, 193–194.

    Article  Google Scholar 

  • Gabel, D. L., & Bunce, D. M. (1994). Research on problem solving: Chemistry. In D. L. Gabel (Ed.), Handbook of research on science teaching and learning (pp. 301–326). New York: Macmillan.

    Google Scholar 

  • Garritz, A., Sosa, S., Hernández-Millán, G., López-Villa, N. M., Nieto-Calleja, E., Flor de María Reyes-Cárdenas, F., & César Robles Haro, C. (2013). Una secuencia de enseñanza/aprendizaje para los conceptos de sustancia y reacción química con base en la Naturaleza de la Ciencia y la Tecnología. Educacion Quimica, 24, 439–450.

    Google Scholar 

  • Giere, R. N. (1995a). Viewing science. In R. Burian, D. Hull, & M. Forbes (Eds.), PSA 1994 (Vol. 2). East Lansing: Philosophy of Science Association (revised version of the Presidential address at the Biennial Meeting of the Philosophy of Science Association, New Orleans, October, 1994).

    Google Scholar 

  • Giere, R. N. (1995b). The skeptical perspective: Science without laws of nature. In F. Weinert (Ed.), Laws of nature: Essays on the philosophical, scientific and historical dimensions (pp. 120–138). Berlin: Walter de Gruyter.

    Google Scholar 

  • Giere, R. N. (1999). Science without laws. Chicago: University of Chicago Press.

    Google Scholar 

  • Giere, R. N. (2006a). Scientific perspectivism. Chicago: University of Chicago Press.

    Book  Google Scholar 

  • Good, R. (1993). Editorial: The many forms of constructivism. Journal of Research in Science Teaching, 30, 1015.

    Article  Google Scholar 

  • Gulacar, O., Eilks, I., & Bowman, C. R. (2014). Differences in general cognitive abilities and domain-specific skills of higher– and lower-achieving students in stoichiometry. Journal of Chemical Education, 91, 961–968.

    Article  Google Scholar 

  • Gultepe, N., Celik, A. Y., & Kilic, Z. (2013). Exploring effects of high school students’ mathematical processing skills and conceptual understanding of chemical concepts on algorithmic problem solving. Australian Journal of Teacher Education, 38(10), 105–122.

    Article  Google Scholar 

  • Justi, R., & Gilbert, J. (1999). A cause of ahistorical science teaching: Use of hybrid models. Science Education, 83, 163–177.

    Article  Google Scholar 

  • Kirschner, P. A., Sweller, J., & Clark, R. (2006). Why minimal guidance during instruction does not work: An analysis of the failure of constructivist, discovery, problem-based, experiential and inquiry-based teaching. Educational Psychologist, 41, 75–86.

    Article  Google Scholar 

  • Kitchener, R. F. (1993). Piaget’s epistemic subject and science education: Epistemological vs psychological issues. Science & Education, 2, 137–148.

    Article  Google Scholar 

  • Lakatos, I. (1970). Falsification and the methodology of scientific research programmes. In I. Lakatos & A. Musgrave (Eds.), Criticism and the growth of knowledge (pp. 91–195). Cambridge: Cambridge University Press.

    Chapter  Google Scholar 

  • Lakatos, I. (1971). History of science and its rational reconstructions. In R. C. Buck & R. S. Cohen (Eds.), Boston studies in the philosophy of science (Vol. 8, pp. 91–136). Dordrecht: Reidel.

    Google Scholar 

  • Lawler, J. (1975). Dialectical philosophy and developmental psychology: Hegel and Piaget on contradiction. Human Development, 18, 1–17.

    Article  Google Scholar 

  • Lawson, A. E., Abraham, M. R., & Renner, J. W. (1989). A theory of instruction: Using the learning cycle to teach science concepts and thinking skills. Monographs of the National Association for Research in Science Teaching, 1, 1–57.

    Google Scholar 

  • Lee, G., & Yi, J. (2013). Where cognitive conflict arises from? The structure of creating cognitive conflict. International Journal of Science and Mathematics Education, 11, 601–623.

    Article  Google Scholar 

  • Lombardi, O., & Labarca, M. (2007). The philosophy of chemistry as a new resource for chemistry education. Journal of Chemical Education, 84(1), 187–192.

    Article  Google Scholar 

  • Matthews, M. R. (1987). Experiment as the objectification of theory: Galileo’s revolution. Proceedings of the second international seminar on misconceptions and educational strategies in science and mathematics (I, pp. 289–298). Ithaca: Cornell University.

    Google Scholar 

  • Matthews, M. R. (1997). Introductory comments on philosophy and constructivism in science education. Science & Education, 6, 5–14.

    Article  Google Scholar 

  • McMullin, E. (1985). Galilean idealization. Studies in History and Philosophy of Science, 16, 247–273.

    Article  Google Scholar 

  • Niaz, M. (1988). Manipulation of M-demand of chemistry problems and its effect on student performance: A neo-Piagetian study. Journal of Research in Science Teaching, 25, 643–657.

    Article  Google Scholar 

  • Niaz, M. (1995a). Cognitive conflict as a teaching strategy in solving chemistry problems: A dialectic-constructivist perspective. Journal of Research in Science Teaching, 32, 959–970.

    Article  Google Scholar 

  • Niaz, M. (1995b). Progressive transitions from algorithmic to conceptual understanding in student ability to solve chemistry problems: A Lakatosian interpretation. Science Education, 79, 19–36.

    Article  Google Scholar 

  • Niaz, M. (2001a). Understanding nature of science as progressive transitions in heuristic principles. Science Education, 85, 684–690.

    Article  Google Scholar 

  • Niaz, M. (2001b). How important are the laws of definite and multiple proportions in chemistry and teaching chemistry? — A history and philosophy of science perspective. Science & Education, 10, 243–266.

    Article  Google Scholar 

  • Niaz, M. (2008). Teaching general chemistry: A history and philosophy of science approach. New York: Nova Science Publishers.

    Google Scholar 

  • Niaz, M. (2009). Critical appraisal of physical science as a human enterprise: Dynamics of scientific progress. Dordrecht: Springer.

    Google Scholar 

  • Niaz, M. (2011). Innovating science teacher education: A history and philosophy of science perspective. New York: Routledge.

    Google Scholar 

  • Niaz, M. (2012a). From ‘science in the making’ to understanding the nature of science: An overview for science educators. New York: Routledge.

    Google Scholar 

  • Niaz, M., & Montes, L. A. (2012). Understanding stoichiometry: Towards a history and philosophy of chemistry. Educacion Quimica, 23, 290–297.

    Google Scholar 

  • Niaz, M., & Robinson, W. R. (1993). Teaching algorithmic problem solving or conceptual understanding: Role of developmental level, mental capacity, and cognitive style. Journal of Science Education and Technology, 2, 407–416.

    Article  Google Scholar 

  • Niaz, M., Abd-El-Khalick, F., Benarroch, A., Cardellini, L., Laburú, C. E., Marín, N., Montes, L. A., Nola, R., Orlik, Y., Scharmann, L. C., Tsai, C.-C., & Tsaparlis, G. (2003). Constructivism: Defense or a continual critical appraisal — A response to Gil-Pérez et al. Science & Education, 12, 787–797.

    Article  Google Scholar 

  • Nola, R. (1997). Constructivism in science and science education: A philosophical critique. Science & Education, 6, 55–83.

    Article  Google Scholar 

  • Nurrenbern, S. C., & Pickering, M. (1987). Concept learning versus problem solving: Is there a difference? Journal of Chemical Education, 64, 508–510.

    Article  Google Scholar 

  • Osborne, J. F. (1996). Beyond constructivism. Science Education, 80, 53–82.

    Article  Google Scholar 

  • Padilla, K., & Furio-Mas, C. (2008). The importance of history and philosophy of science in correcting distorted views of ‘amount of substance’ and ‘mole’ concepts in chemistry teaching. Science & Education, 17, 403–424.

    Article  Google Scholar 

  • Pascual-Leone, J. (1976). A view of cognition from a formalist’s perspective. In K. F. Riegel & J. A. Meacham (Eds.), The developing individual in a changing world (pp. 89–100). The Hague: Mouton.

    Google Scholar 

  • Pascual-Leone, J. (1987). Organismic processes for neo-Piagetian theories: A dialectical causal account of cognitive development. International Journal of Psychology, 22, 531–570.

    Article  Google Scholar 

  • Perkins, D. N. (2006). Constructivism and troublesome knowledge. In J. H. F. Meyer & R. Lands (Eds.), Overcoming barriers to student understanding: Threshold concepts and troublesome knowledge (pp. 33–47). London: Routledge.

    Google Scholar 

  • Phillips, D. C. (1995). The good, the bad, and the ugly: The many faces of constructivism. Educational Researcher, 24, 5–12.

    Article  Google Scholar 

  • Piaget, J. (1985). The equilibration of cognitive structures: The central problem of intellectual development. Chicago: University of Chicago Press.

    Google Scholar 

  • Piaget, J., & Garcia, R. (1989). Psychogenesis and the history of science. New York: Columbia University Press.

    Google Scholar 

  • Reese, H. (1982). A comment on the meaning of ‘dialectics’. Human Development, 25, 423–429.

    Article  Google Scholar 

  • Riegel, K. F. (1979). Foundations of dialectical psychology. New York: Academic Press.

    Google Scholar 

  • Rocke, A. J. (2013a). Email to author dated October 30, 2013, reproduced with permission.

    Google Scholar 

  • Rocke, A. J. (2013b). Email to author dated November 3, 2013, reproduced with permission.

    Google Scholar 

  • Rodgers, G. E. (1995). Introduction to coordination, solid state, and descriptive inorganic chemistry (Spanish ed.). New York: McGraw-Hill.

    Google Scholar 

  • Ryan, A. G., & Aikenhead, G. S. (1992). Students’ preconceptions about the epistemology of science. Science Education, 76, 559–580.

    Article  Google Scholar 

  • Sawrey, B. (1990). Concept learning versus problem solving: Revisited. Journal of Chemical Education, 67, 253–254.

    Article  Google Scholar 

  • Schmidt, H. J. (1997). An alternative path to stoichiometry problem solving. Research in Science Education, 27, 237–249.

    Article  Google Scholar 

  • Segal, B. G. (1989). Chemistry: Experiment and theory (2nd ed.). New York: Wiley.

    Google Scholar 

  • Smith, M. U., & Scharmann, L. C. (1999). Defining versus describing the nature of science: A pragmatic analysis for classroom teachers and science educators. Science Education, 83(4), 493–509.

    Article  Google Scholar 

  • St Clair-Thompson, H. L., Overton, T., & Bugler, M. (2012). Mental capacity and working memory in chemistry: Algorithmic versus open-ended problem solving. Chemistry Education Research and Practice, 13, 484–489.

    Article  Google Scholar 

  • Staver, J. R., & Lumpe, A. T. (1995). Two investigations of students’ understanding of the mole concept and its use in problem solving. Journal of Research in Science Teaching, 32, 177–193.

    Article  Google Scholar 

  • Stinner, A. (1992). Science textbooks and science teaching: From logic to evidence. Science Education, 76(1), 1–16.

    Article  Google Scholar 

  • Taylor, P. C. (2015). Constructivism. In R. Gunstone (Ed.), Encyclopedia of science education (pp. 218–223). Heidelberg: Springer.

    Chapter  Google Scholar 

  • Tobias, S. (2009). An eclectic appraisal of the success or failure of constructivist instruction. In S. Tobias & T. M. Duffy (Eds.), Constructivist instruction: Success or failure? (pp. 335–350). New York: Routledge.

    Google Scholar 

  • Tsaparlis, G. (1998). Dimensional analysis and predictive models in problem solving. International Journal of Science Education, 20, 335–350.

    Article  Google Scholar 

  • Tsaparlis, G., & Zoller, U. (2003). Evaluation of higher vs. lower-order cognitive skills-type examinations in chemistry: Implications for university in-class assessment and examinations. University Chemistry Education, 7, 50–57.

    Google Scholar 

  • Yuan, K., Steedle, J., Shavelson, R., Alonzo, A., & Oppezzo, M. (2006). Working memory, fluid intelligence and science learning. Educational Research Review, 1, 83–98.

    Article  Google Scholar 

  • Zoller, U., & Tsaparlis, G. (1997). Higher and lower-order cognitive skills: The case of chemistry. Research in Science Education, 27, 117–130.

    Article  Google Scholar 

  • Zoller, U., Dori, Y. J., & Lubezky, A. (2002). Algorithmic, LOCS and HOCS (chemistry) exam questions: Performance and attitudes of college students. International Journal of Science Education, 24(2), 185–203.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Niaz, M. (2016). Understanding Stoichiometry: Do Scientific Laws Help in Learning Science?. In: Chemistry Education and Contributions from History and Philosophy of Science. Science: Philosophy, History and Education. Springer, Cham. https://doi.org/10.1007/978-3-319-26248-2_5

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-26248-2_5

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-26246-8

  • Online ISBN: 978-3-319-26248-2

  • eBook Packages: EducationEducation (R0)

Publish with us

Policies and ethics