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Biogenic—Abiogenic Interactions in Natural and Anthropogenic Systems pp 517–529Cite as

Biomimetic Synthesis of Strontium-Containing Apatite and Its Peculiar Properties

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Part of the book series: Lecture Notes in Earth System Sciences ((LNESS))

Abstract

This paper examines the influence of strontium chloride on the process of crystallization of strontium-substituted carbonated hydroxyapatite from prototype human synovial fluid. Products of synthesis were studied by Fourier transform infrared spectroscopy, X-ray diffraction, and differential thermal analysis. The amount of strontium in the sample using atomic emission analysis was determined. For the synthesized phases, Ca/P-ratio, the parameters of crystallinity, the crystallite size using the formula of Selyakov-Scherrer, and crystal lattice parameters were calculated. It was established that increasing the concentration of strontium ions in the analytical model increases the proportion of brushite in the solid phase. It was found that with increasing formation of a precipitate beneath the mother liquor, the kinetically stable-phase of brushite transforms to the thermodynamically more stable phase (Sr-containing carbonated hydroxyapatite).

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Acknowledgments

The study was supported by Russian Foundation for Basic Research (RFBR) within the scientific project №14_03_31506 mol_a.

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Authors and Affiliations

  1. Omsk F.M. Dostoevsky State University, Omsk, Russia

    Rinat R. Izmailov & Olga A. Golovanova

  2. National Research Tomsk Polytechnic University, Tomsk, Russia

    Marina V. Kuimova

Authors
  1. Rinat R. Izmailov
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  2. Olga A. Golovanova
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  3. Marina V. Kuimova
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Corresponding author

Correspondence to Rinat R. Izmailov .

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Editors and Affiliations

  1. Institute of Earth Sciences, Saint Petersburg State University, Saint Petersburg, Russia

    Olga V. Frank-Kamenetskaya

  2. Department of Geochemistry, Saint Petersburg State University, Saint Petersburg, Russia

    Elena G. Panova

  3. Department of Botany, Saint Petersburg State University, Saint Petersburg, Russia

    Dmitry Yu. Vlasov

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© 2016 Springer International Publishing Switzerland

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Izmailov, R.R., Golovanova, O.A., Kuimova, M.V. (2016). Biomimetic Synthesis of Strontium-Containing Apatite and Its Peculiar Properties. In: Frank-Kamenetskaya, O., Panova, E., Vlasov, D. (eds) Biogenic—Abiogenic Interactions in Natural and Anthropogenic Systems. Lecture Notes in Earth System Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-24987-2_39

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