Abstract
Optical properties of noble metal (Au, Ag) nanoclusters are of remarkable interest owing to the understanding fundamental issues of electronic properties in the small metallic clusters and their applications in nonlinear optics. The surface plasmon resonance (SPR), defined as resonance frequency of coherently oscillating free electrons with the exciting light, occurring in the near-UV-Visible region leads to the major applications. We discuss results, both experimental and theoretical, reporting the red or blue shift of the SPR frequency with decreasing noble metal cluster size as an effect of embedding matrix and surrounding porosity as well as in free noble metal nanoclusters without matrix. Reduction of the electron density (spillout effect) in the small nanoclusters and the interband screening of electrons in noble metals for larger nanoclusters shift the frequency of light absorbed either to the red or blue region, respectively, with decreasing cluster size. A strong dependence of the cluster size with the SPR frequency is discussed using time dependent local density approximation (TDLDA) with the consideration of porosity of surrounding medium. As the most recent report, quantum effect is also considered to understand blue shift of the SPR frequency of individual Ag nanoclusters with reducing size.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Lermé J, Palpant B, Prével B, Pellarin M, Treilleux M, Vialle JL, Perez A, Broyer M (1998) Quenching of the size effects in free and matrix-embedded silver clusters. Phys Rev Lett 80:5105–5108
Liao HB, Xiao RF, Fu JS, Yu P, Wong GKL, Sheng P (1997) Large third-order optical nonlinearity in Au:SiO2 composite films near the percolation threshold. Appl Phys Lett 70:1–3
Dhara S, Lu C-Y, Magudapathy P, Huang Y-F, Tu W-S, Chen K-H (2015) Surface plasmon polariton assisted optical switching in noble bimetallic nanoparticle system. Appl Phys Lett 106:023101
Dhara S, Lu C-Y, Chen K-H (2015) Plasmonic switching in Au functionalized GaN nanowires in the realm of surface plasmon polatriton propagation: a single nanowire switching device. Plasmonics 10:347–350
Atwater HA, Polman A (2010) Plasmonics for improved photovoltaic devices. Nature Mater 9:205–213
Lal S, Clare SE, Halas NJ (2008) Nanoshell-enabled photothermal cancer therapy: impending clinical impact. Acc Chem Res 41:1842–1851
Juluri BK, Zheng YB, Ahmed D, Jensen L, Huang TJ (2008) Effects of geometry and composition on charge-induced plasmonic shifts in gold nanoparticles. J Phys Chem C 112:7309–7317
Nie S, Emory SR (1997) Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275:1102–1106
Garg P, Dhara S (2013) Single molecule detection using SERS study in PVP functionalized Ag nanoparticles. AIP Conf Proc 1512:206–207
Zhang R, Zhang Y, Dong ZC, Jiang S, Zhang C, Chen LG, Zhang L, Liao Y, Aizpurua J, Luo Y, Yang JL, Hou JG (2013) Chemical mapping of a single molecule by plasmon-enhanced Raman scattering. Nature 498:82–86
Kreibig U, Vollmer M (1995) Optical properties of metal clusters. Springer, Berlin
Palpant B, Prével B, Lermé J, Cottancin E, Pellarin M, Treilleux M, Perez A, Vialle JL, Broyer M (1998) Optical properties of gold clusters in the size range 2–4 nm. Phys Rev B 57:1963–1970
Lermé J, Palpant B, Prével B, Cottancin E, Pellarin M, Treilleux M, Vialle JL, Perez A, Broyer M (1998) Optical properties of gold metal clusters: a time-dependent local-density-approximation investigation. Eur Phys J D 4:95–108
Srivastava SK, Gangopadhyay P, Amirthapandian S, Sairam TN, Basu J, Panigrahi BK, Nair KGM (2014) Effects of high-energy Si ion-irradiations on optical responses of Ag metal nanoparticles in a SiO2 matrix. Chem Phys Lett 607:100–104
Scholl JA, Koh AL, Dionne JA (2012) Quantum plasmon resonances of individual metallic nanoparticles. Nature 483:421–427
Hosoya Y, Suga T, Yanagawa T, Kurokawa Y (1997) Linear and nonlinear optical properties of sol–gel-derived Au nanometer-particle-doped alumina. J Appl Phys 81:1475–1480
Meldrum A, Boatner LA, White CW, Ewing RC (2000) Ion irradiation effects in nonmetals: formation of nanocrystals and novel microstructures. Mater Res Innov 3:190–204
Miotelo A, De Merchi G, Mattei G, Mazzoldi P, Sada C (2001) Clustering of gold atoms in ion-implanted silica after thermal annealing in different atmospheres. Phys Rev B 63:075409
Dai Z, Yamamoto S, Narumi K, Miyashita A, Naramoto H (1999) Gold nanoparticle fabrication in single crystal SiO2 by MeV Au ion implantation and subsequent thermal annealing. Nucl Instr Meth Phys Res B 149:108–112
Ila D, Williams EK, Zimmerman RL, Poker DB, Hensley DK (2000) Radiation induced nucleation of nanoparticles in silica. Nucl Instr Meth Phys Res B 166–167:845–850
Dhara S, Sundaravel B, Ravindran TR, Nair KGM, David C, Panigrahi BK, Magudapathy P, Chen KH (2004) ‘Spillout’ effect in gold nanoclusters embedded in c-Al2O3(0001) matrix. Chem Phys Lett 399:354–358
Dhara S, Kesavamoorthy R, Magudapathy P, Premila M, Panigrahi BK, Nair KGM, Wu CT, Chen KH (2003) Quasiquenching size effects in gold nanoclusters embedded in silica matrix. Chem Phys Lett 370:254–260
Raza S, Stenger N, Kadkhodazadeh S, Fischer SV, Kostesha N, Jauho A-P, Burrows A, Wubs M, Mortensen NA (2013) Blueshift of the surface plasmon resonance in silver nanoparticles studied with EELS. Nanophotonics 2:131–138
Palpant B, Portales H, Saviot L, Lerme J, Prevel B, Pellarin M, Duval E, Perez A, Broyer M (1999) Quadrupolar vibrational mode of silver clusters from plasmon-assisted Raman scattering. Phys Rev B 60:17107–17111
Saviot L, Murray DB, de Lucas M (2004) Vibrations of free and embedded anisotropic elastic spheres: application to low-frequency Raman scattering of silicon nanoparticles in silica. Phys Rev B 69:113402–113404
Ekardt W (1984) Work function of small metal particles: self-consistent spherical jellium-background model. Phys Rev B 29:1558–1564
Wannier GH (1962) Dynamics of band electrons in electric and magnetic fields. Rev Mod Phys 34:645–655
Nenciu G (1991) Dynamics of band electrons in electric and magnetic fields: rigorous justification of the effective Hamiltonians. Rev Mod Phys 63:91–128
Feldmann J, Leo K, Shah J, Miller DAB, Cunningham JE, Meier T, von Plessen G, Schulze A, Thomas P, Schmitt-Rink S (1992) Optical investigation of Bloch oscillations in a semiconductor superlattice. Phys Rev B 46:7252–7255
Hawton M, Dignam MM (2003) Infinite-order excitonic Bloch equations for asymmetric nanostructures. Phys Rev Lett 91:267402
Bruggeman DAG (1935) Calculation of various physical constants of heterogeneous substances. Ann Phys (Leipzig) 24:636–679
Tiggesbäumker J, Köller L, Meiwes-Broer KH, Liebsch A (1993) Blue shift of the Mie plasma frequency in Ag clusters and particles. Phys Rev A 48:R1749–R1752
Fedrigo S, Harbich W, Buttet J (1993) Collective dipole oscillations in small silver clusters embedded in rare-gas matrices. Phys Rev B 47:10706
Charl’e KP, Schulze W, Winter B (1989) The size dependent shift of the surface plasmon absorption band of small spherical metal particles. Z Phys D 12:471–475
Genzel L, Martin TP, Kreibig U (1975) Dielectric function and plasma resonances of small metal particles. Z Phys B 21:339–346
Cottancin E, Lerme’ J, Gaudry M, Pellarin M, Vialle J-L, Broyer M, Pre’vel B, Treilleux M, Me’linon P (2000) Size effects in the optical properties of Au n Ag n embedded clusters. Phys Rev B 62:5179–5185
Thongrattanasiri S, Manjavacas A, GarcÃa de Abajo FJ (2012) Quantum finite-size effects in graphene plasmons. ACS Nano 6:1766–1775
Bailo E, Deckert V (2008) Tip-enhanced Raman scattering. Chem Soc Rev 37:921–930
Gaudry M, Lerme’ J, Cottancin E, Pellarin M, Vialle J-L, Broyer M, Pre’vel B, Treilleux M, Me’linon P (2001) Optical properties of (Au x Ag1−x ) n clusters embedded in alumina: evolution with size and stoichiometry. Phys Rev B 64:085407
Ripken K (1972) Optical-constants of Au, Ag and their alloys in energy region from 2.4 to 4.4 eV. Z Phys 250:228–234
Nilsson PO (1970) Electronic structure of disordered alloys: optical and photoemission measurements on Ag-Au and Cu-Au alloys. Phys Kondens Mater 11:1–18
Rakić AD, Djurišić AB, Elazar JM, Majewski ML (1998) Optical properties of metallic films for vertical-cavity optoelectronic devices. Appl Opt 37:5271–5283
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Dhara, S. (2016). Origin of Shifts in the Surface Plasmon Resonance Frequencies for Au and Ag Nanoparticles. In: Geddes, C. (eds) Reviews in Plasmonics 2015. Reviews in Plasmonics, vol 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-24606-2_11
Download citation
DOI: https://doi.org/10.1007/978-3-319-24606-2_11
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-24604-8
Online ISBN: 978-3-319-24606-2
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)