Skip to main content

AlGaN-Based Ultraviolet Laser Diodes

  • Chapter
  • First Online:
III-Nitride Ultraviolet Emitters

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 227))

Abstract

The current status of UV lasers and laser diodes (LDs) based on group III-nitrides is reviewed. The focus is on the design, fabrication, and performance of AlGa(In)N laser heterostructures grown by metal–organic vapor phase epitaxy (MOVPE) on high-quality bulk AlN substrates. The review begins with the fundamentals of laser diode operation and identifies the challenges to realize short-wavelength devices with wide band gap materials. In particular, simultaneously achieving high material quality and good p-type conductivity becomes increasingly challenging with higher aluminum concentrations in the epitaxial films. Using low defect density bulk AlN substrates is a good strategy to realize high internal quantum efficiencies and, ultimately, high gain within the active zone. Polarization-assisted hole generation with a short-period superlattice for the cladding layer is a viable approach to overcome the limitations of thermally activated p-type doping. Topics include LD processing considerations that are relevant for the high band gap materials, issues related to efficient carrier injection at the high current densities required for LD operation, and specific approaches to improve the functionality of the electron blocking layer. Next, results are presented for optically pumped UV lasers, with wavelengths down to λ = 237 nm and low lasing thresholds, and design options are described to manipulate the polarization of the emitted laser light. The review concludes with a discussion of alternative laser designs to realize deep-UV laser emission with nitride semiconductors.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 99.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 129.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. A.L. Schawlow, C.H. Townes, Infrared and optical masers. Phys. Rev. 112, 1940 (1958)

    Article  Google Scholar 

  2. S. Nakamura, M. Senoh, S. Nagahama, N. Iwasa, T. Yamada, T. Matsushita, Y. Sugimoto, H. Kiyoku, Room-temperature continuous-wave operation of InGaN multi-quantum-well structure laser diodes. Appl. Phys. Lett. 69, 4056 (1996)

    Article  Google Scholar 

  3. S. Brüninghoff, C. Eichler, S. Tautz, A. Lell, M. Sabathil, S. Lutgen, U. Strauß, 8 W single-emitter InGaN laser in pulsed operation. Phys. Status Solidi A 206, 1149 (2009)

    Article  Google Scholar 

  4. S. Nagahama, Current Status and future prospects of GaN-based LDs, in IWN 2012 Conference, Sapporo (2012)

    Google Scholar 

  5. K. Yanashima, H. Nakajima, K. Tasai et al., Long-lifetime true green laser diodes with output power over 50 mW above 525 nm grown on semipolar 2021 GaN substrates. Appl. Phys. Exp. 5, 082103 (2012)

    Article  Google Scholar 

  6. S.R. Lee, D.D. Koleske, K.C. Cross, J.A. Floro, K.E. Waldrip, A.T. Wise, S. Mahajan, In situ measurements of the critical thickness for strain relaxation in AlGaN/GaN heterostructures. Appl. Phys. Lett. 85, 6164 (2004)

    Article  Google Scholar 

  7. K.B. Nam, M.L. Nakarmi, J. Li, J.Y. Lin, H.X. Jiang, Mg acceptor level in AlN probed by deep ultraviolet photoluminescence. Appl. Phys. Lett. 83, 878 (2003)

    Article  Google Scholar 

  8. M. Kneissl, T. Kolbe, J. Schlegel, J. Stellmach, C. Chua, Z. Yang, A. Knauer, M. Weyers, N.M. Johnson, AlGaN-Based Ultraviolet Lasers—Applications and Materials Challenges. OSA Technical Digest (CD) (Optical Society of America, 2011), JTuB1 (2011)

    Google Scholar 

  9. H. Yoshida, Y. Yamashita, M. Kuwabara, H. Kan, Demonstration of an ultraviolet 336 nm AlGaN multiple-quantum-well laser diode. Appl. Phys. Lett. 93, 241106 (2008)

    Article  Google Scholar 

  10. M. Kneissl, Z. Yang, M. Teepe, C. Knollenberg, O. Schmidt, P. Kiesel, N.M. Johnson, S. Schujman, L.J. Schowalter, Ultraviolet semiconductor laser diodes on bulk AlN. J. Appl. Phys. 101, 123103 (2007)

    Article  Google Scholar 

  11. S.B. Schujman, L.J. Schowalter, R.T. Bondokov, K.E. Morgan, W. Liu, J.A. Smart, T. Bettles, Structural and surface characterization of large diameter, crystalline AlN substrates for device fabrication. J. Cryst. Growth 310, 887 (2008)

    Article  Google Scholar 

  12. R. Dalmau, B. Moody, R. Schlesser, S. Mita, J. Xie, M. Feneberg, B. Neuschl, K. Thonke, R. Collazo, A. Rice, J. Tweedie, Z. Sitar, Growth and characterization of AlN and AlGaN epitaxial films on AlN single crystal substrates. J. Electrochem. Soc. 158, H530 (2011)

    Article  Google Scholar 

  13. C. Guguschev, A. Dittmar, E. Moukhina, C. Hartmann, S. Golka, J. Wollweber, M. Bickermann, R. Fornari, Growth of bulk AlN single crystals with low oxygen content taking into account thermal and kinetic effects of oxygen-related gaseous species. J. Cryst. Growth 360, 185 (2012)

    Article  Google Scholar 

  14. P. Lu, R. Collazo, R. Dalmau, G. Durkaya, N. Dietz, B. Raghothamachar, M. Dudley, Z. Sitar, Seeded growth of AlN bulk crystals in m- and c-orientation. J. Cryst. Growth 312, 58 (2009)

    Article  Google Scholar 

  15. A. Rice, R. Collazo, J. Tweedie, R. Dalmau, S. Mita, J. Xie, Z. Sitar, Surface preparation and homoepitaxial deposition of AlN on (0001)-oriented AlN substrates by metalorganic chemical vapor deposition. J. Appl. Phys. 108, 043510 (2010)

    Article  Google Scholar 

  16. T. Wunderer, C.L. Chua, J.E. Northrup, Z. Yang, N.M. Johnson, M. Kneissl, G.A. Garrett, H. Shen, M. Wraback, B. Moody, H.S. Craft, R. Schlesser, R.F. Dalmau, Z. Sitar, Optically pumped UV lasers grown on bulk AlN substrates. Phys. Status Solidi (c) 9, 822–825 (2012)

    Article  Google Scholar 

  17. B. Neuschl, K. Thonke, M. Feneberg, R. Goldhahn, T. Wunderer, Z. Yang, N.M. Johnson, J. Xie, S. Mita, A. Rice, R. Collazo, Z. Sitar, Direct determination of the silicon donor ionization energy in homoepitaxial AlN from photoluminescence two-electron transitions. Appl. Phys. Lett. 103, 122105 (2013)

    Article  Google Scholar 

  18. R. Collazo, S. Mita, J. Xie, A. Rice, J. Tweedie, R. Dalmau, Z. Sitar, Progress on n-type doping of AlGaN alloys on AlN single crystal substrates for UV optoelectronic applications. Phys. Status Solidi (c) 8, 2031 (2011)

    Google Scholar 

  19. T. Wunderer, C.L. Chua, Z. Yang, J.E. Northrup, N.M. Johnson, G.A. Garrett, H. Shen, M. Wraback, Pseudomorphically grown ultraviolet-C photopumped lasers on bulk AlN substrates. Appl. Phys. Exp. 4, 092101 (2011)

    Google Scholar 

  20. F. Bernardini, in Nitride Semiconductor Devices: Principles and Simulations, ed. by J. Piprek (Wiley-VCH, Weinheim, 2007), pp. 49–67

    Google Scholar 

  21. M.L. Nakarmi, K.H. Kim, M. Khizar, Z.Y. Fan, J.Y. Lin, X. Jianga, Electrical and optical properties of Mg-doped Al0.7Ga0.3N alloys. Appl. Phys. Lett. 86, 092108 (2005)

    Article  Google Scholar 

  22. B. Cheng, S. Choi, J.E. Northrup, Z. Yang, C. Knollenberg, M. Teepe, T. Wunderer, C.L. Chua, N.M. Johnson, Enhanced vertical and lateral hole transport in high aluminum-containing AlGaN for deep ultraviolet light emitters. Appl. Phys. Lett. 102, 231106 (2013)

    Article  Google Scholar 

  23. R. Goldhahn, M. Feneberg, Private communication

    Google Scholar 

  24. J. Simon, V. Protasenko, C. Lian, H. Xing, D. Jena, Polarization-induced hole doping in wide–band-gap uniaxial semiconductor heterostructures. Science 327, 60–64 (2010)

    Article  Google Scholar 

  25. J. Cho, E.F. Schubert, J.K. Kim, Efficiency droop in light-emitting diodes: Challenges and countermeasures. Laser Photon. Rev. 7, 408 (2013)

    Article  Google Scholar 

  26. C. Verzellesi, D. Saguatti, M. Meneghini, F. Bertazzi, M. Goano, G. Meneghesso, E. Zanoni, Efficiency droop in InGaN/GaN blue light-emitting diodes: Physical mechanisms and remedies. J. Appl. Phys. 114, 071101 (2013)

    Article  Google Scholar 

  27. L. Zhang, K. Ding, J.C. Yan, J.X. Wang, Y.P. Zeng, T.B. Wei, Y.Y. Li, B.J. Sun, R.F. Duan, J.M. Li, Three-dimensional hole gas induced by polarization in (0001)-oriented metal-face III-nitride structure. Appl. Phys. Lett. 97, 062103 (2010)

    Article  Google Scholar 

  28. T. Takano, Y. Narita, A. Horiuchi, H. Kawanishi, Room-temperature deep-ultraviolet lasing at 241.5 nm of AlGaN multiple-quantum-well laser. Appl. Phys. Lett. 84, 3567 (2004)

    Article  Google Scholar 

  29. M. Martens, F. Mehnke, C. Kuhn, C. Reich, V. Kueller, A. Knauer, C. Netzel, C. Hartmann, J. Wollweber, J. Rass, T. Wernicke, M. Bickermann, M. Weyers, M. Kneissl, Performance characteristics of UV-C AlGaN-based lasers grown on sapphire and bulk AlN substrates. IEEE Photon. Tech. Lett. 26, 342 (2014)

    Article  Google Scholar 

  30. Z. Lochner, T.-T. Kao, Y.-S. Liu, X.-H. Li, M. Satter, S.-C. Shen, P.D. Yoder, J.-H. Ryou, R.D. Dupuis, Y. Wei, H. Xie, A. Fischer, F.A. Ponce, Deep-ultraviolet lasing at 243 nm from photopumped AlGaN/AlN heterostructure on AlN substrate. Appl. Phys. Lett. 102, 101110 (2013)

    Article  Google Scholar 

  31. J. Xie, S. Mita, Z. Bryan, W. Guo, L. Hussey, B. Moody, R. Schlesser, R. Kirste, M. Gerhold, R. Collazo, Z. Sitar, Lasing and longitudinal cavity modes in photo-pumped deep ultraviolet AlGaN heterostructures. Appl. Phys. Lett. 102, 171102 (2013)

    Article  Google Scholar 

  32. M. Martens, F. Mehnke, C. Kuhn, C. Reich, T. Wernicke, J. Rass, V. Küller, A. Knauer, C. Netzel, M. Weyers, M. Bickermann, M. Kneissl, Performance characteristics of UV-C AlGaN-based lasers grown on sapphire and bulk AlN substrates. IEEE Photon. Tech. Lett. 26, 342 (2014)

    Article  Google Scholar 

  33. J.E. Northrup, C.L. Chua, Z. Yang, T. Wunderer, M. Kneissl, N.M. Johnson, T. Kolbe, Effect of strain and barrier composition on the polarization of light emission from AlGaN/AlN quantum wells. Appl. Phys. Lett. 100, 021101 (2012)

    Article  Google Scholar 

  34. T. Kolbe, A. Knauer, C. Chua, Z. Yang, S. Einfeldt, P. Vogt, N.M. Johnson, M. Weyers, M. Kneissl, Optical polarization characteristics of ultraviolet (In)(Al)GaN multiple quantum well light emitting diodes. Appl. Phys. Lett. 97, 171105 (2010)

    Google Scholar 

  35. K.B. Nam, J. Li, M.L. Nakarmi, J.Y. Lin, H.X. Jiang, Unique optical properties of AlGaN alloys and related ultraviolet emitters. Appl. Phys. Lett. 84, 5264 (2004)

    Google Scholar 

  36. D.S. Sizov, R. Bhat, A. Heberle, K. Song, C. Zah, Internal optical waveguide loss and p-type absorption in blue and green InGaN quantum well laser diodes. Appl. Phys. Express 3, 122104 (2010)

    Article  Google Scholar 

  37. V.I. Kozlovsky, A.B. Krysa, Y.K. Skyasyrsky, Y.M. Popov, A. Abare, M.P. Mack, S. Keller, U. K. Mishra, L. Coldren, Steven DenBaars, Michael D. Tiberi, T. George, Electron beam pumped MQW InGaN/GaN laser. MRS Internet J. Nitride Semicond. Res. 2, 38 (1997)

    Google Scholar 

  38. M. Tiberi, V. Kozlovsky, P. Kuznetsov, Electron beam pumped lasers based on II–VI compound nanostructures from the visible to UVA. Phys. Status Solidi (B) 247, 1547 (2010)

    Google Scholar 

  39. T. Oto, R.G. Banal, K Kataoka, M. Funato, 100 mW deep-ultraviolet emission from aluminium-nitride-based quantum wells pumped by an electron beam. Nat. Photon. 4, 767 (2010)

    Google Scholar 

  40. O.G. Okhotnikov, Semiconductor Disk Laser (Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim, 2010)

    Book  Google Scholar 

  41. S.-H. Park, J. Kim, H. Jeon, T. Sakong, S.-N. Lee, S. Chae, Y. Park, C.-H. Jeong, G.-Y. Yeom, Y.-H. Cho, Room-temperature GaN vertical-cavity surface-emitting laser operation in an extended cavity scheme. Appl. Phys. Lett. 83, 2121 (2003)

    Article  Google Scholar 

  42. R. Debusmann, N. Dhidah, V. Hoffmann, L. Weixelbaum, U. Brauch, T. Graf, M. Weyers, M. Kneissl, InGaN-GaN disk laser for blue-violet emission wavelengths. IEEE Photon. Technol. Lett. 22, 652 (2010)

    Article  Google Scholar 

  43. T. Wunderer, J.E. Northrup, Z. Yang, M. Teepe, A. Strittmatter, N.M. Johnson, P. Rotella, M. Wraback, In-well pumping of InGaN/GaN vertical-external-cavity surface-emitting lasers. Appl. Phys. Lett. 99, 201109 (2011)

    Article  Google Scholar 

  44. X. Zeng, D.L. Boïko, G. Cosendey, M. Glauser, J.-F. Carlin, N. Grandjean, Optically pumped long external cavity InGaN/GaN surface-emitting laser with injection seeding from a planar microcavity. Appl. Phys. Lett. 101, 141120 (2012)

    Article  Google Scholar 

Download references

Acknowledgment

We would like to thank Dr. Chris Chua, Zhihong Yang, Mark Teepe, Clifford Knollenberg, Dr. Bowen Cheng, and Dr. Suk Choi from PARC for their crucial support throughout the project. Special thanks are expressed to Dr. Gregory A. Garrett and Dr. Michael Wraback from the Army Research Laboratory, Adelphi, MD, USA, Dr. Martin Feneberg and Prof. Rüdiger Goldhahn from the OvG University Magdeburg, Germany, and Dr. Benjamin Neuschl and Prof. Klaus Thonke from the University of Ulm, Germany. We are pleased to acknowledge financial support from the Defense Advanced Research Projects Agency (DARPA) and the Defense Threat Reduction Agency (DTRA) under U.S. Army Cooperative Agreement no. W911NF-10-02-0102 and W911NF-10-2-0008.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Thomas Wunderer .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Wunderer, T., Northrup, J.E., Johnson, N.M. (2016). AlGaN-Based Ultraviolet Laser Diodes. In: Kneissl, M., Rass, J. (eds) III-Nitride Ultraviolet Emitters. Springer Series in Materials Science, vol 227. Springer, Cham. https://doi.org/10.1007/978-3-319-24100-5_8

Download citation

Publish with us

Policies and ethics