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Advancements in Eco-friendly Lubricants for Tribological Applications: Past, Present, and Future

  • Carlton J. Reeves
  • Pradeep L. Menezes
Chapter
Part of the Materials Forming, Machining and Tribology book series (MFMT)

Abstract

This chapter highlights the evolution of eco-friendly lubricants derived from natural oils and fats to green lamellar solid additives to a new class of “greener” functional fluids known as room temperature ionic liquids (RTILs). The attraction to these bio-based lubricants began with vegetable oils due to their low friction and wear properties. These superior tribological characteristics are a result of their chemical composition of triacylglycerol molecules made up of esters derived from glycerol and long chains of polar fatty acids. It is these fatty acids within the natural oils that establish monolayers that enable high lubricity in boundary-lubricated regimes. Despite these accolades, vegetable oils suffer from thermal-oxidative instability, high pour points, and inconsistent chemical compositions. To improve upon the tribological properties, vegetable oils were subjected to additives such as lamellar solid powders to establish more resilient transfer layers to mitigate wear and surface damage. Currently, RTIL lubricants derived from bio-based feedstock represent a promising potential solution to many of the problems associated with previous eco-friendly lubricants. An investigation into RTILs begins with a discussion on the history of ionic liquids and an assessment on their tribological properties. The chapter also includes a case study on the use of RTILs as additives in vegetable oils and as neat lubricants as well as exploring the effects of cation-anion moiety exchange within ionic liquids themselves. Ultimately, the RTILs are compared to more traditional bio-based lubricants for their tribological performance as a new class of eco-friendly lubricants and their potential as a future lubrication technology.

Keywords

Ionic Liquid Base Fluid Room Temperature Ionic Liquid Lubricant Mixture Superior Tribological Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Bannister KE (1996) Lubrication for industry. Industrial Press, New YorkGoogle Scholar
  2. 2.
    Mang T, Dresel W (2006) Lubricants and lubrication. Wiley, WeinheimCrossRefGoogle Scholar
  3. 3.
    United States (1997) Central intelligence A. Central Intelligence Agency, The CIA world fact book. Washington DCGoogle Scholar
  4. 4.
    Reeves C, Menezes PL, Lovell M, Jen T-C (2013) Macroscale applications in tribology. In: Menezes PL, Nosonovsky M, Ingole SP, Kailas SV, Lovell MR (eds) Tribology for scientists and engineers. Springer, New York, pp 881–919Google Scholar
  5. 5.
    Reeves C, Menezes PL, Lovell M, Jen T-C (2013) Microscale applications in tribology. In: Menezes PL, Nosonovsky M, Ingole SP, Kailas SV, Lovell MR (eds) Tribology for scientists and engineers. Springer, New York, pp 921–948Google Scholar
  6. 6.
    Menezes PL, Reeves C, Kailas S, Lovell M (2013) Tribology in metal forming. In: Menezes PL, Nosonovsky M, Ingole SP, Kailas SV, Lovell MR (eds) Tribology for scientists and engineers. Springer, New York, pp 783–818Google Scholar
  7. 7.
    Bartz WJ (2006) Automotive and industrial lubrication 15th International Colloquium Tribology. TAE, OstfildernGoogle Scholar
  8. 8.
    Lingg G, Gosalia A (2008) The dynamics of the global lubricants industry: markets, competitors and trends. In: Technische Akademie Esslingen international tribology colloquium proceedings, p 16Google Scholar
  9. 9.
    Reeves CJ, Menezes PL, Jen T-C, Lovell MR (2012) Evaluating the tribological performance of green liquid lubricants and powder additive based green liquid lubricants. STLE annual meeting and exhibition. STLE, St. LouisGoogle Scholar
  10. 10.
    Menezes PL, Reeves C, Lovell M (2013) Fundamentals of Lubrication. In: Menezes PL, Nosonovsky M, Ingole SP, Kailas SV, Lovell MR (eds) Tribology for scientists and engineers. Springer, New York, pp 295–340Google Scholar
  11. 11.
    Lundgren SM, Persson K, Mueller G, Kronberg B, Clarke J, Chtaib M et al (2007) Unsaturated fatty acids in alkane solution: adsorption to steel surfaces. Langmuir ACS J Surf Colloids 23:10598–10602Google Scholar
  12. 12.
    Lovell MR, Menezes PL, Kabir MA, Higgs CF III (2010) Influence of boric acid additive size on green lubricant performance. Philos Trans R Soc A Math Phys Eng Sci 368:4851–4868CrossRefGoogle Scholar
  13. 13.
    Lundgren SM, Ruths M, Danerlov K, Persson K (2008) Effects of unsaturation on film structure and friction of fatty acids in a model base oil. J Colloid Interf Sci 326:530–536CrossRefGoogle Scholar
  14. 14.
    Schneider MP (2006) Plant-oil-based lubricants and hydraulic fluids. J Sci Food Agric 86:1769–1780CrossRefGoogle Scholar
  15. 15.
    Deffeyes KS (2009) Hubbert’s peak. Princeton (N.J.). Princeton University Press, OxfordGoogle Scholar
  16. 16.
    Goodstein DL (2004) Out of gas: the end of the age of oil, 1st edn. W.W. Norton, New YorkGoogle Scholar
  17. 17.
    Menezes PL, Lovell MR, Kabir MA, Higgs III CF, Rohatgi PK (2012) Green lubricants: role of additive size. In: Nosonovsky M, Bhushan B (eds) Green tribology. Springer, Berlin, pp 265–286Google Scholar
  18. 18.
    Bennion M, Scheule B (2010) Introductory foods. Prentice Hall, Upper Saddle RiverGoogle Scholar
  19. 19.
    Duzcukoglu H, Sahin O (2011) Investigation of wear performance of canola oil containing boric acid under boundary friction condition. Tribol Trans 54:57–61CrossRefGoogle Scholar
  20. 20.
    Erdemir A (1990) Tribological properties of boric acid and boric acid forming surfaces: part 1, crystal chemistry and self-lubricating mechanism of boric acid. In: Society of tribologists lubrication engineers annual conference. Argonne National Labs, DenverGoogle Scholar
  21. 21.
    Lovell M, Higgs CF, Deshmukh P, Mobley A (2006) Increasing formability in sheet metal stamping operations using environmentally friendly lubricants. J Mater Process Technol 177:87CrossRefGoogle Scholar
  22. 22.
    Kumar A, Sharma S (2008) An evaluation of multipurpose oil seed crop for industrial uses (Jatropha curcas L.): a review. Ind Crops Prod 28:1–10CrossRefGoogle Scholar
  23. 23.
    Reeves CJ, Menezes PL, Lovell MR, Jen T-C (2015) Science and technology of environmentally friendly lubricants. Environmentally friendly and biobased lubricants. CRC Press, Boca RatonGoogle Scholar
  24. 24.
    Grushcow J (2005) High oleic plant oils with hydroxy fatty acids for emission reduction. In: World tribology congress III. American Society of Mechanical Engineers, Washington, DC, pp 485–486Google Scholar
  25. 25.
    Reeves CJ, Menezes PL, Jen T-C, Lovell MR (2015) The influence of fatty acids on tribological and thermal properties of natural oils as sustainable biolubricants. Tribol Int 90:123–134CrossRefGoogle Scholar
  26. 26.
    Fox NJ, Tyrer B, Stachowiak GW (2004) Boundary lubrication performance of free fatty acids in sunflower oil. Tribol Lett 16:275–281CrossRefGoogle Scholar
  27. 27.
    Grushcow J, Smith MA (2005) Next generation feedstocks from new frontiers in oilseed engineering. ASME Conf Proc 2005:487–488Google Scholar
  28. 28.
    Reeves CJ, Menezes PL, Lovell MR, Jen T-C (2013) The size effect of boron nitride particles on the tribological performance of biolubricants for energy conservation and sustainability. Tribol Lett 51:437–452CrossRefGoogle Scholar
  29. 29.
    Reeves C, Menezes PL, Lovell M, Jen T-C (2013) Tribology of solid lubricants. In: Menezes PL, Nosonovsky M, Ingole SP, Kailas SV, Lovell MR (eds) Tribology for scientists and engineers. Springer, New York, pp 447–494Google Scholar
  30. 30.
    Liang H, Jahanmir S (1995) Boric acid as an additive for core-drilling of alumina. J Tribol Journal of Tribology. 1995;117Google Scholar
  31. 31.
    Reeves CJ, Jen TC, Menezes PL, Lovell MR (2015) The influence of surface roughness and particulate size on the tribological performance of bio-based multi-functional hybrid lubricants. Tribol Int Tribol Int 88:40–55CrossRefGoogle Scholar
  32. 32.
    Reeves CJ, Menezes PL, Jen T-C, Lovell MR (2013) The effect of surface roughness on the tribological performance of environmentally friendly bio-based lubricants with varying particle size. In: STLE annual meeting and exhibition. STLE, DetroitGoogle Scholar
  33. 33.
    Li Y, Pang A, Wang C, Wei M (2011) Metal organic frameworks: promising materials for improving the open circuit voltage of dye-sensitized solar cells. J Mater Chem 21:17259–17264CrossRefGoogle Scholar
  34. 34.
    Passerini S, Alessandrini F, Appetecchi GB, Conte M (2006) Ionic liquid based electrolytes for high energy electrochemical storage devices. ECS Trans 1:67–71CrossRefGoogle Scholar
  35. 35.
    Liu W, Ye C, Gong Q, Wang H, Wang P (2002) Tribological performance of room-temperature ionic liquids as lubricant. Tribol Lett 13:81–85CrossRefGoogle Scholar
  36. 36.
    Garvey SL, Hawkins CA, Dietz ML (2012) Effect of aqueous phase anion on the mode of facilitated ion transfer into room-temperature ionic liquids. Talanta 95:25–30CrossRefGoogle Scholar
  37. 37.
    Hawkins CA, Garvey SL, Dietz ML (2012) Structural variations in room-temperature ionic liquids: influence on metal ion partitioning modes and extraction selectivity. SEPPUR Sep Purif Technol 89:31–38CrossRefGoogle Scholar
  38. 38.
    Zaijun L, Jie C, Haixia S, Jiaomai P (2007) Advance of room temperature ionic liquid as solvent for extraction and separation. Rev Anal Chem 26:109–153Google Scholar
  39. 39.
    Liu X, Zhou F, Liang Y, Liu W (2006) Tribological performance of phosphonium based ionic liquids for an aluminum-on-steel system and opinions on lubrication mechanism. Wear 261:1174–1179CrossRefGoogle Scholar
  40. 40.
    Smith PG (1961) High-temperature molten-salt lubricated hydrodynamic. J Bear ASLE Trans 4:263–274CrossRefGoogle Scholar
  41. 41.
    Ye C, Liu W, Chen Y, Yu L (2001) Room-temperature ionic liquids: a novel versatile lubricant. Chem Commun 2001:2244–2245CrossRefGoogle Scholar
  42. 42.
    Zhou F, Liang Y, Liu W (2009) Ionic liquid lubricants: designed chemistry for engineering applications. Chem Soc Rev 38:2590–2599CrossRefGoogle Scholar
  43. 43.
    Yao M, Liang Y, Xia Y, Zhou F (2009) Bisimidazolium ionic liquids as the high-performance antiwear additives in poly(ethylene glycol) for steel-steel contacts. ACS Appl Mater Interf ACS Appl Mater Interf 1:467–471CrossRefGoogle Scholar
  44. 44.
    Phillips BS, Zabinski JS (2004) Ionic liquid lubrication effects on ceramics in a water environment. Tribol Lett 17:533–541CrossRefGoogle Scholar
  45. 45.
    Wang H, Lu Q, Ye C, Liu W, Cui Z (2004) Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact. Wear 256:44–48CrossRefGoogle Scholar
  46. 46.
    Liu W, Ye C, Chen Y, Ou Z, Sun DC (2002) Tribological behavior of sialon ceramics sliding against steel lubricated by fluorine-containing oils. Tribol Int 35:503–509CrossRefGoogle Scholar
  47. 47.
    Mu Z, Liu W, Zhang S, Zhou F (2004) Functional room-temperature ionic liquids as lubricants for an aluminum-on-steel system. Chem Lett 33:524–525CrossRefGoogle Scholar
  48. 48.
    Lu Q, Wang H, Ye C, Liu W, Xue Q (2004) Room temperature ionic liquid 1-ethyl-3-hexylimidazolium-bis(trifluoromethylsulfonyl)-imide as lubricant for steelsteel contact. Tribol Int 37:547–552Google Scholar
  49. 49.
    Reich RA, Stewart PA, Bohaychick J, Urbanski JA (2003) Base oil properties of ionic liquids. Lubr Eng 59:16–21Google Scholar
  50. 50.
    Mu Z, Zhou F, Zhang S, Liang Y, Liu W (2005) Effect of the functional groups in ionic liquid molecules on the friction and wear behavior of aluminum alloy in lubricated aluminum-on-steel contact. Tribol Int 38:725–731CrossRefGoogle Scholar
  51. 51.
    Jimenez AE, Bermudez MD, Iglesias P, Carrion FJ, Martinez-Nicolas G (2006) 1-N-alkyl -3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel-aluminium contacts. Wear 260:766–782CrossRefGoogle Scholar
  52. 52.
    Jimenez AE, Bermudez MD, Carrion FJ, Martinez-Nicolas G (2006) Room temperature ionic liquids as lubricant additives in steel-aluminium contacts: Influence of sliding velocity, normal load and temperature. Wear 261:347–359CrossRefGoogle Scholar
  53. 53.
    Omotowa BA, Phillips BS, Zabinski JS, Shreeve JM (2004) Phosphazene-based ionic liquids: synthesis, temperature-dependent viscosity, and effect as additives in water lubrication of silicon nitride ceramics. Inorg Chem 43:5466–5471CrossRefGoogle Scholar
  54. 54.
    Yu G, Zhou F, Liu W, Liang Y, Yan S (2006) Preparation of functional ionic liquids and tribological investigation of their ultra-thin films. Wear 260:1076–1080CrossRefGoogle Scholar
  55. 55.
    Yu B, Zhou F, Mu Z, Liang Y, Liu W (2006) Tribological properties of ultra-thin ionic liquid films on single-crystal silicon wafers with functionalized surfaces. Tribol Int 39:879–887CrossRefGoogle Scholar
  56. 56.
    Xia Y, Wang S, Zhou F, Wang H, Lin Y, Xu T (2006) Tribological properties of plasma nitrided stainless steel against SAE52100 steel under ionic liquid lubrication condition. Tribol Int 39:635–640CrossRefGoogle Scholar
  57. 57.
    Qu J, Bansal DG, Yu B, Howe JY, Luo H, Dai S et al (2012) Antiwear performance and mechanism of an oil-miscible ionic liquid as a lubricant additive. ACS Appl Mater Interf 4:997–1002CrossRefGoogle Scholar
  58. 58.
    Reeves CJ, Menezes PL, Garvey SL, Jen TC, Dietz ML, Lovell MR (2013) The effect of anion-cation moiety manipulation to characterize the tribological performance of environmentally benign room temperature ionic liquid lubricants. In: STLE annual meeting and exhibition (STLE2013). Society of Tribologists and Lubrication Engineers, DetroitGoogle Scholar
  59. 59.
    Mo Y, Zhao W, Zhu M, Bai M (2008) Nano/Microtribological properties of ultrathin functionalized imidazolium wear-resistant ionic liquid films on single crystal silicon. Tribol Lett 32:143–151CrossRefGoogle Scholar
  60. 60.
    Zhu M, Yan J, Mo Y, Bai M (2008) Effect of the anion on the tribological properties of ionic liquid nano-films on surface-modified silicon wafers. Tribol Lett 29:177–183CrossRefGoogle Scholar
  61. 61.
    Palacio M, Bhushan B (2008) Ultrathin wear-resistant ionic liquid films for novel MEMS/NEMS applications. Adv Mater 20:1194–1198CrossRefGoogle Scholar
  62. 62.
    Bhushan B, Palacio M, Kinzig B (2008) AFM-based nanotribological and electrical characterization of ultrathin wear-resistant ionic liquid films. J Colloid Interf Sci 317:275–287CrossRefGoogle Scholar
  63. 63.
    Palacio M, Bhushan B (2008) Nanotribological and nanomechanical properties of lubricated PZT thin films for ferroelectric data storage applications. J Vac Sci Technol A Vac Surf Films 26:768–776CrossRefGoogle Scholar
  64. 64.
    Minami I, Inada T, Sasaki R, Nanao H (2010) Tribo-chemistry of phosphonium-derived ionic liquids. Tribol Lett 40:225–235CrossRefGoogle Scholar
  65. 65.
    Zeng Z, Shreeve JM, Phillips BS, Xiao JC (2008) Polyfluoroalkyl, polyethylene glycol, 1,4-bismethylenebenzene, or 1,4-bismethylene-2,3,5,6-tetrafluorobenzene bridged functionalized dicationic ionic liquids: synthesis and properties as high temperature lubricants. Chem Mater 20:2719–2726CrossRefGoogle Scholar
  66. 66.
    Shah F, Glavatskih S, Antzutkin ON (2009) Synthesis, physicochemical, and tribological characterization of S-Di-n-octoxyboron-O, O’-di-n-octyldithiophosphate. ACS Appl Mater Interf 1:2835–2842CrossRefGoogle Scholar
  67. 67.
    Mosey NJ (2005) Molecular mechanisms for the functionality of lubricant additives. Science 307:1612–1615CrossRefGoogle Scholar
  68. 68.
    Mangolini F, Rossi A, Spencer ND (2011) Chemical reactivity of triphenyl phosphorothionate (TPPT) with iron: an ATR/FT-IR and XPS investigation. J Phys Chem C 115:1339–1354CrossRefGoogle Scholar
  69. 69.
    Shah F, Glavatskih S, Höglund E, Lindberg M, Antzutkin ON (2011) Interfacial antiwear and physicochemical properties of alkylborate-dithiophosphates. ACS Appl Mater Interf 3:956–968CrossRefGoogle Scholar
  70. 70.
    Minami I (2009) Ionic liquids in tribology. Molecules (Basel, Switzerland 14:2286–2305Google Scholar
  71. 71.
    Itoh T, Ishioka A, Hayase S, Kawatsura M, Watanabe N, Inada K et al (2009) Design of alkyl sulfate ionic liquids for lubricants. Chem Lett 38:64–65CrossRefGoogle Scholar
  72. 72.
    Ohtani H, Ishimura S, Kumai M (2008) Thermal decomposition behaviors of imidazolium-type ionic liquids studied by pyrolysis-gas chromatography. Anal Sci Int J Jpn Soc Anal Chem 24:1335–1340CrossRefGoogle Scholar
  73. 73.
    Jimâenez A-E, Bermâudez M-D (2007) Ionic liquids as lubricants for steel-aluminum contacts at low and elevated temperatures. Tribol Lett 26:53–60CrossRefGoogle Scholar
  74. 74.
    Shah FU, Glavatskih S, MacFarlane DR, Somers A, Forsyth M, Antzutkin ON (2011) Novel halogen-free chelated orthoborate-phosphonium ionic liquids: synthesis and tribophysical properties. Chem Phys (Incorporating Faraday Transactions) 13:12865–12873Google Scholar
  75. 75.
    Sun J, Howlett PC, MacFarlane DR, Lin J, Forsyth M (2008) Synthesis and physical property characterisation of phosphonium ionic liquids based on P(O)2(OR)2 and P(O)2(R)2 anions with potential application for corrosion mitigation of magnesium alloys. Electrochim Acta 54:254–260CrossRefGoogle Scholar
  76. 76.
    Weng L, Liu X, Liang Y, Xue Q (2007) Effect of tetraalkylphosphonium based ionic liquids as lubricants on the tribological performance of a steel-on-steel system. Tribol Lett 26:11–17CrossRefGoogle Scholar
  77. 77.
    Minami I, Kamimura H, Mori S (2007) Thermo-oxidative stability of ionic liquids as lubricating fluids. J Synth Lubr 24:135–147CrossRefGoogle Scholar
  78. 78.
    Kamimura H, Kubo T, Minami I, Mori S (2007) Effect and mechanism of additives for ionic liquids as new lubricants. Tribol Int 40:620–625CrossRefGoogle Scholar
  79. 79.
    Zhao W, Mo Y, Pu J, Bai M (2009) Effect of cation on micro/nano-tribological properties of ultra-thin ionic liquid films. Tribol Int 42:828–835CrossRefGoogle Scholar
  80. 80.
    Reeves CJ, Menezes PL, Lovell MR, Jen TC, Garvey SL, Dietz ML (2013) The tribological performance of bio-based room temperature ionic liquid lubricants: a possible next step in biolubricant technology. World tribology congress—5th. Society of Tribologists and Lubrication Engineers, TorinoGoogle Scholar
  81. 81.
    Reeves CJ, Garvey SL, Menezes PL, Dietz ML, Jen TC, Lovell MR (2012) Tribological performance of environmentally friendly ionic liquid lubricants. In: ASME/STLE 2012 international joint tribology conference. STLE, DenverGoogle Scholar
  82. 82.
    Reeves CJ, Menezes PL, Lovell MR, Jen TC (2014) The effect of particulate additives on the tribological performance of bio-based and ionic liquid-based lubricants for energy conservation and sustainability. In: STLE (ed) STLE annual meeting and exhibition. STLE, Buena VistaGoogle Scholar
  83. 83.
    Freemantle M (2010) An Introduction to ionic liquids. RSC Pub, CambridgeGoogle Scholar
  84. 84.
    Matlack A (2010) Introduction to green chemistry. Taylor & Francis GroupGoogle Scholar
  85. 85.
    Manahan SE (1994) Environmental chemistry. Lewis, Boca RatonGoogle Scholar
  86. 86.
    Suisse J-M, Bellemin-Laponnaz S, Douce L, Maisse-François AWR (2005) A new liquid crystal compound based on an ionic imidazolium salt. Tetrahedron Lett 46:4303–4305CrossRefGoogle Scholar
  87. 87.
    Yao Y, Wang X, Guo J, Yang X, Xu B (2008) Tribological property of onion-like fullerenes as lubricant additive. Mater Lett 62:2524–2527CrossRefGoogle Scholar
  88. 88.
    Xia Y, Sasaki S, Murakami T, Nakano M, Shi L, Wang H (2007) Ionic liquid lubrication of electrodeposited nickel-Si3N4 composite coatings. Wear 262:765CrossRefGoogle Scholar
  89. 89.
    Battez HA, Alonso DB, Rodriguez RG, Viesca Rodriguez JL, Fernandez-Gonzalez A, Garrido AH (2011) Lubrication of DLC and tin coatings with two ionic liquids used as neat lubricant and oil additives. In: Proceedings of the STLE/ASME international joint tribology conference. American Society of Mechanical Engineers, Los AngelesGoogle Scholar
  90. 90.
    Bermúdez MD, Jiménez AE, Sanes J, Carrión FJ (2009) Ionic liquids as advanced lubricant fluids. Molecules 14:2888–2908CrossRefGoogle Scholar
  91. 91.
    Xue H, Tong ZF, Wei FY, Qing SG (2008) Crystal structure of room-temperature ionic liquid 1-butyl-isoquinolinium gallium tetrachloride [(BIQL)GaCl4]. Chem Rec 11:90–94Google Scholar
  92. 92.
    Canter N (2005) Evaluating ionic liquids as potential lubricants. Tribol Lubr Technol 61:15–17Google Scholar
  93. 93.
    Sheldon RA, Arends I, Hanefeld U (2007) Green chemistry and catalysis. Wiley, WeinheimGoogle Scholar
  94. 94.
    Wang H, Malhotra SV, Francis AJ (2011) Toxicity of various anions associated with methoxyethyl methyl imidazolium-based ionic liquids on Clostridium sp. Chemosphere 82:1597–1603CrossRefGoogle Scholar
  95. 95.
    Atefi F, Garcia MT, Singer RD, Scammells PJ (2009) Phosphonium ionic liquids: design, synthesis and evaluation of biodegradability. Green Chem 11:1595–1604CrossRefGoogle Scholar
  96. 96.
    Handy ST (2003) Greener solvents: room temperature ionic liquids from biorenewable sources. Eur J Chem 9:2938–2944CrossRefGoogle Scholar
  97. 97.
    Gathergood N, Scammells PJ, Garcia TM (2006) Biodegradable ionic liquids part III. The first readily biodegradable ionic liquids. Green Chem 8:156–160CrossRefGoogle Scholar
  98. 98.
    Gathergood N, Garcia TM, Scammells PJ (2004) Biodegradable ionic liquids: part I. Concept, preliminary targets and evaluation. Green Chem 6:166–175CrossRefGoogle Scholar
  99. 99.
    Corma A, Iborra S, Velty A (2007) Chemical routes for the transformation of biomass into chemicals. Chem Inform 38Google Scholar
  100. 100.
    Zhang ZC (2013) Catalytic transformation of carbohydrates and lignin in ionic liquids. WENE Wiley interdisciplinary reviews: energy and environmentGoogle Scholar
  101. 101.
    Reeves CJ, Jen T-C, Garvey SL, Dietz ML, Menezes PL, Lovell MR (2014) The effect of phosphonium-and imidazolium-based ionic liquids as additives in natural oil: an investigation of tribological performanceGoogle Scholar

Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  1. 1.Department of Mechanical EngineeringUniversity of Wisconsin-MilwaukeeMilwaukeeUSA
  2. 2.Department of Mechanical EngineeringUniversity of Nevada-RenoRenoUSA

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