Liquid-Liquid Mass Transfer Using Ionic Liquids

  • Dimitrios A. TsaoulidisEmail author
Part of the Springer Theses book series (Springer Theses)


In this chapter the mass transfer during liquid-liquid plug flow in small channels is presented. The extraction of dioxouranium(VI) ions from nitric acid solutions into TBP/IL mixtures (Table  3.2), relevant to spent nuclear fuel reprocessing was investigated.


Ionic Liquid Extraction Efficiency Mass Transfer Coefficient Plug Flow Nitric Acid Solution 
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  1. Billard, I., Ouadi, A., Jobin, E., Champion, J., Gaillard, C., & Georg, S. (2011a). Understanding the extraction mechanism in ionic liquids: UO2 2+/HNO3/TBP/C4-mimTf2N as a case study. Solvent Extraction and Ion Exchange, 29, 577–601.CrossRefGoogle Scholar
  2. Billard, I., Ouadi, A., & Gaillard, C. (2011b). Liquid–liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: From discovery to understanding. Analytical and Bioanalytical Chemistry, 400, 1555–1566.CrossRefGoogle Scholar
  3. Cervera-Padrell, A. E., Morthensen, S. T., Lewandowski, D. J., Skovby, T., Kiil, S., & Gernaey, K. V. (2012). Continuous hydrolysis and liquid-liquid phase separation of an active pharmaceutical ingredient intermediate using a miniscale hydrophobic membrane separator. Organic Process Research & Development, 16, 888–900.CrossRefGoogle Scholar
  4. Dessimoz, A.-L., Cavin, L., Renken, A., & Kiwi-Minsker, L. (2008). Liquid–liquid two-phase flow patterns and mass transfer characteristics in rectangular glass microreactors. Chemical Engineering Science, 63, 4035–4044.CrossRefGoogle Scholar
  5. Dietz, M. L., & Stepinski, D. C. (2008). Anion concentration-dependent partitioning mechanism in the extraction of uranium into room-temperature ionic liquids. Talanta, 75, 598–603.CrossRefGoogle Scholar
  6. Di Miceli Raimondi, N., Prat, L., Gourdon, C. & Cognet, P. (2008). Direct numerical simulations of mass transfer in square microchannels for liquid–liquid slug flow. Chemical Engineering Science, 63, 5522–5530.Google Scholar
  7. Fernandes, J., & Sharma, M. (1967). Effective interfacial area in agitated liquid—liquid contactors. Chemical Engineering Science, 22, 1267–1282.CrossRefGoogle Scholar
  8. Ghaini, A., Kashid, M., & Agar, D. (2010). Effective interfacial area for mass transfer in the liquid–liquid slug flow capillary microreactors. Chemical Engineering and Processing: Process Intensification, 49, 358–366.CrossRefGoogle Scholar
  9. Giridhar, P., Venkatesan, K., Subramaniam, S., Srinivasan, T. & Vasudeva Rao, P. (2008). Extraction of uranium (VI) by 1.1 M tri-n-butylphosphate/ionic liquid and the feasibility of recovery by direct electrodeposition from organic phase. Journal of Alloys and Compounds, 448, 104-108.Google Scholar
  10. Kashid, M., Gupta, A., Renken, A., & Kiwi-Minsker, L. (2010). Numbering-up and mass transfer studies of liquid–liquid two-phase microstructured reactors. Chemical Engineering Journal, 158, 233–240.CrossRefGoogle Scholar
  11. Kashid, M. N., Renken, A., & Kiwi-Minsker, L. (2011). Gas–liquid and liquid–liquid mass transfer in microstructured reactors. Chemical Engineering Science, 66, 3876–3897.CrossRefGoogle Scholar
  12. Nash, K. L. & Lumetta, G. J. (2011). Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment. Amsterdam: Elsevier.Google Scholar
  13. Tan, J., Lu, Y., Xu, J., & Luo, G. (2012). Mass transfer characteristic in the formation stage of gas–liquid segmented flow in microchannel. Chemical Engineering Journal, 185, 314–320.CrossRefGoogle Scholar
  14. Visser, A. E., & Rogers, R. D. (2003). Room-temperature ionic liquids: New solvents for f-element separations and associated solution chemistry. Journal of Solid State Chemistry, 171, 109–113.CrossRefGoogle Scholar
  15. Wang, J. S., Sheaff, C. N., Yoon, B., Addleman, R. S., & Wai, C. M. (2009). Extraction of uranium from aqueous solutions by using ionic liquid and supercritical carbon dioxide in conjunction. Chemistry-A European Journal, 15, 4458–4463.CrossRefGoogle Scholar
  16. Verma, R., & Sharma, M. (1975). Mass transfer in packed liquid—liquid extraction columns. Chemical Engineering Science, 30, 279–292.CrossRefGoogle Scholar

Copyright information

© Springer International Publishing Switzerland 2015

Authors and Affiliations

  1. 1.Chemical Engineering DepartmentUniversity College LondonLondonUK

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