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Non-equilibrium Phenomena in Confined Soft Matter pp 245–263Cite as

Dynamics of Confined Glass-Forming Liquids Near Equilibrium Conditions

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Part of the book series: Soft and Biological Matter ((SOBIMA))

Abstract

The influence of nanopore confinement on the glass transition and dynamics of glass-forming liquids is reviewed. Recent calorimetric measurements are discussed for small molecules, oligomers, and polymers confined to pores, including those having specific interactions with the pores walls, and results are placed in the context of previous work. The ability to extract information on the dynamics of nanopore-confined chains from changes in the polymerization kinetics and thermodynamics is also discussed. Of particular interest are changes in the dynamics for glass-forming liquids in nanconfined but near-equilibrium conformations.

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Acknowledgments

Funding from the National Science Foundation NSF DMR-1006972 is gratefully acknowledged.

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  1. Department of Chemical Engineering, Texas Tech University, Lubbock, TX, 79409-3121, USA

    Sindee L. Simon

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  1. Polymer and Soft Matter Dynamics, Faculté des Sciences, Université Libre de Bruxelles (ULB), Brussels, Belgium

    Simone Napolitano

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Simon, S.L. (2015). Dynamics of Confined Glass-Forming Liquids Near Equilibrium Conditions. In: Napolitano, S. (eds) Non-equilibrium Phenomena in Confined Soft Matter. Soft and Biological Matter. Springer, Cham. https://doi.org/10.1007/978-3-319-21948-6_11

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