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Fluoro-polyanionic Compounds

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Book cover Lithium Batteries

Abstract

In this chapter, we present the progress that allows several lithium-intercalation compounds to become the active cathode element of a new generation of Li-ion batteries, namely the materials with a poly-anion-based structure M x (XO4) y (M is a transition-metal cation and X = P, S), which are promising to improve the technology of energy storage and electric transportation, and address the replacement of gasoline engine by meeting the increasing demand for green energy power sources. The electrode materials considered here are fluorine-containing compounds including fluorophosphates LiMPO4F (M = V, Fe, T), Li2 M′PO4F (M = Fe, Co, Ni), hybrid ion Li x Na1−x VPO4F, and fluorosulfates LiMSO4F; M = Fe, Co, Ni, Mn, Zn, Mg). The electrochemical performance of these materials as the active cathode element of Li-ion batteries is also discussed.

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Authors and Affiliations

  1. Physicochimie des Electrolytes et Nanosystèmes Interfaciaux (PHENIX) UMR 8234, Sorbonne Universités UPMC Univ. Paris 06, Paris, France

    Christian Julien

  2. Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC) Muséum d’Histoire Naturelle, Institut de Recherche pour le Développement IRD UMR 7590 et 206, Sorbonne Universités, UPMC Univ Paris 06, Paris, France

    Alain Mauger

  3. Institut de Recherches d’Hydro-Québec (IREQ), Quebec, Québec, Canada

    Ashok Vijh & Karim Zaghib

Authors
  1. Christian Julien
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  3. Ashok Vijh
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  4. Karim Zaghib
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Julien, C., Mauger, A., Vijh, A., Zaghib, K. (2016). Fluoro-polyanionic Compounds. In: Lithium Batteries. Springer, Cham. https://doi.org/10.1007/978-3-319-19108-9_8

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  • DOI: https://doi.org/10.1007/978-3-319-19108-9_8

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