Skip to main content

High-pressure phase behavior of aqueous pNIPAm solutions

  • Chapter
  • First Online:
Smart Nanohybrids of RAFT Polymers and Inorganic Particles

Part of the book series: Springer Theses ((Springer Theses))

  • 519 Accesses

Abstract

This chapter is dedicated to the study of the special responsive behavior of aqueous solutions of the pNIPAm samples prepared in the preceding chapter upon exertion of high pressures. After a detailed literature study on the current state of research regarding the high-pressure experiments and the outline of the experimental set-up, the effect of different parameters on the phase-behavior is examined systematically. Especially the addition of ethanol as a cononsolvent provides new insight into this kind of system. By the later combination with nanoparticles, the polymer’s special responsive features can be passed on to the resulting smart nanohybrids.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References for Chapter 6

  1. Grobelny, S., Hofmann, C. H., Erlkamp, M., Plamper, F. A., Richtering, W., Winter, R., Soft Matter 2013, 9 (25), 5862–5866.

    Google Scholar 

  2. Hirotsu, S., J. Chem. Phys. 1988, 88 (1), 427–431.

    Google Scholar 

  3. Hirotsu, S., Onuki, A., J. Phys. Soc. Jap. 1989, 58 (5), 1508–1511.

    Google Scholar 

  4. Li, Y., Tanaka, T., J. Chem. Phys. 1989, 90 (9), 5161–5166.

    Google Scholar 

  5. Hirotsu, S., Macromolecules 1990, 23 (3), 903–905.

    Google Scholar 

  6. Hirotsu, S., J. Chem. Phys. 1991, 94 (5), 3949–3957.

    Google Scholar 

  7. Lee, K., Cussler, E., Marchetti, M., McHugh, M., Chem. Eng. Sci. 1990, 45 (3), 766–767.

    Google Scholar 

  8. Ohta, H., Ando, I., Fujishige, S., Kubota, K., J. Polym. Sci., Part B: Polym. Phys. 1991, 29 (8), 963–968.

    Google Scholar 

  9. Sanefuji, T., Ando, I., Inoue, Y., Uematsu, I., Shoji, A., Macromolecules 1985, 18 (3), 583–585.

    Google Scholar 

  10. Otake, K., Karaki, R., Ebina, T., Yokoyama, C., Takahashi, S., Macromolecules 1993, 26 (9), 2194–2197.

    Google Scholar 

  11. Kunugi, S., Takano, K., Tanaka, N., Suwa, K., Akashi, M., Macromolecules 1997, 30 (15), 4499–4501.

    Google Scholar 

  12. Suwa, K., Yamamoto, K., Akashi, M., Takano, K., Tanaka, N., Kunugi, S., Colloid Polym. Sci. 1998, 276 (6), 529–533.

    Google Scholar 

  13. Kunugi, S., Yamazaki, Y., Takano, K., Tanaka, N., Akashi, M., Langmuir 1999, 15 (12), 4056–4061.

    Google Scholar 

  14. Yamazaki, Y., Tada, T., Kunugi, S., English Colloid Polym. Sci. 2000, 278 (1), 80–83.

    Google Scholar 

  15. Rebelo, L. P. N., Visak, Z. P., Sousa, H. C. de, Szydlowski, J., Gomes de Azevedo, R., Ramos, A. M., Najdanovic-Visak, V., Nunes da Ponte, M., Klein, J., Macromolecules 2002, 35 (5), 1887–1895.

    Google Scholar 

  16. Gomez de Azevedo, R., Rebelo, L. P. N., Ramos, A. M., Szydlowski, J., Sousa, H. C. de, Klein, J., Fluid Phase Equilib. 2001, 185 (1-2), 189–198.

    Google Scholar 

  17. Kato, E., Kitada, T., Nakamoto, C., Macromolecules 1993, 26 (7), 1758–1760.

    Google Scholar 

  18. Kato, E., Kitada, T., J. Phys. Soc. Jap. 1994, 63 (7), 2831–2832.

    Google Scholar 

  19. Kato, E., J. Chem. Phys. 1994, 101 (1), 468–472.

    Google Scholar 

  20. Kato, E., Murakami, T., J. Phys. Soc. Jap. 1995, 64 (5), 1449–1452.

    Google Scholar 

  21. Nakamoto, C., Kitada, T., Kato, E., Polym. Gels Networks 1996, 4 (1), 17–31.

    Google Scholar 

  22. Kato, E., J. Chem. Phys. 1997, 106 (9), 3792–3797.

    Google Scholar 

  23. Kato, E., J. Chem. Phys. 2000, 113 (3), 1310–1314.

    Google Scholar 

  24. Kato, E., J. Appl. Polym. Sci. 2005, 95 (5), 1069–1072.

    Google Scholar 

  25. Kato, E., J. Appl. Polym. Sci. 2005, 97 (1), 405–412.

    Google Scholar 

  26. Zhong, X., Wang, Y.-X., Wang, S.-C., Chem. Eng. Sci. 1996, 51 (12), 3235–3239.

    Google Scholar 

  27. Kitada, T., J. Polym. Sci., Part A: Polym. Chem. 2001, 39 (13), 2315–2325.

    Google Scholar 

  28. Shibayama, M., Isono, K., Okabe, S., Karino, T., Nagao, M., Macromolecules 2004, 37 (8), 2909–2918.

    Google Scholar 

  29. Nasimova, I., Karino, T., Okabe, S., Nagao, M., Shibayama, M., Macromolecules 2004, 37 (23), 8721–8729.

    Google Scholar 

  30. Nasimova, I., Karino, T., Okabe, S., Nagao, M., Shibayama, M., J. Chem. Phys. 2004, 121 (19), 9708–9715.

    Google Scholar 

  31. Buckingham, A. D., Hentschel, H. G. E., J. Polym. Sci., Polym. Phys. Ed. 1980, 18 (4), 853–861.

    Google Scholar 

  32. Meersman, F., Wang, J., Wu, Y., Heremans, K., Macromolecules 2005, 38 (21), 8923–8928.

    Google Scholar 

  33. Wu, Y., Meersman, F., Ozaki, Y., Macromolecules 2006, 39 (3), 1182–1188.

    Google Scholar 

  34. Wu, Y., Meersman, F., Heremans, K., Ozaki, Y., J. Mol. Struct. 2006, 799 (1—3), 134–140.

    Google Scholar 

  35. Wu, Y., Jiang, J.-H., Ozaki, Y., J. Phys. Chem. A 2002, 106 (11), 2422–2429.

    Google Scholar 

  36. Wu, Y., Yuan, B., Zhao, J.-G., Ozaki, Y., J. Phys. Chem. B 2003, 107 (31), 7706–7715.

    Google Scholar 

  37. Puehse, M., Keerl, M., Scherzinger, C., Richtering, W., Winter, R., Polymer 2010, 51 (16), 3653–3659.

    Google Scholar 

  38. Pelton, R., Adv. Colloid Interface Sci. 2000, 85 (1), 1–33.

    Google Scholar 

  39. Saunders, B. R., Vincent, B., Adv. Colloid Interface Sci. 1999, 80 (1), 1–25.

    Google Scholar 

  40. Lietor-Santos, J. J., Sierra-Martin, B., Gasser, U., Fernandez-Nieves, A., Soft Matter 2011, 7 (14), 6370–6374.

    Google Scholar 

  41. Kunugi, S., Tanaka, N., Biochim. Biophys. Acta 2002, 1595 (1-2), 329–344.

    Google Scholar 

  42. Winter, R., Lopes, D., Grudzielanek, S., Vogtt, K., J. Non-Equilib. Thermodyn. 2007, 32 (1), 41–97.

    Google Scholar 

  43. Mishra, R., Winter, R., Angew. Chem. Int. Ed. 2008, 47 (35), 6518–6521.

    Google Scholar 

  44. Tamura, T., Yamaoka, T., Kunugi, S., Panitch, A., Tirrell, D. A., Biomacromolecules 2000, 1 (4), 552–555.

    Google Scholar 

  45. Hummer, G., Garde, S., Garda, A. E., Paulaitis, M. E., Pratt, L. R., Proc. Natl. Acad. Sci. U.S.A. 1998, 95 (4), 1552–1555.

    Google Scholar 

  46. Kunugi, S., Kameyama, K., Tada, T., Tanaka, N., Shibayama, M., Akashi, M., Braz. J. Med. Biol. Res. 2005, 38,1233–1238.

    Google Scholar 

  47. Paschek, D., Nonn, S., Geiger, A., Phys. Chem. Chem. Phys. 2005, 7 (14), 2780–2786.

    Google Scholar 

  48. Osaka, N., Shibayama, M., Macromolecules 2012, 45 (4), 2171–2174.

    Google Scholar 

  49. Osaka, N., Shibayama, M., Kikuchi, T., Yamamuro, O., J. Phys. Chem. B 2009, 113 (39), 12870–12876.

    Google Scholar 

  50. Ebeling, B., Eggers, S., Hendrich, M., Nitschke, A., Vana, P., Macromolecules 2014, 47 (4), 1462–1469.

    Google Scholar 

  51. Buback, M., Latz, H., Macromol. Chem. Phys. 2003, 204 (4), 638–645.

    Google Scholar 

  52. Becker, F., Buback, M., Latz, H., Sadowski, G., Tumakaka, F., Fluid Phase Equilib. 2004,215 (2), 263–282.

    Google Scholar 

  53. Latz, H. Kinetische und thermodynamische Untersuchungen der Hochdruck-Copolymerisation von Ethen mit (Meth)Acrylsaureestern, Ph.D. thesis, Georg-August-Universitat Gottingen, 2004.

    Google Scholar 

  54. Tumakaka, F., Sadowski, G., Latz, H., Buback, M., J. Supercrit. Fluids 2007, 41 (3), 461–471.

    Google Scholar 

  55. Hare, D. E., Sorensen, C. M., J. Chem. Phys. 1987, 87 (8), 4840–4845.

    Google Scholar 

  56. Sotani, T., Arabas, J., Kubota, H., Kijima, M., Asada, S., High Temp. High Press. 2000, 32 (4), 433–440.

    Google Scholar 

  57. Asada, S., Sotani, T., Arabas, J., Kubota, H., Matsuo, S., Tanaka, Y., J. Phys.: Condens. Matter 2002, 14 (44), 11447.

    Google Scholar 

  58. Saul, A., Wagner, W., J. Phys. Chem. Ref. Data 1989, 18 (4), 1537–1564.

    Google Scholar 

  59. Handbook of Chemistry and Physics; Lide, D. R., Ed.; CRC PRESS: 2003–2004; Vol. 84th.

    Google Scholar 

  60. Bertolini, D., Cassettari, M., Salvetti, G., Chem. Phys. Lett. 1985, 119 (6), 553–555.

    Google Scholar 

  61. Verma, M. P., Computers Geosci. 2003, 29 (9), 1155–1163.

    Google Scholar 

  62. Muller, A., Krebs, B., Monatsh. Chem. 1967, 98 (4), 1540–1544.

    Google Scholar 

  63. Patel, T., Ghosh, G., Yusa, S.-i., Bahadur, P., J. Dispersion Sci. Technol. 2011, 32 (8), 1111–1118.

    Google Scholar 

  64. Smeller, L., Biochim. Biophys. Acta 2002, 1595 (1—2), 11–29.

    Google Scholar 

  65. Okada, Y., Tanaka, F., Macromolecules 2005, 38 (10), 4465–4471.

    Google Scholar 

  66. Zheng, X., Tong, Z., Xie, X., Zeng, F., Polym. J. 1998, 30 (4), 284–288.

    Google Scholar 

  67. Tong, Z., Zeng, F., Zheng, X., Sato, T., Macromolecules 1999, 32 (13), 4488–4490.

    Google Scholar 

  68. Schild, H. G., Tirrell, D. A., J. Phys. Chem. 1990, 94 (10), 4352–4356.

    Google Scholar 

  69. Baltes, T., Garret-Flaudy, F., Freitag, R., J. Polym. Sci., Part A: Polym. Chem. 1999, 37 (15), 2977–2989.

    Google Scholar 

  70. Fujishige, S., Kubota, K., Ando, I., J. Phys. Chem. 1989, 93 (8), 3311–3313.

    Google Scholar 

  71. Tiktopulo, E. I., Uversky, V. N., Lushchik, V. B., Klenin, S. I., Bychkova, V. E., Ptitsyn, O. B., Macromolecules 1995, 28 (22), 7519–7524.

    Google Scholar 

  72. Ding, Z., Chen, G., Hoffman, A. S., Bioconjugate Chem. 1996, 7 (1), 121–125.

    Google Scholar 

  73. Furyk, S., Zhang, Y., Ortiz-Acosta, D., Cremer, P. S., Bergbreiter, D. E., J. Polym. Sci., Part A: Polym. Chem. 2006, 44 (4), 1492–1501.

    Google Scholar 

  74. Poole, P. H., Sciortino, F., Essmann, U., Stanley, H. E., Nature 1992, 360 (6402), 324–328.

    Google Scholar 

  75. Poole, P. H., Sciortino, F., Grande, T., Stanley, H. E., Angell, C. A., Phys. Rev. Lett. 1994, 73 (12), 1632–1635.

    Google Scholar 

  76. Tanaka, H., Nature 1996, 380 (6572), 328–330.

    Google Scholar 

  77. Mishima, O., Stanley, H. E., Nature 1998, 392 (6672), 164–168.

    Google Scholar 

  78. Mishima, O., Stanley, H. E., Nature 1998, 396 (6709), 329–335.

    Google Scholar 

  79. R0nne, C., Astrand, P.-O., Keiding, S. R., Phys. Rev. Lett. 1999, 82 (14), 2888–2891.

    Google Scholar 

  80. Starr, F. W., Sciortino, F., Stanley, H. E., Phys. Rev. E 1999, 60 (6), 6757–6768.

    Google Scholar 

  81. Errington, J. R., Debenedetti, P. G., Torquato, S., Phys. Rev. Lett. 2002, 89 (21), 215503.

    Google Scholar 

  82. Giovambattista, N., Buldyrev, S. V., Starr, F. W., Stanley, H. E., Phys. Rev. Lett. 2003, 90 (8), 085506.

    Google Scholar 

  83. Paschek, D., J. Chem. Phys. 2004, 120 (14), 6674–6690.

    Google Scholar 

  84. Scala, A., Starr, F. W., La Nave, E., Sciortino, F., Stanley, H. E., Nature 2000, 406 (6792), 166–169.

    Google Scholar 

  85. Soper, A. K., Ricci, M. A., Phys. Rev. Lett. 2000, 84 (13), 2881–2884.

    Google Scholar 

  86. Okhulkov, A. V., Demianets, Y. N., Gorbaty, Y. E., J. Chem. Phys. 1994, 100 (2), 1578–1588.

    Google Scholar 

  87. Brovchenko, I., Geiger, A., Oleinikova, A., J. Chem. Phys. 2003, 118 (21), 9473–9476.

    Google Scholar 

  88. Tanaka, H., Phys. Rev. E 2000, 62 (5), 6968–6976.

    Google Scholar 

  89. Bellissent-Funel, M.-C., Europhys. Lett. 1998, 42 (2), 161.

    Google Scholar 

  90. Mishima, O., Phys. Rev. Lett. 2000, 85 (2), 334–336.

    Google Scholar 

  91. Paschek, D., Phys. Rev. Lett. 2005, 94 (21), 217802.

    Google Scholar 

  92. Cavaille, D., Combes, D., Zwick, A., J. Raman Spectrosc. 1996, 27 (11), 853–857.

    Google Scholar 

  93. Costa, R. O., Freitas, R. F., Polymer 2002, 43 (22), 5879–5885.

    Google Scholar 

  94. Yang, C., Li, W., Wu, C., J. Phys. Chem. B 2004, 108 (31), 11866–11870.

    Google Scholar 

  95. Dubrovinsky, L., Dubrovinskaia, N., Prakapenka, V. B., Abakumov, A. M., Nat. Commun. 2012, 3, 1163.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bastian Ebeling .

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Ebeling, B. (2015). High-pressure phase behavior of aqueous pNIPAm solutions. In: Smart Nanohybrids of RAFT Polymers and Inorganic Particles. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-15245-5_6

Download citation

Publish with us

Policies and ethics