Abstract
Environmental protection has been a topic of great interest in recent years. Discharging azo dyes in aquatic systems contaminates water and causes serious ecological problems. Azo dyes are bio-accumulative, and, due to allergenic, carcinogenic and mutagenic properties, are a grave threat to people and the environment. Because of economic feasibility, simplicity and a high efficiency, adsorption is the most suitable process for treatment of wastewater. The increasingly interesting bio-degradable adsorbents are those that stem from ecologically and economically sustainable sources. The aim of the study is preparation and characterisation of polymer complexes based on naturally occurring polysaccharide-chitosan and poly(itaconic acid), as an adsorbent for removal of Reactive Orange 16 dye from wastewater. The complexes are characterised by Fourier-Transform Infrared Spectroscopy and Scanning electron microscopy. The effect of initial dye concentration, temperature and pH value of the solution on the adsorption capacities is investigated. Comparison of the obtained results with reported data shows the studied complex being an efficiently replacement for conventional adsorbents removing Reactive Orange 16 from wastewater.
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References
Ahmad MA, Rahman NK (2011) Equilibrium, kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon. Chem Eng J 170:154–161
Calvete T, Lima EC, Cardoso NF, Vaghetti JCP, Dias SLP, Pavan FA (2010) Application of carbon adsorbents prepared from Brazilian-pine fruit shell for the removal of Bezactiv Orange 16 from aqueous solution: Kinetic, equilibrium, and thermodynamic studies. J Environ Manage 91:1695–1706
Chiou MS, Ho PY, Li HY (2004) Adsorption of anionic dyes in acid solutions using chemically cross-linked chitosan beads. Dyes Pigm 60:69–84
Copello GJ, Mebert AM, Raineri M, Pesentia MP, Diaz LE (2011) Removal of dyes from water using chitosan hydrogel/SiO2 and chitin hydrogel/SiO2 hybrid materials obtained by the sol–gel method. J Hazard Mater 186:932–939
Crini G (2005) Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment. Prog Polym Sci 30:38–70
Dai J, Yan H, Yang H, Cheng R (2010) Simple method for preparation of chitosan/poly(acrylic acid) blending hydrogel beads and adsorption of copper(II) from aqueous solutions. Chem Eng J 165:240–249
Furlan FR, de Melo da Silva LG, Morgado AF, de Souza AAU, Ulson de Souza SMAG (2010) Removal of reactive dyes from aqueous solutions using combined coagulation/flocculation and adsorption on activated carbon. Resour Conserv Recyc 54:283–290
Gong R, Ding Y, Li M, Yang C, Liu H, Sun Y (2005) Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution. Dyes Pigment 64:187–192
Guibal E (2004) Interactions of metal ions with chitosan-based sorbents: a review. Sep Purif Technol 38:43–74
Hamdine M, Heuzey MC, Begin A (2005) Effect of organic and inorganic acids on concentrated chitosan solutions and gels. Int J Biol Macromol 37:134–142
Hameed BH, Mahmoud DK, Ahmad AL (2008) Equilibrium modeling and kinetic studies on the adsorption of basic dye by a low-cost adsorbent: coconut (Cocos nucifera) bunch waste. J Hazard Mater 158:65–72
Hasan M, Ahmad AL, Hameed BH (2008) Adsorption of reactive dye onto cross-linked chitosan/oil palm ash composite beads. Chem Eng J 136:164–172
Hu ZG, Zhang J, Chan WL, Szeto YS (2006) The sorption of acid dye onto chitosan nanoparticles. Polymer 47:5838–5842
Huang XY, Mao XY, Bu HT, Yu XY, Jiang GB, Zeng MH (2011) Chemical modification of chitosan by tetraethylenepentamine and adsorption study for anionic dye removal. Carbohydr Res 346:1232–1240
Kamari A. Pulford ID, Hargreaves JSJ (2011) Binding of heavy metal contaminants onto chitosan: an evaluation for remediation of metal contaminated soil and water, J Enviro Manage 92:2675–2682
Kirimura K, Sato T, Nakanishi N, Terada M, Usami S (1997) Breeding of starch-utilizing and itaconic-acid-producing koji molds by interspecific protoplast fusion between Aspergillus terreus and Aspergillus usamii. Appl Microbiol Biotechnol 47:127–131
Kołodynska D (2012) Adsorption characteristics of chitosan modified by chelating agents of a new generation. Chem Eng J 179:33–43
Kumar Konaganti V, Kota R, Patil S, Madras G (2010) Adsorption of anionic dyes on chitosan grafted poly(alkyl methacrylate)s. Chem Eng J 158:393–401
Ong ST, Lee CK, Zainal Z (2007) Removal of basic and reactive dyes using ethylenediamine modified rice hull. Biores Technol 98:2792–2799
Riscaldati E, Moresi M, Federici F, Petruccioli M (2000) Effect of pH and stirring rate on itaconate production by Aspergillus terreus. J Biotechnol 83:219–230
Royer B, Cardoso NF, Lima EC, Ruiz VSO, Macedo TR, Airoldi C (2009) Organofunctionalized kenyaite for dye removal from aqueous solution. J Colloid Interface Sci 336:398–405
Saiano F, Ciofalo M, Cacciola SO, Ramirez S (2005) Metal ion adsorption by Phomopsis sp. biomaterial in laboratory experiments and real wastewater treatments. Water Res 39:2273–2280
Smitha B, Sridhar S, Khan AA (2004) Polyelectrolyte complexes of chitosan and poly(acrylic acid) as proton exchange membranes for fuel cells. Macromolecules 37:2233–2239
Stephen B, Chiu CP, Ho GH, Yang J, Chen BH (2006) Removal of cationic dyes from aqueous solution using an anionic poly-glutamic acid-based adsorbent. J Hazard Mater 137(1):226–234
Sugama T, Cook M (2000) Poly(itaconic acid)-modified chitosan coatings for mitigating corrosion of aluminum substrates. Prog Organic Coat 38:79–87
Uzun I (2006) Kinetics of the adsorption of reactive dyes by chitosan. Dyes Pigment 70:76–83
Velickovic SJ, Dzunuzovic ES, Griffiths PC, Lacik I, Filipovic J, Popovic IG (2008) Polymerization of Itaconic Acid Initiated by a Potassium Persulfate/N,N-Dimethylethanolamine System. J Appl Polym Sci 110:3275–3282
Wan Ngah WS, Isa IM (1998) Comparison study of copper ion adsorption on chitosan dowex A-1 and zerolit 225. J Appl Polym Sci 67:1067–1070
Won SW, Choi SB, Yun YS (2006) Performance and mechanism in binding of Bezactiv Orange 16 to various types of sludge. Biochem Eng J 28:208–214
Yoshida H, Fukuda S, Okamoto A, Kataoka T (1991) Recovery of direct dye and acid dye by adsorption on chitosan fiber-equilibria. Water Sci Technol 23:1667–1676
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The authors acknowledge the Ministry of Science, Technology and Development of the Republic Serbia for funding the Science Projects No. 43009 and 172062.
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Nesic, A.R., Onjia, A., Velickovic, S.J., Antonovic, D.G. (2015). Preparation and Characterisation of Novel Biodegradable Material Based on Chitosan and Poly(Itaconic Acid) as Adsorbent for Removal of Reactive Orange 16 Dye from Wastewater. In: Leal Filho, W., Úbelis, A., Bērziņa, D. (eds) Sustainable Development, Knowledge Society and Smart Future Manufacturing Technologies. World Sustainability Series. Springer, Cham. https://doi.org/10.1007/978-3-319-14883-0_18
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